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SAFETY DATA SHEET

BELZONA 2111 (D&A HI-BUILD ELASTOMER) SOLIDIFIER
1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
PRODUCT NAME

BELZONA 2111 (D&A HI-BUILD ELASTOMER) SOLIDIFIER

INTERNAL ID

1117/1265/06

APPLICATION

Solidifier component of a two component system. Mix with Belzona 2100 Base component before use.
Durable and abrasion resistant system for coating metal surfaces and for repairing, rebuilding and
protecting rubber substrates. Application by plastic applicator or spatula provided. Please refer to the
relevant Belzona Instructions For Use for further information. For use only by professional operators.

SUPPLIER

Belzona Polymerics Limited

Claro Road, Harrogate
North Yorkshire
HG1 4DS, England
+44 (0) 1423 567641
+44 (0) 1423 505967
[email protected]

EMERGENCY TELEPHONE

+44 (0) 1423 567641 (office hours)

2 HAZARDS IDENTIFICATION
Harmful if swallowed. May cause sensitisation by skin contact. Harmful: danger of serious damage to health by prolonged exposure in
contact with skin and if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Possible risk of irreversible effects.
For further information, please refer to Sections 8 and 11.
CLASSIFICATION

Xn;R22, R48/21/22. Mut 3;R68. R43. N;R50/53.

3 COMPOSITION/INFORMATION ON INGREDIENTS
Name

EC No.

POLYETHER POLYOL

CAS-No.

Content

Classification

25322-69-4

30-60%

Xn;R22.
Muta3;R68 T;R23/24/25 R43 Xi;R36
N;R50/53
T;R25,R48/24/25. C;R34. N;R50/53.

PHENYLENEDIAMINE -meta

203-584-7

108-45-2

1-5%

PHENYLMERCURIC NEODECANOATE

247-783-7

26545-49-3

1-5%

The Full Text for all R-Phrases are Displayed in Section 16

4 FIRST-AID MEASURES
GENERAL INFORMATION
In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person.
INHALATION
Remove to fresh air. Keep the patient warm and at rest. If breathing has stopped, administer artificial respiration. Give nothing by mouth.
If unconscious, place in the recovery position and seek medical advice.
INGESTION
If accidentally swallowed obtain immediate medical attention. Keep at rest. Rinse mouth with plenty of water and drink plenty of water. Do
NOT induce vomiting.
SKIN CONTACT
Remove contaminated clothing. Wash skin thoroughly with soap and water or use a proprietary skin cleaner. Do NOT use solvents or
thinners. If irritation or inflammation persists, seek medical attention.
EYE CONTACT
Contact lenses should be removed. Irrigate copiously with clean, fresh water for at least 15 minutes, holding the eyelids apart, and seek
medical advice.

5 FIRE-FIGHTING MEASURES
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EXTINGUISHING MEDIA
Use: sand, alcohol resistant foam, carbon dioxide, chemical powder, water fog for larger fires.
Do NOT use water jet.
SPECIAL FIRE FIGHTING PROCEDURES
Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). Exposure to decomposition products
may be a hazard to health. Appropriate self-contained breathing apparatus may be required. Cool closed containers exposed to fire with
water spray. Do not allow run-off from fire fighting to enter drains or watercourses.

6 ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS
Exclude sources of ignition and ventilate the area. Exclude non-essential personnel. Avoid contact with skin and eyes. Refer to protective
measures listed in Section 8.
ENVIRONMENTAL PRECAUTIONS
Prevent spills from entering drains or sewers. If the product enters drains or sewers in large quantities, the local Water Company should be
contacted immediately; in the case of contamination of streams, rivers or lakes, the appropriate National regulating agency. Refer to
information sources listed in Section 16.
SPILL CLEAN UP METHODS
Contain and collect spillages with non-combustible absorbent materials e.g. sand, earth, vermiculite, diatomaceous earth and place into a
suitable labelled container. Clean surfaces down with a water and detergent mixture. Refer to disposal methods listed in Section 13. Do not
allow spilled product or the associated washings to enter surface water drains or watercourses.

