CHEMCAD 6.3.

1 Page 1

Simulation: Ammonia Date: 05/03/2014 Time: [Link]

FLOWSHEET SUMMARY

Equipment Label Stream Numbers

1 COMP 1 -2
2 MIXE 11 2 -3
3 HTXR 3 -4
4 HTXR 5 -6
5 GIBS 4 -5
6 FLAS 6 -7 -9
7 DIVI 7 -10 -8
8 COMP 10 -11


Stream Connections

Stream Equipment Stream Equipment Stream Equipment
From To From To From To
1 1 5 5 4 9 6
2 1 2 6 4 6 10 7 8
3 2 3 7 6 7 11 8 2
4 3 5 8 7


CHEMCAD 6.3.1 Page 2

Simulation: Ammonia Date: 05/03/2014 Time: [Link]

Calculation mode : Sequential
Flash algorithm : Normal

Equipment Calculation Sequence
1 2 3 5 4 6 7 8

Equipment Recycle Sequence
2 3 5 4 6 7 8


Recycle Cut Streams
11


Recycle Convergence Method: Direct Substitution

Max. loop iterations 1000

Recycle Convergence Tolerance

Flow rate 1.000E-003
Temperature 1.000E-003
Pressure 1.000E-003
Enthalpy 1.000E-003
Vapor frac. 1.000E-003

Recycle calculation has converged.


CHEMCAD 6.3.1 Page 3

Simulation: Ammonia Date: 05/03/2014 Time: [Link]

Overall Mass Balance lbmol/h lb/h
Input Output Input Output
Nitrogen 100.000 6.403 2801.400 179.377
Hydrogen 300.000 17.976 604.740 36.235
Carbon Dioxide 100.000 100.247 4401.000 4411.872
Ammonia 0.000 188.471 0.000 3209.858

Total 500.000 313.097 7807.140 7837.341


CHEMCAD 6.3.1 Page 4

Simulation: Ammonia Date: 05/03/2014 Time: [Link]

Overall Energy Balance MMBtu/h
Input Output
Feed Streams -16.9265
Product Streams -22.7344
Total Heating 32.3054
Total Cooling -41.2299
Power Added 3.17456
Power Generated 0

Total -22.6764 -22.7344

CHEMCAD 6.3.1 Page 5

Simulation: Ammonia Date: 05/03/2014 Time: [Link]

COMPONENTS
ID # Name Formula
1 46 Nitrogen N2
2 1 Hydrogen H2
3 49 Carbon Dioxide CO2
4 63 Ammonia H3N


THERMODYNAMICS

K-value model : SRK
Enthalpy model : SRK
Liquid density : Library

Std vapor rate reference temperature is 60 F.
Atmospheric pressure is 14.6959 psi.

SRK Parameters:
Bip = A + B * T + C * T * T T = Temperature in degree K

I J A B C
1 2 0.02100 0.00000 0.00000
1 3 -0.02200 0.00000 0.00000
2 3 0.09400 0.00000 0.00000
2 4 0.11853 0.00000 0.00000
CHEMCAD 6.3.1 Page 6

Simulation: Ammonia Date: 05/03/2014 Time: [Link]
EQUIPMENT SUMMARIES

Compressor Summary

Equip. No. 1 8
Name
Pressure out psia 4000.0000 4000.0000
Type of Compressor 2 2
Efficiency 0.7500 0.7500
Actual power hp 1227.6591 19.9542
Cp/Cv 1.3900 1.5530
Theoretical power hp 802.0355 14.9590
Ideal Cp/Cv 1.3624 1.2667
Calc Pout psia 4000.0000 4000.0000
Calc. mass flowrate 7807 64581
(lb/h)



Mixer Summary

Equip. No. 2
Name
Output Pressure psia 4000.0000



Heat Exchanger Summary

Equip. No. 3 4
Name
1st Stream T Out F 900.0001 80.0000
Calc Ht Duty MMBtu/h 32.3054 -41.2299
LMTD Corr Factor 1.0000 1.0000
1st Stream Pout psia 4000.0000 3970.0000



