Methanol For Growth
Methanol For Growth
[11]
Patent Number:
5,981,441
Nov. 9, 1999
[45]
Date of Patent:
OTHER PUBLICATIONS
[57]
ABSTRACT
A method for improving the groWth characteristics of plants of the C3 and CAM varieties comprises applying to the roots
of the plants an aqueous solution containing methanol together With a high nitrogen fertilizer. The fertilizer com prises an NPK fertilizer having a high nitrogen content, preferably a 24-6-6 value, in Which the nitrogen component
[58]
[56]
References Cited
U.S. PATENT DOCUMENTS
P.P. 2,716 2/1967
3/1976
P.P. 2,777
P.P. 3,836
11/1967 Fitzgerald
3/1986 Germaske .
10/1969 10/1975 Miller Miller .............. ..
Greatly improved groWth characteristics have been demon strated in comparative experimental tests With a large variety
P.P. 5,688
3,472,647 3,915,686
Plt./87.3
.... .. 71/122 504/353
5,597,400
5,642,586
71/28
25 Claims, N0 Drawings
5,981,441
1
USE OF METHANOL FOR IMPROVING PLANT GROWTH
CROSS REFERENCE TO RELATED APPLICATION
2
to promote plant groWth. According to the present invention,
a methanol-enhanced aqueous solution of a high nitrogen
This is a continuation-in-part of application Ser. No. 08/886,058, ?led Jun. 30, 1997, noW abandoned, Which is a
improvements in many groWth characteristics of C3 plants. Moreover, such plant groWth improvement has been pro duced in a variety of C3 plant species including fruits, vegetables, trees and ?oWering plants. Improved groWth in
CAM variety plants also has been demonstrated.
10
plant roots.
BACKGROUND OF THE INVENTION
20
and a nitrogen-phosphorus-potassium (NPK)-based fertiliZer having a high nitrogen content. The invention is based on a recognition of the role of nitrogen When using methanol for groWth enhancement. The source of the nitro gen used in the methanol-enhanced fertiliZer component is
critical. There are a variety of available nitrogen-based chemicals used in fertiliZers. These include urea Which is broken doWn sloWly during use. Urea as a source of nitrogen
is substantially avoided in the present invention. The pre ferred nitrogen source is a fast-acting nitrogen component selected from the group Which includes nitrate ions and ammonium ions. Preferably, the nitrogen source is provided
principally by ammonium nitrate, ammonium phosphate and potassium nitrate. The ammonium phosphate and potassium nitrate components also provide the phosphorus and potas
30
aqueous solution containing methanol and a high nitrogen fertiliZer applied to the plant roots of a large number of
sium components of the NPK fertiliZer formulation. The preferred high nitrogen fertiliZer has an NPK ratio
in the range from about 3.5:1:1 to about 8:1:1, With the
detail beloW, demonstrates remarkable enhanced groWth characteristics for a large number of C3 and CAM plant
varieties.
DETAILED DESCRIPTION
40
My U.S. Pat. No. 5;642,586, Which is incorporated herein by this reference, describes development of a method for
fertiliZer solution and applied to orchid plant roots by saturating the ?r bark groWing media. No damage or toxic effects to the plant Were observed by repeated application to
50
the same plant. Subsequently, a solution of 0.17% methanol With half strength standard fertiliZer knoWn as DynaGro
Arecent article by McGiffen, Jr., M. E. and J. A. Manthey, The Role of Methanol and Promoting Plant GroWth: A
doubled (1/z tsp/gal) and subsequently plants Were treated With full strength fertiliZer With increasing percentages of
alcohol up to 5% methanol, Without any short term toxic effects. Results shoWed that the methanol treatment
productivity; and that although the methods have not been consistent across all of the studies, investigations that dupli cated Nonomura and Bensons procedures failed to ?nd consistent increases in crop yield. McGiffen et al. concluded that additional ?eld experiments that simply repeat Nono
mura and Bensons protocol are unlikely to provide neW
improved the ?oWering, shoot groWth and glossiness of the foliage and enhanced the blooming period Which took place
60
over 19 months time as opposed to a typical period of three to four years for orchid plants of the same siZe When no methanol treatment is applied. It has been concluded that up to 2% methanol added to the standard fertiliZer/Water for mulation (5 to 10 cc fertiliZer per four liters (approximately
insights, and that the foliar application of methanol is unlikely to become a practical yield enhancer. The present invention is based on the recognition that,
contrary to the McGiffen et al. study, methanol can be used
groWth.
