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1. Nitrogen (I) oxide is produced by the thermal decomposition of ammonium nitrate and the interaction of hydroxyl amine with nitrous acid. 2. Carborundum is obtained when silica is heated at high temperature with carbon. 3. Silver nitrate does not give NO2 on heating.

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Uday Prakash Sahu
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142 views

P Block

1. Nitrogen (I) oxide is produced by the thermal decomposition of ammonium nitrate and the interaction of hydroxyl amine with nitrous acid. 2. Carborundum is obtained when silica is heated at high temperature with carbon. 3. Silver nitrate does not give NO2 on heating.

Uploaded by

Uday Prakash Sahu
Copyright
© Attribution Non-Commercial (BY-NC)
Available Formats
Download as PDF, TXT or read online on Scribd
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p-BLOCK ELEMENTS

Q.1 Nitrogen (I) oxide is produced by(i) Thermal decomposition of ammonium nitrate (ii) Disproportionation of N2 O4 (iii) Thermal decomposition of ammonium nitrite (iv) Interaction of hydroxyl amine with nitrous acid (A) i, iv (B) ii, iv (C) i, ii (D) iii,iv

Q.2 Carborundum is obtained when silica is heated at high temperature with(A) Carbon (C) Carbon dioxide (B) Carbon monoxide (D) Calcium carbonate

Q.3 Which of the following does not give NO2 on heating ? (A) KNO3 (B) Pb(NO3 )2 (C) Cu(NO3 )2 (D) AgNO3

Q.4 The bonds present in N2 O5 are(A) Only ionic (C) Only covalent (B) Covalent and coordinate (D) Covalent ionic

Q.5 Concentrated HNO3 reacts with iodine to give(A) HI (B) HOI (C) HOIO2 (D) HOIO3

Q.6 Nitrogen is liberated by the thermal decomposition of only(A) NH4 NO2 (B) NaN 3 (C) (NH4 )2 Cr2 O7 (D) All the three

Q.7 Which one of the following oxides is neutral ? (A) CO (B) SnO2 (C) ZnO (D) SiO2

Q.8 The correct order of increasing C O bond length of CO, CO3 2 , CO2 is(A) CO3 2 < CO2 < CO (C) CO < CO3 2 < CO2 Q.9 [X] + H2 SO4
?? ?

(B) CO2 < CO3 2 < CO (D) CO < CO2 < CO3 2

[Y] a colourless gas with irritating smeel


?? ?

[Y] + K2 Cr2 O7 + H2 SO4 (A) SO3 2 , SO2 Q.10 H3 BO3 is :

green solution. [X] and [Y] are (C) S2 , H2 S (D) CO3 2 , CO2

(B) Cl , HCl

(A) Monobasic and weak Lewis acid (B) Monobasic and weak Bronsted acid (C) Monobasic and strong Lewis acid (D) Tribasic and weak Bronsted acid

ANSWER KEY
Q.No. Ans. 1 A 2 A 3 A 4 B 5 C 6 D 7 A 8 D 9 A 10 A

SOLUTIONS (p-BLOCK ELEMENTS)


? Ans.1 NH4 NH3 (aq) ? ?? ? N2 O + 2H2 O

? ? N2 O + 2H2 O NH2 OH + HNO2 ? ?


(Electric furnace) Ans.2 SiO2 + 3C ? ?Heat ? ? ? ? ? ? ? ? ? SiC + 2CO? ? Ans.3 2KNO3 ? ?? ? 2KNO2 + O2 .

Ans.4

Ans.5

? ? H2 O + 2NO3 + [O]] 5 [2HNO3 ? ? ? ? I 2 O5 I 2 + 5[O] ? ? ? ? 2HIO3 I 2 O5 + H2 O ? ? ? ? 4H2 O + 10NO2 + 2HIO3 10HNO3 + I 2 ? ?

Ans.6 All the three compounds liberate nitrogen on heating


? NH4 NO2 ? ?? ? N2 ? + 2H2 O 2NaN 3 ? ?574K ? ? ? 2Na + 3N2 ? ? (NH4 )2 Cr2 O7 ? ?? + 4H2 O? ? Cr2 O3 + N2 ? ?

Ans.7 CO is a neutral oxide of C. SnO2 and ZnO are amphoteric while SiO2 is acidic in nature. Ans.8 CO contains carbon-oxygen triple bond. CO2 contains carbon-oxygen double bonds and CO3 2 contains carbon-oxygen bond which is a resonance hybride of single and double bond. Therefore, CO bond length increases in order of CO < CO2 < CO3 2 . Ans.9 The pair is SO3 2 and SO2 .
? ? SO2 + H2 O + SO4 2 SO3 2 + H2 SO4 ? ?
(x) (y) (y)

? ? Cr2 (SO4 )3 + K2 SO4 + H2 O 3SO2 + K2 Cr2 O7 + H2 SO7 ? ?


(Green colour)

Ans.10 Boric acid acts as a weak monobasic acid by accepting a lone pair of electrons from OH ion, thereby, acting as a Lewis acid.

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