Gibbs Reactor Summary

Equip. No. 5
Name
Thermal mode 1
Reaction Phase 1
Temperature F 1003.4233
Pressure psia 3970.0000
Overall Heat of Rxn -3.7159
(MMBtu/h)
Inert Component 3



CHEMCAD 6.3.1 Page 7

Simulation: Ammonia Date: 05/03/2014 Time: [Link]
EQUIPMENT SUMMARIES

Flash Summary

Equip. No. 6
Name

K values:
Nitrogen 7.081
Hydrogen 12.106
Carbon Dioxide 0.555
Ammonia 0.146



Divider Summary

Equip. No. 7
Name
Output stream #1 0.9990
Output stream #2 0.0010

CHEMCAD 6.3.1 Page 8

Simulation: Ammonia Date: 05/03/2014 Time: [Link]
STREAM PROPERTIES

Stream No. 1 2 3 4
Name Feed
- - Overall - -
Molar flow lbmol/h 500.0000 500.0000 5011.5342 5011.5342
Mass flow lb/h 7807.1396 7807.1396 72418.5781 72418.5781
Temp F 80.0000 862.7227 151.9864 900.0000
Pres psia 300.0000 4000.0000 4000.0000 4000.0000
Vapor mole fraction 1.000 1.000 1.000 1.000
Enth MMBtu/h -16.926 -13.803 -160.24 -127.93
Tc F -240.1219 -240.1219 -208.3119 -208.3119
Pc psia 772.2456 772.2456 829.0967 829.0967
Std. sp gr. wtr = 1 0.448 0.448 0.426 0.426
Std. sp gr. air = 1 0.539 0.539 0.499 0.499
Degree API 184.3625 184.3625 200.7613 200.7613
Average mol wt 15.6143 15.6143 14.4504 14.4504
Actual dens lb/ft3 0.8092 4.0329 8.2056 3.6497
Actual vol ft3/hr 9647.4492 1935.8833 8825.5078 19842.2852
Std liq ft3/hr 279.1612 279.1612 2723.9226 2723.9226
Std vap 60F scfh 189739.3125 189739.3125 1901770.1250 1901770.1250
- - Vapor only - -
Molar flow lbmol/h 500.0000 500.0000 5011.5342 5011.5342
Mass flow lb/h 7807.1396 7807.1396 72418.5781 72418.5781
Average mol wt 15.6143 15.6143 14.4504 14.4504
Actual dens lb/ft3 0.8092 4.0329 8.2056 3.6497
Actual vol ft3/hr 9647.4492 1935.8833 8825.5078 19842.2852
Std liq ft3/hr 279.1612 279.1612 2723.9226 2723.9226
Std vap 60F scfh 189739.3125 189739.3125 1901770.1250 1901770.1250
Cp Btu/lbmol-F 7.4695 8.3010 9.0195 8.6398
Z factor 0.9996 1.0915 1.0733 1.0855
Visc cP 0.01597 0.03281 0.02091 0.03243
Th cond Btu/hr-ft-F 0.0483 0.1002 0.0625 0.1074
CHEMCAD 6.3.1 Page 9