As mentioned, the NPK ratio of the DynaGro
fertiliZer that I had previously used on the orchid plants Was
5,981,441
3
10-5-5. During the course of experimentation With fertilizers having different NPK values, I added some ammonium nitrate to the fertilizer formulation to increase its nitrogen content. Following months of experimentation With orchid plants, and after adjusting the ratio to 4:1:1 and using a less concentrated solution, optimum groWth characteristics Were
4
the range of about 3.5:1:1 to about 8:1:1. The preferred NPK content is 24-6-6 (4:1:1). The invention requires
use of a fast-acting nitrogen source and avoids use of a
sloW-acting nitrogen source such as urea. In one experiment, an 18% urea fertiliZer added to methanol produced no
ions and nitrate ions, predominantly ammonium nitrate, potassium nitrate and ammonium phosphate. The preference
for using ammonium nitrate is to keep the salt content (from potassium and phosphorous) loW because too much salt can
soluble in Water, the nitrogen component is not immediately available to the plant. Urea is broken doWn sloWly, and it
therefore provides a sloW release nitrogen source used in many commercial fertiliZers as a fraction of the nitrogen source to lengthen the time release of nitrogen available to
15
burn the leaves of the plant. The preferred ratio of potassium to phosphorous in the formulation is about 1:1 although
variations in the range from about 2:1 to 1:2 are possible.
The presently preferred methanol/fertilizer formulation comprises one part by volume 24-6-6 fertiliZer, tWo parts by
20
the plant.
Carbon dioxide is the most common source of carbon and
volume Water, and one part by volume methanol. The methanol is a 100% solution (containing no Water). The
plants use this gas along With Water, fertiliZer and light to
24-6-6 fertiliZer blend is initially prepared by mixing granu lar ammonium nitrate, ammonium phosphate and potassium
nitrate in the previously described 24-6-6 amount on a
dehyde and then to various sugars. Supplementing standard fertiliZers With methanol increases plant groWth in some instances because there is usually some extra nitrogen available. HoWever, the form of the nitrogen may not be
optimal When methanol is used in combination With a fertiliZer. There are a variety of nitrogen-based chemicals used in fertiliZers. In the Nonomura et al. article described previously, methanol Was added to a urea-based nitrogen source. On the other hand, nitrate ions (not available from
11.5% nitrate nitrogen and 12.5% ammoniacal nitrogen. There is 6% available phosphorus (P205) and 6% potassium (K20). Minor elements (all chelated consist of iron (0.2%),
and cobalt (0.005%)). The granular mixture dissolves in the Water/methanol blend. The preferred ratio of methanol to fertiliZer is one part granular fertiliZer to one part methanol, by volume, to produce a basic groWth formulation. The ratio
of methanol to fertiliZer can be up to about tWo parts
35
urea) are immediately available to plants, and ammonium ions are converted rapidly by bacteria to the nitrate form.
Standard fertiliZers typically include a substantial per
centage of urea. In addition, there are some ammonium and nitrate components. The reason for these mixtures is to
40
blooms during the September to February groWth cycles for orchids. Each plant variety has its oWn blooming period. Comparative studies evaluated the 24-6-6 methanol/high
nitrogen formulation of this invention compared to use of the methanol/fertilizer formulation described in my 586 patent, in Which the methanol Was blended With the Dyna Gro (10-5-5) fertiliZer formulation. Both formulations Were applied to the roots of similar orchid plants in the same
amounts and over the same time intervals. The results
45
supply the nitrate ions rapidly to the plant. Then the urea is
Methanol is metaboliZed rapidly and if not used it Will evaporate from the soil. An important aspect of the fertiliZer formulation of this
invention is the NPK value. There are many fertiliZer
shoWed that the methanol-enhanced high nitrogen fertiliZer of this invention produced faster root groWth, higher ?oWer production With larger ?oWer and richer colors, more than doubling of most plant groWth, prevention of unfavorable decomposition of the ?r bark groWth media, production of
50
shinny fat pseudobulbs and shinier leaves, and improved plant groWth in higher temperatures, increased light levels
and loWer humidity environments. The present invention has been expanded beyond orchids to a large variety of C3 and CAM plants, and in all instances
keep the total amount of salt reasonably loW since plants are sensitive to salt concentration. Thus, to keep the salt con centration loW While having a high concentration of nitrogen, the P and K concentrations are kept relatively loW.
The NPK value of 24-6-6 has been tested on a large
55
variety of C3 and CAM plants and thus far none of the plants tested has suffered from a de?ciency of potassium or phos phorous. Contrary to the conclusions of the McGiffen et al. article described previously, I have discovered that methanol
added to a fertiliZer solution and applied to the roots of C3 and CAM plants, in addition to orchids, can produce a Wide
60
groWth characteristics of orchids of both the C3 and CAM families. C4 plants have photosynthetic rates up to three times higher than C3 plants and are located in high light
5,981,441
5
the temperature, different grasses can be either C3 or C4. For example, the cool growing grasses are C3 and the Warmer growing ones are C4. Most of the temperate plants are either
6
of this invention. The groWth characteristics Were compared using the fertiliZer of this invention compared to the use of
DynaGro (10-5-5).
