1st PU Chemistry March 2014 PDF
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Prasad C M1st PU Chemistry March 2014 PDF
Uploaded by
Prasad C MFor More Question Papers Visit - www.pediawikiblog.
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PUC FIRST YEAR DIST. LEVEL ANNUAL.EXAM FEB I MARCH 2014
Duration : 3 Hrs 15 Min.
Max. Marks : 7O
subject : CHEMIsTRY
Code : 34
Date :
i)
ji)
PART . A
'
10x1=10
Name the fundamental particle of an atom that has highest value of e/m.
Give reason : H-l is Lewis base.
lo
2)
3)
questions.
g.
I. Answer ALL the following
1) What is S.I. unit of density
co
The question paper has FOUR parts A, B, C and D. All the parts qre compulsory.
Write balanced chemical equations and draw labelled diagrams wherever asked.
iii)Uselogtablesandsimplecalculatorsifnecessary
(Use of scientific calculators is not allowed)
Instructions :
as
ik
ib
6) A mixture of carbon monoxide and''hydrogen is known
7) Which alkali metal is str:ongest reducing agent ?
8) Mention the type.of hybridisation in graphite.
9) What is electrophile ?
10) Write the bond line formula for 2- bromobutane.
ia
PART - B:
IL Answer any FIVE of the following questions.
11) How many significant figures are in 4.O1 x 1O2 ? How many seconds are
there in two days ?
12) State Boyle's iaw and write the relationship between density and molar
13) Define bond ord-er. Write the electronic
5x2=1,0
configuration o{ Li.,molecule.
.p
ed
14) Calculate [H+] of solution whose pH is 8.8.
15)Writethebalancedequationsforreactionsbetween..
an.' ^Or
-:r.1 O..
'ii)
\ril |L': -.r'"
2.
"2.
16) What happens when Aluminium is heated with concentrated H2SO4 ?
17) What is meant by Biochemical Oxygen Demand (BOD) ? What is its significant ?
18) Write the IUPRC names of
cHs
/i\ /-r/Au'tr.,;
4J,
(i) cH3-c-cH3
I
cHa
PART -,C
III. Answer any FIVE of the following questions.
19) State modern periodic law. Define 'P' block elements and write its
common outer electronic configuration.
20) Give any three postulates of Molecular Orbital theory. (MOT),
21) Write any three differences between sigma bond and pi- bond.
22) Explain SP3 hybridisation in methane molecule.
23) Balance the redox reaction by oxidation number method.
Fe2* + MnOll
_--)
Fe3* +.Mn2*
5x3={5
(P.r.o.)
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PAGE NO. 2
GHEMISTRY P.U.G1 FIRST YEAR
6)
[dF
co
25)
How is hydrogen prepared by electrolysis of water ? What is
meant by "2O vol." HrO, ?
With equation explain what happens when diboran is exposed to air ?
Name one metal present in 14th group of periodic table.
Write the chemical reaction taking place during the manufacture of caustic
soda by Solvay's process.
PART
g.
24)
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_D
Answer any FIVE of the following questions.
ZZ') a) A compound contains 4.O7o/o hydrogen, 24.27o/o carbon and71.65Yo
. chlorine- Its molecular mass is 98.96. Calculate its empirieal formula.
b) State law of of multiple proportions.
28) a) Write'the significance of all quantum.numbers.
b) State Pauli's exclusion principle.
29) a) Galculate the wave number of first line in Balmer series of hydrogen
spectrum. (R = 1.096 x 1O*7 m-1).
b) Find the number of protons and neutrons in 56re.
5 x 5 = 25
ib
lo
IV.
[3 + 2]
ik
14
.p
ed
ia
[4 +1I
c)
increasing external pressure. Catbulate the maximum work done.
(R = 8.314 JK-1 mol-1 and log.,o 2 = O.3010)
State Hess's law.
What is entropy
Give its
unit.
33) a) Explain Bronsted - Lowry concept of acids and bases
b)
34) a)
b)
13+ 2l
11 + 2
What is conjugate acid for NH. 2
Give the relationship between Kp and Kc.
State Le-Chatelier's principle and what is the effect of change of
temperature and pressure for the reaction.
N',n,
+ 2l
3H',nl
2NHt,n,'
AH =
[4 + 1]
92'4KJ
Explain common ion effect.
V. Answer any TWO of the following questions.
35) a) Write the equations for step$ i'nvolved In the mechanism of
chlorination of benzene.
b) Explain geometrical isomerism in But - 2 -ene.
36) a), How is halogen estimated by Carius method ?
b) What iq homologous series ?
37) a) Explain with an example Wurtz reaction.
b) How do you convert ethyne to benzene ?
c)
17
[3 + 2]
,26
30) a) Write any four postulates of Kinetic theory of gases.
b) Write Van-der Waal's equation for one mole of a. real gas.
31) a) Explain the measurment of AU by bomb calorimeter in brief.
b) Six moles of an ideal gas at 27oC is compressed at constant temperature
'
isothermally and.reversibly from a voltrme of 5lits to 1O lits by slowly
32) a)
Name the'reagent used for dehydrohalogenation of
haloalkanes.
[3+2]
12
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+ 2+
1l