7 HANDLING AND STORAGE

USAGE PRECAUTIONS
GENERAL
Keep the container tightly closed when not in use. Where possible open containers and mix components in a well ventilated place away
from the application area. Vapours may collect in the container headspace during transit or prolonged storage. Avoid the inhalation of
vapour when opening the container. Handle with extreme care to avoid all skin and eye contact. Smoking, eating and drinking should be
prohibited in areas of storage and use. For personal protection see Section 8. Always keep in containers made of the same material as the
supply container. Good housekeeping methods and regular safe removal of waste materials should be observed. The Manual Handling
Operations Regulations may apply to the handling of containers/packages of this product. Refer to the guide weight on the
container/package when carrying out assessments.
FIRE/EXPLOSION
This product is combustible. Exclude sources of heat, sparks and open flame.
SPECIAL
In cold conditions to ease mixing, containers should be allowed to reach room temperature in a warm ventilated store inside the work
place. The phenylenediamine -meta contained within this product reacts when mixed with the Base component eliminating the risk of
exposure during subsequent product application.
STORAGE PRECAUTIONS
Observe the label precautions. Store between 5C and 30C unless otherwise stated in a dry, well ventilated place away from sources of
heat, ignition and direct sunlight. No smoking. Prevent unauthorised access. Store separately from oxidising agents and strongly alkaline
and strongly acidic materials.
ENVIRONMENTAL STORAGE PRECAUTIONS
Spillage, incorrect storage of chemicals or waste materials or unsuitable disposal activities can result in pollutants seeping through the
soil, causing serious harm to groundwater- which is a vital source of drinking water. All wastes especially liquid wastes, must be securely
stored on site in designated areas that are isolated from surface drains and bunded to contain any spillages.
STORAGE CLASS
The principals contained in the HSE guidance note Chemical Warehousing: storage of packaged dangerous substances (HSG71) should
be observed when storing this product.

8 EXPOSURE CONTROLS/PERSONAL PROTECTION

INGREDIENT COMMENTS
When personal protective equipment, including respiratory protective equipment, is used to control exposure to hazardous substances it
must be selected to meet the requirements of the COSHH Regulations.
Phenylenediamine -meta is solid at ambient temperatures. Due to the physical form of this product it is not likely to pose an inhalation
exposure risk during normal storage, use or disposal.
ENGINEERING MEASURES
Open containers in a well ventilated area.
RESPIRATORY EQUIPMENT
Respiratory protection is not normally required but it may be required when this product is used in confined spaces or where adequate
ventilation cannot be achieved.

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HAND PROTECTION
GENERAL GUIDANCE ON HAND PROTECTION
Hand protection should be selected in accordance with EN 374 Protective gloves against chemicals. The breakthrough time of the gloves
selected should exceed the expected use period. Where this is not possible gloves should be changed in good time, and in any case
before the breakthrough time is exceeded. If any doubt exists, advice should be sought from glove suppliers on appropriate types. Barrier
creams may help to protect exposed areas of skin but are not substitutes for full physical protection. They should not be applied once
exposure has occurred.
SPECIFIC RECOMMENDATIONS
Use protective gloves made of: Nitrile. Polyvinyl chloride (PVC).
STANDARD APPLICATIONS
Medium-heavy weight gauntlet type gloves that provide wrist protection are suitable.
EYE PROTECTION
It is recommended that eye protection, for example safety spectacles or goggles are worn at all times during the handling and use of this
material. Eye protection should be selected in accordance with EN 166 Personal eye protection.
OTHER PROTECTION
STANDARD APPLICATIONS
Synthetic polyethylene coveralls such as the Tyvek PRO-TECH or equivalent coveralls manufactured to EN 13034 Type 6, Protective
clothing against liquid chemicals. Grossly contaminated clothing should be removed and the skin washed with soap and water or a
proprietary skin cleaner.
HYGIENE MEASURES
Wash at the end of each work shift and before eating, smoking and using the toilet. Ensure eye wash facilities (fountain, bottle, vials,
etc.) are readily available. Do not put contaminated articles or equipment e.g. spatulas, applicators, brushes, cloths etc., into pockets.
Where necessary, contaminated work clothing should be removed to prevent cross contamination of surfaces and the risk of inadvertent
skin contact and ingestion.

9 PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE

Liquid

COLOUR

Black

ODOUR

Slight odour

PHYSICAL DATA COMMENTS

This section contains typical values for Health, Safety and Environmental guidance only and is not
intended to represent a technical specification for the product. L = Low. NIA = No Information available.
LP = See Section 12.

SOLUBILITY

Partially miscible with water.

BOILING POINT (C)

VAPOUR DENSITY (air=1)
VISCOSITY

> 100 @ 760 mm Hg

>1
NIA

FLASH POINT (C)

> 120 CC (Closed cup).

PARTITION COEFFICIENT
(N-Octanol/Water)

LP

RELATIVE DENSITY
VAPOUR PRESSURE

0.99 - 1.01 @ 20 C
L
DECOMPOSITION TEMPERATURE NIA
(C)
> 330 C
AUTO IGNITION
TEMPERATURE (C)

10 STABILITY AND REACTIVITY

STABILITY
Stable under recommended storage and handling conditions (see Section 7). In a fire, hazardous decomposition products such as smoke,
carbon monoxide, carbon dioxide, oxides of nitrogen and mercury vapours may be produced.
CONDITIONS TO AVOID
Keep away from oxidising agents and strongly alkaline and strongly acidic materials to prevent the possibility of exothermic reaction.

