Page 1 of 5
Sika Canada Inc.
MATERIAL SAFETY DATA SHEET
SECTION I: PRODUCT INFORMATION
PRODUCT:
Sikalastic Duochem 390 Membrane
USAGE:
Urethane membrane
PART A
REVISION DATE: November 8, 2012
MANUFACTURER/SUPPLIER: SIKA CANADA INC.
601, avenue Delmar
Pointe Claire, QC
H9R 4A9
EMERGENCY TELEPHONE NUMBER: CANUTEC (collect) (613) 996-6666
TDG CLASSIFICATION:
UN NUMBER:
Packaging Group
Not regulated
Not applicable
Not applicable
WHMIS Classification: D2B
Class:
Not applicable
SECTION II: HAZARDOUS INGREDIENTS
Hazardous ingredients
Castor oil
T.L.V.
# CAS
LD50 (mg/kg)
(species, route)
LC50
(species, route)
60-100
N.A.
8001-79-4
> 5000 (oral, rat)
N.A.
SECTION III: PHYSICAL CHARACTERISTICS
Physical State:
Liquid
Appearance and Odor: Neutral or colored liquid, no odor
Odor Threshold:
Evaporation Rate:
Vapor Density:
Vapor Pressure:
Not established
Not applicable
Not applicable
Not applicable
Boiling Point:
Freezing Point:
Density:
Water Solubility:
pH:
% volatility:
Water/Oil Distribution:
Not established
Not established
098 1.03 g/ml
No
Not established
Not applicable
Not established
Page 2 of 5
MATERIAL SAFETY DATA SHEET
Sika Canada Inc.
PRODUCT:
Sikalastic Duochem 390 Membrane
PART A
SECTION IV: FIRE AND EXPLOSION HAZARDS
Flammability:
No
If Yes, under what conditions:
Extinguishing methods:
Special Methods:
Foam, dry chemical
products, CO2, water hose.
Firefighters must wear
usual protective clothing
and respiratory
equipment. A water hose
may be used to cool the
containers and dissipate
the vapors.
TDG Flammability Class:
Flammable upper limits (% vol.):
Flammable lower limits (% vol.):
Flash Point (method used):
Auto-ignition temperature:
Not regulated
Not established
Not established
o
~ 282 C (tcc)
Not established
Dangerous Combustion Products:
COx
Protect from mechanical impact:
No
Protect from static discharge:
No
SECTION V: REACTIVITY
Chemical stability:
Yes
If not, under what conditions
But avoid
excessive heat.
Incompatibility with other material:
Yes
If Yes, which ones:
Oxidizer.
Dangerous decomposition products:
No
Polymerization Risks:
No.
Page 3 of 5
Sika Canada Inc.
PRODUCT:
MATERIAL SAFETY DATA SHEET
Sikalastic Duochem 390 Membrane
PART A
SECTION VI: TOXIC PROPERTIES
ROUTE OF ENTRY / CONTACT
Eyes:
May cause light eye irritations.
Carcinogenicity:
Not Established
Skin:
No effect known or suspected.
Toxic effects
on reproduction:
Not Established
Teratogenicity:
Not Established
Mutagenicity:
Not Established
Product with synergistic
effects:
Not Established
Inhalation:
Ingestion:
No effect known.
May cause discomfort.
An acute or chronic exposure will increase the toxic effects mentioned in this section and may aggravate respiratory
problems.
Page 4 of 5
Sika Canada Inc.
PRODUCT:
MATERIAL SAFETY DATA SHEET
Sikalastic Duochem 390 Membrane
PART A
SECTION VII: PREVENTIVE MEASURES
PERSONAL PROTECTIVE EQUIPMENT
OTHERS
Gloves:
Ventilation:
Chemical resistant gloves.
Respiratory equipment: Not necessary under normal use.
Eyes:
Full-face mask or safety glasses
Shoes:
Leather
Clothing:
Rubber apron
Other:
Eye wash station, shower
Procedure in case
of leaks:
Sufficient ventilation required.
Absorb with sand or other
absorbent material. Residue may
be removed with steam or hot
water and soap. All precautions
should be taken when cleaning
the spill with solvent.
Handling and Equipment
methods:
Avoid skin, eye and clothing
contact.
Warehouse
requirements:
Special Shipping
Instructions:
Waste Disposal:
Keep all containers closed. Keep
in a cool, dry and well ventilated
area. Keep away from heat and
open flame.
See TDG class.
Dispose of sand and rinse water
according to municipal, provincial
or federal laws for disposal of
chemicals.
Page 5 of 5
Sika Canada Inc.
PRODUCT:
MATERIAL SAFETY DATA SHEET
Sikalastic Duochem 390 Membrane
PART A
SECTION VIII: FIRST AID
Skin:
Remove contaminated clothing and shoes.
Wash immediately with plenty of soap and water.
Wash clothing before re-wearing.
Consult a physician if required.