Simulation: Ammonia Date: 05/03/2014 Time: [Link]
STREAM PROPERTIES

Stream No. 5 6 7 8
Name Purge Stream
- - Overall - -
Molar flow lbmol/h 4823.2227 4823.2227 4514.6406 4.5146
Mass flow lb/h 72418.6328 72418.6328 64646.0000 64.6460
Temp F 1003.4233 80.0000 80.0000 80.0000
Pres psia 3970.0000 3970.0000 3970.0000 3970.0000
Vapor mole fraction 1.000 0.9360 1.000 1.000
Enth MMBtu/h -127.94 -169.17 -146.59 -0.14659
Tc F -179.6352 -179.6352 -204.7303 -204.7304
Pc psia 887.4791 887.4791 836.1565 836.1566
Std. sp gr. wtr = 1 0.442 0.442 0.423 0.423
Std. sp gr. air = 1 0.518 0.518 0.494 0.494
Degree API 188.6149 188.6149 202.7900 202.7900
Average mol wt 15.0146 15.0146 14.3192 14.3192
Actual dens lb/ft3 3.5152 10.2186 9.4030 9.4030
Actual vol ft3/hr 20601.2773 7086.9600 6875.0146 6.8750
Std liq ft3/hr 2624.3469 2624.3469 2446.4124 2.4464
Std vap 60F scfh 1830309.8750 1830309.8750 1713209.6250 1713.2101
- - Vapor only - -
Molar flow lbmol/h 4823.2227 4514.6406 4514.6406 4.5146
Mass flow lb/h 72418.6328 64646.0000 64646.0000 64.6460
Average mol wt 15.0146 14.3192 14.3192 14.3192
Actual dens lb/ft3 3.5152 9.4030 9.4030 9.4030
Actual vol ft3/hr 20601.2773 6875.0146 6875.0146 6.8750
Std liq ft3/hr 2624.3469 2446.4124 2446.4124 2.4464
Std vap 60F scfh 1830309.8750 1713209.6250 1713209.6250 1713.2101
Cp Btu/lbmol-F 8.9978 9.4363 9.4363 9.4365
Z factor 1.0801 1.0440 1.0440 1.0440
Visc cP 0.03404 0.02026 0.02026 0.02026
Th cond Btu/hr-ft-F 0.1105 0.0593 0.0593 0.0593
- - Liquid only - -
Molar flow lbmol/h 308.5826
Mass flow lb/h 7772.6958
Average mol wt 25.1884
Actual dens lb/ft3 36.6731
Actual vol ft3/hr 211.9453
Std liq ft3/hr 177.9346
Std vap 60F scfh 117100.4922
Cp Btu/lbmol-F 19.9450
Z factor 0.4390
Visc cP 0.1077
Th cond Btu/hr-ft-F 0.0933
Surf. tens. dyne/cm 2.3686
CHEMCAD 6.3.1 Page 10

Simulation: Ammonia Date: 05/03/2014 Time: [Link]
STREAM PROPERTIES

Stream No. 9 10 11
Name Product
- - Overall - -
Molar flow lbmol/h 308.5826 4510.1265 4510.1265
Mass flow lb/h 7772.6953 64581.2930 64581.2930
Temp F 80.0000 80.0000 81.3895
Pres psia 3970.0000 3970.0000 4000.0000
Vapor mole fraction 0.0000 1.000 1.000
Enth MMBtu/h -22.588 -146.44 -146.39
Tc F 163.3947 -204.7304 -204.7304
Pc psia 1276.6422 836.1567 836.1567
Std. sp gr. wtr = 1 0.700 0.423 0.423
Std. sp gr. air = 1 0.870 0.494 0.494
Degree API 70.7198 202.7900 202.7900
Average mol wt 25.1884 14.3192 14.3192
Actual dens lb/ft3 36.6731 9.4030 9.4336
Actual vol ft3/hr 211.9452 6868.1401 6845.9106
Std liq ft3/hr 177.9346 2443.9661 2443.9661
Std vap 60F scfh 117100.4844 1711496.6250 1711496.6250
- - Vapor only - -
Molar flow lbmol/h 4510.1265 4510.1265
Mass flow lb/h 64581.2930 64581.2930
Average mol wt 14.3192 14.3192
Actual dens lb/ft3 9.4030 9.4336
Actual vol ft3/hr 6868.1401 6845.9106
Std liq ft3/hr 2443.9661 2443.9661
Std vap 60F scfh 1711496.6250 1711496.6250
Cp Btu/lbmol-F 9.4365 9.4345
Z factor 1.0440 1.0458
Visc cP 0.02026 0.02033
Th cond Btu/hr-ft-F 0.0593 0.0595
- - Liquid only - -
Molar flow lbmol/h 308.5826
Mass flow lb/h 7772.6953
Average mol wt 25.1884
Actual dens lb/ft3 36.6731
Actual vol ft3/hr 211.9452
Std liq ft3/hr 177.9346
Std vap 60F scfh 117100.4844
Cp Btu/lbmol-F 19.9452
Z factor 0.4390
Visc cP 0.1077
Th cond Btu/hr-ft-F 0.0933
Surf. tens. dyne/cm 2.3686