EXAMPLE
cantaloupe, raspberry, straWberry, Watermelon, beans, daylily, ferns, canna, lantana, Japanese maple, gardenia,
pepper, lettuce, rose, tomato, cyclamen, dahlia, petunia, African violet, vinca, pansy, quince, clematis, papyrus,
Chinese lantern, Iceland poppy, marigold, and stock.
Improved results for some of these plants are described beloW. One dramatic example of improved results Was an orange tree Which had almost all yelloW leaves for four years and simply did not groW. After one application of the fertiliZer of this invention, neW shoots appeared all over the branches
Within about one Week. The leaves are noW deep green, and an abundance of oranges on the tree Were produced by the
10
This example summariZes a study of the 24-6-6 high nitrogen/methanol fertiliZer of the present invention by an
independent expert.
TWenty four seedling Phalaenopsis plants Were divided by
random selection into four groups of six each. Each plant
Was Weighed on an Ohaus Harvard beam balance of labo
15
ratory grade. By random selection four plants Were potted in straight long-?ber sphagnum and tWo plants in O&F mix (50/50#3 charcoal and #3 sponge rock) to Which Vs by
volume MetroMix 200 Was added in each set of six. Plants
Were potted in typical bloW mold sixpacks of nominal 3.5-inch pot siZe. The methanol/high nitrogen fertiliZer Was
mixed in one gallon batches of one, tWo and three teaspoons
20
continued periodic application of the fertiliZer to the roots of the tree. The results of the present invention With respect to
citrus trees contradicts the conclusions of the McGiffen et al.
per gallon strength With distilled Water used as makeup for one gallon volume. Plants Were labeled for application of
each strength and one tray Was tagged as control to receive normal treatment.
article, referred to previously, Which states that methanol does not improve the groWth characteristics of citrus trees. Anumber of flowers groWn With the 24-6-6 high nitrogen/ methanol solution of this invention Were compared With methanol-enhanced fertiliZers from Miracle Gro and Peters.
The result shoWed that the higher concentration of urea as a
34 inches, light intensity Was 3742 fc at midday, and greenhouse temperature reached a maximum of 82 F, but
had an ambient loW temperature of 74 F. Normal care for
nitrogen source, the less the bene?t that methanol exhibits. In one experimental test, a high nitrogen fertiliZer
Phalaenopsis seedlings is 200 ppm NPK fertiliZer every ten days With a soft Water ?ush the fourth day after feeding.
30
Plants Were Watered one day and fed the next day on a
(approximately 24-6-6) Was applied to the plant roots of orchids in the absence of methanol. The high nitrogen content resulted in killing the plants.
Aug. 9, 1997, and terminated Oct. 13, 1997, at Which time all plants Were removed from pots, carefully cleaned and
Weighed. The results Were as folloWs:
Other orchid plants have been the subject of comparative tests utiliZing the high nitrogen fertiliZer/methanol solution of this invention compared With similar plants utiliZing
DynaGro (10-5-5) and the same amount of methanol.
POT ID - MEDIUM
40 A: CONTROL GROUP
g g g g
g g g g
observable decomposition of root bark groWth medium; greater light toleranceplants groW better in 50% more
5.7 g 7.6 g
10.1 g 12.2 g
Total Weight:
47.3 g B: 1 TSP/GAL
g g g g
g g g g
use of a DynaGro (10-5-5) fertiliZer mixed With the same F-O&F amount of methanol: tomato (larger stems, more compact 55 Total Gain: 26.9 g
5.4 g 7.5 g
5.8 g 11.4 g
Total Weight:
45.6 g C: 2 TSP/GAL
g g g g
15.9 g 17.4 g
Total Weight:
49.9 g D: 3 TSP/GAL
(almost double the plant siZe, many more blooms) and tomato (much larger plants, many more blooms) groWn side by side in a ?eld shoWed much improved groWth charac teristics With the high nitrogen fertiliZer/methanol solution
A-Sphagnum
9.1 g
10.2 g
5,981,441
8
-continued
B-Sphagnum C-Sphagnum D-Sphagnum
E-O&F F-O&F
methanol together With a fertilizer and repeating the appli cation at intervals during the groWth cycle of the plant, in Which the fertilizer comprises an NPK fertilizer having a high nitrogen content in Which the nitrogen component comprises from about 3.5 to about 8 times the potassium
Total Weight:
50.5 g
RECAP OF RESULTS
component and the phosphorous component, by Weight, and in Which the nitrogen component is provided by ammonium
ions and nitrate ions substantially in the absence of urea. 7. The method according to claim 6 in Which the
10
GROUP
A-CONTROL GROUP B-ONE TSP/GAL C-TWO TSP/GAL D-THREE TSP/GAL
Start Wt.