Eyes:
Rinse eyes immediately with plenty of water for several minutes, while holding
eyelids wide open, to ensure a proper wash.
Consult a physician if required.
Inhalation:
In the case of overexposure, evacuate to fresh air.
Consult a physician if required.
Ingestion:
Drink plenty of water. Do not induce vomiting.
Do not give anything by mouth to an unconscious person.
See a physician immediately.
SECTION IX: PREPARATION INFORMATION
Prepared By:
Telephone #:
Fax #:
Sika Canada R & D.
(514) 697-2610
(514) 694-2792
Notice To Reader
The information contained in this Material Safety Data Sheet applies only to the actual Sika Canada product identified and described herein. This
information is not intended to address, nor does it address the use or application of the identified Sika product in combination with any other material,
product or process. All of the information set forth herein is based on technical data regarding the identified product that Sika believes to be reliable
as of the date hereof. Prior to each use of any Sika product, the user must always read and follow the warnings and instructions on the product's
current Product Data Sheet, product label and Material Safety Data Sheet for each Sika product, which are available at web site and/or telephone
number listed in Section IX of this MSDS.
SIKA MAKES NO WARRANTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY ARISING FROM THIS INFORMATION OR ITS USE.
SIKA SHALL NOT BE LIABLE UNDER ANY LEGAL THEORY FOR SPECIAL OR CONSEQUENTIAL DAMAGES AND SHALL NOT BE
RESPONSIBLE FOR THE USE OF THIS PRODUCT IN A MANNER TO INFRINGE ON ANY PATENT OR ANY OTHER INTELLECTUAL
PROPERTY RIGHTS HELD BY OTHERS.
All sales of Sika products are subject to its current terms and conditions of sale available at www.sika.ca or 514-697-2610.
AQ 191 A
Date: 2012/02/01
App: S.G.
Page 1 of 5
MATERIAL SAFETY DATA SHEET
Sika Canada Inc.
SECTION I: PRODUCT INFORMATION
PRODUCT:
Sikalastic Duochem 390 Membrane
USAGE:
Hardener
Part B
REVISION DATE: November 8, 2012
MANUFACTURER/SUPPLIER: SIKA CANADA INC.
601, avenue Delmar
Pointe Claire, QC
H9R 4A9
EMERGENCY TELEPHONE NUMBER: CANUTEC (collect) (613) 996-6666
TDG CLASSIFICATION:
UN NUMBER:
Packaging Group:
Not regulated
Not regulated
Not regulated
WHMIS Classification: D1A, D2A, D2B
Class:
Not regulated
SECTION II: HAZARDOUS INGREDIENTS
Hazardous
ingredients
T.L.V.
# CAS
LD50 (mg/kg)
(route, species)
LC50
(species, route)
POLYISOCYANATE
BASED ON MDI
30-60
NOT AVAILABLE
NOT AVAILABLE
NOT AVAILABLE
NOT AVAILABLE
4,4DIPHENYLMETHAN
E DIISOCYANATE
(MDI)
15-40
ACGIH
0.005 ppm
101-68-8
31 600 (rat, oral)
369 mg/m /4H
(rat)
SECTION III: PHYSICAL CHARACTERISTICS
Physical State:
Appearance and Odor:
Odor Threshold:
Evaporation Rate:
Vapor Density:
Vapor Pressure:
Liquid
Straw yellow with slightly musty
odor
Not available
Not available
8.5 (MDI)
Not available
Boiling Point:
Freezing Point:
Density:
Water Solubility:
pH:
% volatility by volume:
Water/Oil Distribution:
208C @ 5 mm Hg (MDI)
< 0C
1.21 g/ml
Slight
Not available
Not available
Not available
Page 2 of 5
MATERIAL SAFETY DATA SHEET
Sika Canada Inc.
PRODUCT:
Sikalastic Duochem 390 Membrane
Part B
SECTION IV: FIRE AND EXPLOSION HAZARDS
Flammability:
No
If Yes, under what conditions:
Extinguishing methods:
Water fog, CO2, dry
chemical, foam
Special Methods:
Fire-fighters must wear
complete protective
clothing with respiratory
equipment
TDG Flammability Class:
Flammable upper limits (% vol.):
Flammable lower limits (% vol.):
Flash Point (setaflash closed cup):
Auto-ignition temperature:
Dangerous Combustion Products
Not applicable
Not applicable
Not applicable
> 200C
> 400C
Carbon oxides,
nitrogen oxides,
HCN and toxic
fumes.
Protect from mechanical impact:
No
Protect from static discharge:
No
SECTION V: REACTIVITY DATA
Chemical stability:
Stable
Dangerous decomposition products:
Carbon oxides,
when in contact
with water.
Polymerization Risks:
May occur
If not, under what conditions:
Incompatibility with other material:
Yes
If Yes, which ones:
Water, moisture,
alcohol, amines
and alkalis.
Page 3 of 5
Sika Canada Inc.