CHEMCAD 6.3.1 Page 11

Simulation: Ammonia Date: 05/03/2014 Time: [Link]
FLOW SUMMARIES:

Stream No. 1 2 3 4
Stream Name Feed
Temp F 80.0000* 862.7227 151.9864 900.0000
Pres psia 300.0000* 4000.0000 4000.0000 4000.0000
Enth MMBtu/h -16.926 -13.803 -160.24 -127.93
Vapor mass frac. 1.0000 1.0000 1.0000 1.0000
Total lbmol/h 500.0000 500.0000 5011.5342 5011.5342
Total lb/h 7807.1396 7807.1396 72418.5781 72418.5781
Total std L ft3/hr 279.1611 279.1611 2723.9225 2723.9225
Total std V scfh 189739.31 189739.31 1901770.13 1901770.13
Flowrates in lb/h
Nitrogen 2801.3999 2801.3999 19638.3184 19638.3184
Hydrogen 604.7400 604.7400 6052.3022 6052.3022
Carbon Dioxide 4401.0000 4401.0000 39884.4766 39884.4766
Ammonia 0.0000 0.0000 6843.4790 6843.4790

Stream No. 5 6 7 8
Stream Name Purge Stream
Temp F 1003.4233 80.0000 80.0000 80.0000
Pres psia 3970.0000 3970.0000 3970.0000 3970.0000
Enth MMBtu/h -127.94 -169.17 -146.59 -0.14659
Vapor mass frac. 1.0000 0.89267 1.0000 1.0000
Total lbmol/h 4823.2227 4823.2227 4514.6406 4.5146
Total lb/h 72418.6328 72418.6328 64646.0000 64.6460
Total std L ft3/hr 2624.3469 2624.3469 2446.4124 2.4464
Total std V scfh 1830309.88 1830309.88 1713209.63 1713.21
Flowrates in lb/h
Nitrogen 17000.6445 17000.6445 16838.1074 16.8381
Hydrogen 5482.9063 5482.9063 5452.1230 5.4521
Carbon Dioxide 39884.4766 39884.4766 35508.1133 35.5081
Ammonia 10050.6055 10050.6055 6847.5952 6.8476

Stream No. 9 10 11
Stream Name Product
Temp F 80.0000 80.0000 81.3895
Pres psia 3970.0000 3970.0000 4000.0000
Enth MMBtu/h -22.588 -146.44 -146.39
Vapor mass frac. 0.00000 1.0000 1.0000
Total lbmol/h 308.5826 4510.1265 4510.1265
Total lb/h 7772.6953 64581.2930 64581.2930
Total std L ft3/hr 177.9346 2443.9660 2443.9660
Total std V scfh 117100.48 1711496.63 1711496.63
Flowrates in lb/h
Nitrogen 162.5385 16821.2676 16821.2676
Hydrogen 30.7831 5446.6709 5446.6709
Carbon Dioxide 4376.3643 35472.6055 35472.6055
Ammonia 3203.0100 6840.7476 6840.7476

CHEMCAD 6.3.1 Page 12

Simulation: Ammonia Date: 05/03/2014 Time: [Link]
FLOW SUMMARIES:

Stream No. 1 2 3 4
Stream Name Feed
Temp F 80.0000* 862.7227 151.9864 900.0000
Pres psia 300.0000* 4000.0000 4000.0000 4000.0000
Enth MMBtu/h -16.926 -13.803 -160.24 -127.93
Vapor mole frac. 1.0000 1.0000 1.0000 1.0000
Total lbmol/h 500.0000 500.0000 5011.5342 5011.5342
Total lb/h 7807.1396 7807.1396 72418.5781 72418.5781
Total std L ft3/hr 279.1611 279.1611 2723.9225 2723.9225
Total std V scfh 189739.31 189739.31 1901770.13 1901770.13
Flowrates in lbmol/h
Nitrogen 100.0000 100.0000 701.0180 701.0180
Hydrogen 300.0000 300.0000 3002.4319 3002.4319
Carbon Dioxide 100.0000 100.0000 906.2595 906.2595
Ammonia 0.0000 0.0000 401.8249 401.8249