11 TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION
There is no data on the product itself. The EC have classified phenylenediamine -meta as a Category 3 mutagen indicating a cause for
concern for humans owing to possible mutagenic effects.
INHALATION
Vapours that may collect in the container headspace during transit or prolonged storage may be harmful by inhalation.
INGESTION
Ingestion is not normally an exposure risk arising from professional applications. Inadvertent ingestion of small amounts of this product
through poor hygiene or cross contamination may be harmful. Harmful: danger of serious damage to health by prolonged exposure if
swallowed.

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SKIN CONTACT
Skin contact constitutes a pronounced hazard. Harmful: danger of serious damage to health by prolonged exposure in contact with skin.
Prolonged or repeated contact with the skin may cause irritation, blistering or dermatitis. Causes of allergic skin reaction have been
observed.
EYE CONTACT
Product splashes in the eye may cause irritation.
ROUTE OF ENTRY
Skin and/or eye contact. Ingestion. Inhalation.
MEDICAL SYMPTOMS
Prolonged or repeated contact with the skin or mucous membrane may result in irritant symptoms such as redness, blistering or dermatitis.
Onset of symptoms may be delayed.
MEDICAL CONSIDERATIONS
Skin contact constitutes a pronounced hazard. Persons with a history of skin sensitisation problems should only be employed in processes
in which this product is used under appropriate medical supervision.

12 ECOLOGICAL INFORMATION
ECOTOXICITY
There is no data on the product itself. The following information is provided on the basis of the individual component data available, and in
strict compliance with the conventional classification guidelines for preparations as outlined in the Chemicals (Hazard Information and
Packaging for Supply) Regulations. The product should not be allowed to enter drains or watercourses or be deposited where it can affect
ground or surface waters. See also Sections 5, 6, 7, 9 and 13.
BIOACCUMULATION
Based on the phenylmercuric neodecanoate and phenylenediamine -meta content, this product is expected to bioaccumulate. Log
octanol/water partition coefficient (Log Pow) is expected to be greater than 3.0. May cause long-term adverse effects in the aquatic
environment.
DEGRADABILITY
Based on the phenylmercuric neodecanoate and phenylenediamine -meta content, this product is not expected to be readily biodegradable
according to OECD/EC guidelines. May cause long-term adverse effects in the aquatic environment.
ACUTE FISH TOXICITY
Based on the individual component data, is expected to have experimental EC50 values less than 1 mg/l in most sensitive species. Very
toxic to aquatic organisms.

13 DISPOSAL CONSIDERATIONS
GENERAL INFORMATION
All cleaning activities including cleaning of equipment, floors and containers, can produce large volumes of contaminated waste. All
cleaning agents used are potentially polluting. Water containing detergents, degreasers or any other cleaning agents must not be allowed
to enter the surface water drains or soakaways. All water based cleaning/degreasing operations should be carried out in designated areas
away from the surface water system and drained to the foul water system. Where this is not possible the surface water system should be
isolated by suitable damming techniques and the contaminated water collected and removed for controlled safe disposal. Where water
immiscible cleaners/degreasers are used for example solvents, the relevant product safety data sheet should be referred to for information
on safe disposal.
DISPOSAL METHODS
GENERAL
Do not allow into drains or watercourses or dispose of where ground or surface waters may be affected. Controlled wastes include
non-hazardous industrial and hazardous chemical wastes. All controlled wastes should be disposed of in accordance with regulations made
under the Control of Pollution Act and the Environmental Protection Act. When in doubt, using information provided in this safety data
sheet, advice should be obtained from the National regulating agency whether the Hazardous Waste Regulations apply. Refer to
information sources listed in Section 16.
COMPONENT DISPOSAL
TRANSIT PACKAGING: shrink or stretch wrap, boxes and fittings that have not been contaminated with product should be re-used or
recycled. UNREACTED PRODUCT: and empty uncleaned containers should be disposed of as controlled wastes. REACTED PRODUCT:
contaminated mixing boards, spatulas, applicators, brushes, nominally empty containers and mixing bowls -as this product contains
heavy metals- should be disposed of as controlled wastes.
WASTE CLASS
European Waste Catalogue (EWC) code: 08 01 11
The EWC code quoted in this section is a general entry. EWC codes should be assigned based on the end use of the product. Where a
more specific code is available it should be used in preference to the code given above. Where in doubt refer to the List of Wastes, your
local licensed waste contractor or the National regulating agency. Refer to information sources listed in Section 16.

14 TRANSPORT INFORMATION

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GENERAL

Transport classification: labelling and packaging requirements may vary with pack and load size. Please
refer to the current transport regulations.
Transport within user's premises: always transport in closed containers that are upright and secure.
Ensure that persons transporting the product know what to do in the event of accident or spillage.

PROPER SHIPPING NAME

Environmentally hazardous substance, liquid, n.o.s. (containing Phenylmercuric neodecanoate mixture)

ROAD TRANSPORT NOTES

Transport category 3

UN NO. ROAD

3082

ADR CLASS NO.