47.3 45.6 45.4 50.5 g g g g
End Wt.
62.2 72.5 49.9 78.1 g g g g
Gain (g)
14.9 26.9 95.3 27.6 g g g g
Gain (%)
31.5 59.0 91.0 54.7
15
the methanol fertilizer solution to the roots of C3 and/or CAM plants and trees selected from the group consisting of
20
methanol/high nitrogen fertilizer Was retained from each application and put on miscellaneous plants in a laboratory
growing area. Some of the plants Were inside but most Were
citrus, cantaloupe, raspberry, straWberry, Watermelon, beans, daylily, fern, canna, lantana, Japanese maple, gardenia,
pepper, lettuce, rose, tomato, cyclamen, dahlia, African
11. The method according to claim 6 in Which the components of the fertilizer principally comprise ammo
Weight.
13. A method of improving the groWth characteristics of plants of the C3 and CAM varieties comprising applying to
the roots of the plants an aqueous solution consisting essen
high rate of groWth. It Would also offer some insight into the demonstrated trait of greater heat tolerance as the plants
Would be venting gaseous Water and heat as a by-product of rapid starch sugar energy conversion cycles. The summer groWing months Were hot and dry, and it appears that the
35
tially of methanol and a fertilizer, and repeating the appli cation at intervals during the groWth cycle of the plant, in Which the fertilizer comprises an NPK fertilizer having
a high nitrogen content in the range from about 3.5:1:1 to
about 8: 1:1, by Weight, and in Which the nitrogen component is provided predominantly by ammonium ions and nitrate
40
plants became more heat tolerant through the application of the 24-6-6 high nitrogen/methanol formulation.
I claim:
ions and substantially in the absence of urea. 14. The method according to claim 13 in Which the
1. A high nitrogen/methanol fertilizer for improving the groWth characteristics of plants of the C3 and CAM varieties
When applied to the roots of the plant, comprising an aqueous solution containing methanol and a high nitrogen NPK fertilizer in Which the nitrogen content comprises
from about 3.5 to about 8 times the amount of available
45
17. The method according to claim 13 comprising apply ing the methanol fertilizer solution to the roots of C3 and/or CAM plants and trees selected from the group consisting of
citrus, cantaloupe, raspberry, straWberry, Watermelon, beans, daylily, ferns, canna, lantana, Japanese maple, gardenia,
55
pepper, lettuce, rose, tomato, cyclamen, dahlia, African violets, vinca, pansy, quince, clematis, papyrus, Chinese lantern, Iceland poppy, marigold and stock.
18. The method according to claim 13 in Which the components of the fertilizer principally comprise ammo
phosphorous to potassium comprises about 24-6-6. 4. The high nitrogen/methanol fertilizer according to
claim 2 in Which the ratio of methanol to fertilizer is about 1:1 to 2:1 by volume.
60
by Weight.
20. A method of improving the groWth characteristics of plants of the C3 and CAM varieties comprising applying to
65
nium phosphate.
6. A method of improving the groWth characteristics of plants of the C3 and CAM varieties comprising applying to
the roots of the plants an aqueous solution containing
nol together With a fertilizer, and repeating the application at intervals during the groWth cycle of the plant, in Which the
5,981,441
9
fertilizer comprises an NPK fertilizer having a high nitrogen content in the range from about 3.5 to about 8 times
10
23. The method according to claim 20 in Which the ratio of methanol to fertilizer is about 1:1 to 2:1 by volume.
provided substantially in its entirety from ammonium nitrate, nitrate ions from potassium nitrate, and ammonium ions from ammonium phosphate, substantially in the
absence of urea, in Which the phosphorous component
24. The method according to claim 20 comprising apply ing the methanol/high nitrogen fertilizer solution to the roots of C3 and/or CAM plants and trees selected from the group
principally comprises the ammonium phosphate, and in Which the potassium component principally comprises the potassium nitrate.
21. The method according to claim 20 in Which the NPK content of nitrogen to phosphorous to potassium comprises about 24-6-6. 22. The method according to claim 21 in Which the ratio
of methanol to fertilizer is about 1:1 to about 2:1 by volume.
consisting of citrus, cantaloupe, raspberry, straWberry, Watermelon, beans, daylily, ferns, canna, lantana, Japanese maple, gardenia, pepper, lettuce, rose, tomato, cyclamen, dahlia, African violets, vinca, pansy, quince, clematis,
10
by Weight.