Dust explosionsCases, causes, consequences, and control

Tasneem Abbasi, S.A. Abbasi

Center for Pollution Control and Energy Technology, Pondicherry University, Pondicherry 605014, India
Received 26 June 2006; received in revised form 3 November 2006; accepted 6 November 2006
Available online 10 November 2006
Abstract
Dust explosions pose the most serious and widespread of explosion hazards in the process industry alongside vapour cloud explosions (VCE)
and boiling liquid expanding vapour explosions (BLEVE). Dust explosions almost always lead to serious nancial losses in terms of damage to
facilities and down time. They also often cause serious injuries to personnel, and fatalities.
We present the gist of the dust explosion state-of-the-art. Illustrative case studies and past accident analyses reect the high frequency, geographic
spread, and damage potential of dust explosions across the world. The sources and triggers of dust explosions, and the measures with which different
factors associated with dust explosions can be quantied are reviewed alongside dust explosion mechanism. The rest of the review is focused on
the ways available to prevent dust explosion, and on cushioning the impact of a dust explosion by venting when the accident does take place.
2006 Elsevier B.V. All rights reserved.
Keywords: Dust explosion; Flammability; Explosion propagation; Vent design; Suppression; Inerting
Contents
1. Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
1.1. Dusts . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
1.2. Dust explosion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
2. Illustrative case histories of a few major dust explosions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
3. The dust explosion pentagon . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
4. Sources and triggers of dust explosions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
4.1. Operations involving dusts . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
4.2. Classication of dusts . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
4.3. Tests to determine the explosibility of dusts . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
4.4. Safety codes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
4.5. Dust explosion triggers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
4.5.1. Flames and direct heat . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
4.5.2. Self-heating . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
4.5.3. Hot work. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
4.5.4. Incandescent material . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
4.5.5. Hot surfaces . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
4.5.6. Electrostatic sparks . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18
4.5.7. Electrical sparks . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18
4.5.8. Friction sparks and hot spots . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18
4.5.9. Impact sparks . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18
4.5.10. Static electricity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18
4.5.11. Lightening, shock waves . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18

Corresponding author. Tel.: +91 413 2655263.