ADR PACK GROUP

III

UN NO. SEA

3082

IMDG CLASS

IMDG PACK GR.

III

MARINE POLLUTANT

Yes.

UN NO. AIR

3082

AIR CLASS

AIR PACK GR.

III

15 REGULATORY INFORMATION
LABELLING

Dangerous for the

environment

Harmful

CONTAINS

POLYETHER POLYOL
PHENYLENEDIAMINE -meta
PHENYLMERCURIC NEODECANOATE

RISK PHRASES
R22

Harmful if swallowed.

R43

May cause sensitisation by skin contact.

R48/21/22

Harmful: danger of serious damage to health by prolonged exposure in contact with skin
and if swallowed.

R50/53

Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.

R68

Possible risk of irreversible effects.

S23C

Do not breathe fumes/vapour.

S36/37

Wear suitable protective clothing and gloves.

S60

This material and its container must be disposed of as hazardous waste.

S61

Avoid release to the environment. Refer to special instructions/safety data sheets.

SAFETY PHRASES

UK REGULATORY REFERENCES
This product is classified and labelled for supply in accordance with the Chemicals (Hazard Information and Packaging for Supply)
Regulations 2002, as amended.
The provisions of the Health and Safety at Work Act and the Control of Substances Hazardous to Health Regulations apply to the use of
this product at work.
The information contained within this safety data sheet is provided in accordance with Regulation (EC) No. 1907/2006 as amended
concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH).
ENVIRONMENTAL LISTING
The Environmental Protection Act 1990.
The Environment Act 1985.
EU DIRECTIVES
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive
1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive
76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
STATUTORY INSTRUMENTS
Chemicals (Hazard Information and Packaging for Supply) Regulations 2002, as amended (SI 2002: 1689).
Control of Substances Hazardous to Health Regulations 2002, as amended (SI 2002: 2677).
Provision and Use of Personal Protective Equipment Regulations 1992 (SI 1992: 2932).
Special Waste Regulations 1996 (SI 1996: 972), as amended (Scotland Only).
The Confined Spaces Regulations 1997 (SI1997: 1713).
The Hazardous Waste Regulations 2005 (SI2005: 894), as amended.
The List of Wastes Regulations 2005 (SI2005: 895), as amended.
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APPROVED CODE OF PRACTICE
Control of Substances Hazardous to Health (Fifth edition) approved code of practice and guidance.
GUIDANCE NOTES
PPG11: Preventing pollution at industrial sites.
PPG18: Control of Spillages and fire fighting run-off.
HSG97 A step by step guide to COSHH assessment.
HSG193 COSHH essentials: easy steps to control chemicals.
Working with ADR: An introduction to the carriage of dangerous goods by road.
Hazardous Waste: Interpretation of the Definition and Classification of Hazardous Waste (Technical Guidance WM2).

16 OTHER INFORMATION
GENERAL INFORMATION
The information contained within this safety data sheet does not constitute the users own assessment of workplace risks as required by
other health and safety legislation. As the specific conditions of use of the product are outside the supplier's control, the user is responsible
for ensuring that the requirements of relevant National legislation are complied with. The information contained within this safety data sheet
is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental
aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications.
RESTRICTIONS ON USE
The product should not be used for purposes other than those recommended and in addition should be applied in line with the procedures
detailed in the related Instructions For Use (IFU) leaflet.
This product may only be used in 'confined spaces' where a suitable and sufficient assessment has been carried out by a competent
person in accordance with the Confined Spaces Regulations. The assessment should cover the risks involved for all work activities.
INFORMATION SOURCES
Health Surveillance at Work (HSG61) available from HSE Books.
UK ENVIRONMENTAL REGULATING AGENCIES: England and Wales- Environment Agency; Scotland- Scottish Environment Protection
Agency (SEPA); Northern Ireland- Environment and Heritage Service.
REVISION COMMENTS
REVISION. This safety data sheet has been revised in the following Section(s): 14, Please observe the REVISION DATE. Should you be
reading a safety data sheet that is more than 24 months old or have concerns over its validity, please contact your local Belzona
consultant or Belzona direct ([email protected]) and the most current information will be sent to you.
REVISION DATE
06-05-2009
SAFETY DATA SHEET STATUS
English. Approved.
RISK PHRASES IN FULL
R22 Harmful if swallowed. , R23/24/25 Toxic by inhalation, in contact with skin and if swallowed. , R25
Toxic if swallowed. , R34 Causes burns. , R36 Irritating to eyes. , R43 May cause sensitisation by skin
contact. , R48/24/25 Toxic: danger of serious damage to health by prolonged exposure in contact with
skin and if swallowed. , R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment. , R68 Possible risk of irreversible effects.
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