PRODUCT:
MATERIAL SAFETY DATA SHEET
Sikalastic Duochem 390 Membrane
Part B
SECTION VI: TOXICOLOGICAL PROPERTIES
ROUTE OF ENTRY / CONTACT
Eyes:
Skin:
Inhalation:
Ingestion:
Will result in eye irritation, tears and
redness. Temporary corneal damage
may occur if left untreated.
Carcinogenicity:
Not Established
Toxic effects
on reproduction:
Not Established
Teratogenicity:
Not Established
Mutagenicity:
Not Established
Product with synergistic
effects:
Not Established
May cause skin irritation, redness and
swelling.
High vapor concentration may produce
nausea, vomiting, headaches, dizziness,
unconsciousness and asphyxia resulting
in central nervous system effects, may
be a respiratory sensitizer
May cause abdominal pain, vomiting
and diarrhea. May cause mouth,
digestive tube and stomach burns.
Over exposure may cause breathing difficulties,
sensitization, headaches, nausea, vomiting.
May aggravate respiratory, skin, eye, lung problems and
allergies.
If the product is applied according to the manufacturer,
none of these symptoms should be encountered.
A person who is sensitized to isocyanate may have a
reaction with a level of isocyanate well below the T.L.V.
An acute or chronic exposure will increase the toxic effects mentioned in this section and may aggravate respiratory
problems.
Page 4 of 5
Sika Canada Inc.
PRODUCT:
MATERIAL SAFETY DATA SHEET
Sikalastic Duochem 390 Membrane
Part B
SECTION VII: PREVENTIVE MEASURES
PERSONAL PROTECTIVE EQUIPMENT
OTHERS
Gloves:
Ventilation:
Chemical resistant gloves.
Respiratory equipment: Use a NIOSH /MSHA approved
air purifying organic vapor mask if
TLV are exceeded
Eyes:
Chemical goggles and full face
shield
Shoes:
Security shoes
Clothing:
Long sleeved, body covering and
protective clothing
Other:
No
Procedure in case
of leaks:
Use adequate ventilation
Remove all sources of ignition
(flames, sparks, etc.). Provide
adequate ventilation. Avoid
prolonged breathing of vapors.
Remove to a container or absorb
with clay, diatomaceous earth or
other suitable inert absorbent.
Handling and Equipment
Methods:
Avoid inhalation, skin and eye
contact. Wash repeatedly with
soap and water during the
workday.
Warehouse
Requirements:
Special Shipping
Instructions:
Waste Disposal:
Keep all containers closed in a
cool, dry and well ventilated area.
See TDG class.
Dispose of residues according to
municipal, provincial or federal
laws for disposal of chemicals.
Do not incinerate closed
containers.
Page 5 of 5
Sika Canada Inc.
PRODUCT:
MATERIAL SAFETY DATA SHEET
Sikalastic Duochem 390 Membrane
Part B
SECTION VIII: FIRST AID
Skin:
Remove contaminated clothing and shoes.
Wash immediately with plenty of soap and water.
Wash clothing before re-wearing.
Consult a physician if required.
Eyes:
Rinse eyes immediately with plenty of water for several minutes, while holding
eyelids wide open, to ensure a proper wash.
Consult a physician if required.
Inhalation:
In the case of overexposure, evacuate to fresh air.
Consult a physician if required.
Ingestion:
Drink plenty of water. Do not induce vomiting.
Do not give anything by mouth to an unconscious person.
See a physician immediately.
SECTION IX: PREPARATION INFORMATION
Prepared By:
Telephone #:
Fax #:
Sika Canada R & D.
(514) 697-2610
(514) 694-2792
Notice To Reader
The information contained in this Material Safety Data Sheet applies only to the actual Sika Canada product identified and described herein. This
information is not intended to address, nor does it address the use or application of the identified Sika product in combination with any other material,
product or process. All of the information set forth herein is based on technical data regarding the identified product that Sika believes to be reliable
as of the date hereof. Prior to each use of any Sika product, the user must always read and follow the warnings and instructions on the product's
current Product Data Sheet, product label and Material Safety Data Sheet for each Sika product, which are available at web site and/or telephone
number listed in Section IX of this MSDS.
SIKA MAKES NO WARRANTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY ARISING FROM THIS INFORMATION OR ITS USE.
SIKA SHALL NOT BE LIABLE UNDER ANY LEGAL THEORY FOR SPECIAL OR CONSEQUENTIAL DAMAGES AND SHALL NOT BE
RESPONSIBLE FOR THE USE OF THIS PRODUCT IN A MANNER TO INFRINGE ON ANY PATENT OR ANY OTHER INTELLECTUAL
PROPERTY RIGHTS HELD BY OTHERS.
All sales of Sika products are subject to its current terms and conditions of sale available at www.sika.ca or 514-697-2610.
AQ 191 A
Date: 2012/02/01
App: S.G.
