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L V L M V: Design Equation: 1000 1

This document presents equations and calculations for the design of a continuous stirred tank reactor (CSTR) process. It includes equations for the design volume, conversion, temperature, reaction rate constant, and reaction rate. The calculations determine that at 35°C, the conversion is 0.71%, the temperature inside the reactor is 324°K, the volume required is 1000L, and the reaction rate is 1.42 mol/L-min.

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solehah misni
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25 views

L V L M V: Design Equation: 1000 1

This document presents equations and calculations for the design of a continuous stirred tank reactor (CSTR) process. It includes equations for the design volume, conversion, temperature, reaction rate constant, and reaction rate. The calculations determine that at 35°C, the conversion is 0.71%, the temperature inside the reactor is 324°K, the volume required is 1000L, and the reaction rate is 1.42 mol/L-min.

Uploaded by

solehah misni
Copyright
© © All Rights Reserved
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
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DESIGN EQUATION:

V 1m 3 1000 L
V0 200000 L / min

C A0
V0

FA0
V0
FA0 1600000mol / min

C A0
16mol / L

V0 100000 L / min
V0 H 2 O EO 100000 100000 200000 L / min
V

FAO X C A0V0 X
C A0V0 X
V0 X

rA
kCA
kCA0 (1 X ) k (1 X )

200000 X
k (1 X )
1000(k kX ) 200000 X
1000k 1000kX 200000 X
1000k 200000 X 1000kX
1000k
k
X

200000 1000k 200 k


1000

ENERGY BALANCE:
H RX 37669 J / mol
Cp A 43.71J / mol.K
Cp B 0.498 J / mol.K
Cp water 0.2747 J / mol.K
i Cpi 43.9847 J / mol.K
Cp 43.212 J / mol.K

X [ H RX (TR )] i Cpi T0 XCpTR


i Cpi XCp

X [37669] 43.9847(308.15) X (43.212)( 298.15)


43.9847 X (43.212)
37669 X 13553.8853 12883.6578 X
T
43.9847 43.212 X
24785.3422 X 13553.8853
T
43.9847 43.212 X
43.9847T 13553.8853 24785.3422 X 43.212 XT
43.9847T 13553.8853
X
24785.3422 43.212T
T

ARHENIUS LAW:
Ea 79046 J / mol
R 8.314 J / mol.K
k1 gradient 0.3144 min 1
T 35C 308.15 K
k2
k1

ln

Ea 1 1
( )
R T1 T2

k2
79046
1
1


8.314 308.15 T2
0.3144

ln

1
1

k 2 0.3144 exp 9507.58

308.15 T2

1000k
k

200000 1000 k 200 k


k
0.0071
200 k
0.0071(200 k ) k
X

1.42 0.0071k k
k 1.4302

1
1

k 2 0.3144 exp 9507.58



308.15 T2

1
1

1.4302 0.3144 exp 9507.58



308.15 T2

T2 324.06 K

V0 X
k (1 X )
200000(0.0071)
V
1.4302(1 0.0071)
999.968 L
V

rA kC A
rA kC A0 (1 X )
rA 1.4302(1)(1 0.0071)
rA 1.4200mol / L. min

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