Stream No. 5 6 7 8
Stream Name Purge Stream
Temp F 1003.4233 80.0000 80.0000 80.0000
Pres psia 3970.0000 3970.0000 3970.0000 3970.0000
Enth MMBtu/h -127.94 -169.17 -146.59 -0.14659
Vapor mole frac. 1.0000 0.93602 1.0000 1.0000
Total lbmol/h 4823.2227 4823.2227 4514.6406 4.5146
Total lb/h 72418.6328 72418.6328 64646.0000 64.6460
Total std L ft3/hr 2624.3469 2624.3469 2446.4124 2.4464
Total std V scfh 1830309.88 1830309.88 1713209.63 1713.21
Flowrates in lbmol/h
Nitrogen 606.8624 606.8624 601.0604 0.6011
Hydrogen 2719.9653 2719.9653 2704.6943 2.7047
Carbon Dioxide 906.2595 906.2595 806.8193 0.8068
Ammonia 590.1359 590.1359 402.0665 0.4021

Stream No. 9 10 11
Stream Name Product
Temp F 80.0000 80.0000 81.3895
Pres psia 3970.0000 3970.0000 4000.0000
Enth MMBtu/h -22.588 -146.44 -146.39
Vapor mole frac. 0.00000 1.0000 1.0000
Total lbmol/h 308.5826 4510.1265 4510.1265
Total lb/h 7772.6953 64581.2930 64581.2930
Total std L ft3/hr 177.9346 2443.9660 2443.9660
Total std V scfh 117100.48 1711496.63 1711496.63
Flowrates in lbmol/h
Nitrogen 5.8020 600.4594 600.4594
Hydrogen 15.2709 2701.9897 2701.9897
Carbon Dioxide 99.4402 806.0125 806.0125
Ammonia 188.0694 401.6645 401.6645

CHEMCAD 6.3.1 Page 13

Simulation: Ammonia Date: 05/03/2014 Time: [Link]
Heating Curves Summary

Eqp # 3 Unit type : HTXR Unit name:

Stream 3

NP Temp Pres Del H Vapor Liquid Vap mole Vap mass
F psia MMBtu/h lb/h lb/h frac. frac.
1 152.0 4000.0 0.000 72419 0 1.0000 1.0000
2 224.4 4000.0 3.23 72419 0 1.0000 1.0000
3 298.1 4000.0 6.46 72419 0 1.0000 1.0000
4 372.8 4000.0 9.69 72419 0 1.0000 1.0000
5 448.0 4000.0 12.9 72419 0 1.0000 1.0000
6 523.5 4000.0 16.2 72419 0 1.0000 1.0000
7 599.1 4000.0 19.4 72419 0 1.0000 1.0000
8 674.7 4000.0 22.6 72419 0 1.0000 1.0000
9 750.1 4000.0 25.8 72419 0 1.0000 1.0000
10 825.2 4000.0 29.1 72419 0 1.0000 1.0000
11 900.0 4000.0 32.3 72419 0 1.0000 1.0000

Eqp # 4 Unit type : HTXR Unit name:

Stream 5

NP Temp Pres Del H Vapor Liquid Vap mole Vap mass
F psia MMBtu/h lb/h lb/h frac. frac.
1 1003.4 3970.0 0.000 72419 0 1.0000 1.0000
2 897.4 3970.0 4.58 72419 0 1.0000 1.0000
3 790.6 3970.0 9.16 72419 0 1.0000 1.0000
4 683.1 3970.0 13.7 72419 0 1.0000 1.0000
5 575.2 3970.0 18.3 72419 0 1.0000 1.0000
6 467.4 3970.0 22.9 72419 0 1.0000 1.0000
7 360.3 3970.0 27.5 72419 0 1.0000 1.0000
8 254.9 3970.0 32.1 72419 0 1.0000 1.0000
9 152.6 3970.0 36.6 72419 0 1.0000 1.0000
10 99.7 3970.0 39.1 72419 0 1.0000 1.0000 Dew
11 80.0 3970.0 41.2 64646 7773 0.9360 0.8927