E-mail address: [email protected] (S.A. Abbasi).
4.6. Domino effect . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
4.6.1. Primary explosions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
4.6.2. Secondary explosions. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
5. Frequency of dust explosions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20
5.1. Historical overview of dust explosion causes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21
6. Dust explosion mechanism . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22
6.1. The dust combustion process . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22
6.2. Role of dust particle size in the combustion process. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23
6.3. Factors inuencing dust explosibility. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24
6.3.1. Particle size . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24
6.3.2. Dust concentration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25
6.3.3. Oxidant concentration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25
6.3.4. Ignition temperature . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25
6.3.5. Role of turbulence . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25
6.3.6. Maximum rate of pressure rise . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26
6.3.7. Admixed inert dust concentration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26
6.3.8. Presence of ammable gases . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26
7. Prevention of dust explosion. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27
7.1. Dust explosion prevention strategies . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27
7.1.1. Process modication . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27
7.1.2. Preventing ammable dust suspensions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27
7.1.3. Elimination of ignition sources . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28
7.1.4. Inerting . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29
7.2. Preventive steps for specic dusts/operations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30
7.2.1. Explosion protection when handling metal dusts [132] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30
7.2.2. Explosion protection when handling carbonaceous dusts [133] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30
7.2.3. Precautions during dust separation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30
8. Dust explosion damage control . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30
8.1. Explosion containment . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31
8.2. Explosion isolation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31
8.3. Explosion suppression . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32
8.4. Explosion venting . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33
8.4.1. Approaches to vent design . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34
8.4.2. Factors inuencing the venting process . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38
8.5. Expert systems. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 40
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 40
1. Introduction
1.1. Dusts
According to BS 2955: 1958 [1,2], materials with particle
size less than 1000 m (16 BS mesh size) are dened as pow-
ders; when particles have a diameter less than 76 m (200 BS
mesh size), they are referred to as dust. As per NFPA [3]
dust is any nely divided solid, 420 m or less in diameter.
Given the nearly six orders-of-magnitude difference between
the sizes stipulated by BS 2955 and NFPA 68, it may be safer
to follow the somewhat wider view of Palmer [4] which does
not exclude from his treatment even particle diameters coarser
than 1000 m [2]. In this write-up we have used the term
dust for all particulate material, irrespective of the particle
size.
More than70%of dusts processedinindustryare combustible
[5]. This implies that majority of industrial plants that have dust-
processing equipment are susceptible to dust explosions.
1.2. Dust explosion
A dust explosion is initiated by the rapid combustion of
ammable particulates suspended in air. Any solid material
that can burn in air will do so with a violence and speed that
increases with the degree of sub-division of the material [6].
Higher the degree of sub-division (in other words smaller
the particle size) more rapid and explosive the burning, till a
limiting stage is reached when particles too ne in size tend
to lump together. If the ignited dust cloud is unconned, it
would only cause a ash re. But if the ignited dust cloud is
conned, even partially, the heat of combustion may result in
rapid development of pressure, with ame propagation across
the dust cloud and the evolution of large quantities of heat and
reaction products. The furious pace of these events results in
an explosion. Besides the particle size, the violence of such
an explosion depends on the rate of energy release due to
combustion relative to the degree of connement and heat
losses. In exceptional situations a destructive explosion can
occur even in an unconned dust cloud if the reactions caused
by combustion are so fast that pressure builds up in the dust
cloud faster than it can be dissipated at the edge of the cloud [7].
The oxygenrequiredfor combustionis mostlysuppliedbyair.
The condition necessary for a dust explosion is a simultaneous
presence of dust cloud of appropriate concentration in air that
will support combustion throughout the process and a suitable
ignition source. In case of dusts made up of volatile substances,
the explosion may occur in three steps which may follow each
other in very quick successiondevolatization (where volatiles
are let off by the particle or the particles are vapourized), gas
phase mixing of fuel (released by dusts) and oxidant (usually
air), and gas phase combustion.
Many combustible dusts if dispersed as a cloud in air and
ignited, will allow a ame to propagate through the cloud in a
manner similar to (though not identical to) the propagation of
ames in premixed fueloxidant gases [8]. Such dusts include
common foodstuffs like sugar our, cocoa, synthetic materials
such as plastics, chemicals and pharmaceuticals, metals such as
aluminumand magnesium, and traditional fuels such as coal and
wood. Generally dust explosion involves oxide formation:
Fuel + oxygen oxide + heat
But metal dusts can also react with nitrogen or carbon dioxide
to generate heat for explosion.
The interdependence of the various parameters which inu-
ence the explosion pressure is described by the equation of state
for ideal gases:
P =
nRT
V
where P is the pressure, V the volume, R the universal gas con-
stant, n the number of moles of gas and T is the temperature.
Other factors being equal, the increase of T due to the heat devel-
oped in the burning dust cloud has the deciding inuence on the
explosion pressure. It follows that higher the heat of combustion
of a given dust per mole of O
2
consumed, greater is the likely
severity of an explosion. Table 1 presents the heat of combus-
Table 1
Heat of combustion of some common dusts [6]
Material Oxidation products Heat of combustion
(kJ/mol O
2
)
Calcium CaO 1270
Magnesium MgO 1240
Aluminum Al
2
O
2
1100
Silicon SiO
2
830
Chromium Cr
2
O
2
750
Zinc ZnO 700
Iron Fe
2
O
3
530
Copper CuO 300
Sucrose CO
2
+H
2
O 470
Starch CO
2
+H
2
O 470
Polyethylene CO
2
+H
2
O 390
Carbon CO
2
400
Coal CO
2
+H
2
O 400
Sulphur SO
2
300
tion of a fewcommonly encountered dusts. It reveals that metals
form highly hazardous dusts from this viewpoint [6,9].
Explosion hazard always exists whenever dusts are produced,
stored or processed and where situations can occur when these
materials are present as a mixture in air [10,11]. The mixture
is deemed explosible if combustible dusts are present in such
quantities in air that an explosion can occur on ignition.
The differences between the mechanism of combustion of
dust clouds and premixed gases has been elaborated in Section 6.
2. Illustrative case histories of a few major dust
explosions
Even though mention of dust explosions is found in liter-
ature since 1785 [6,12], systematic records are available only
from the early 20th century. One of the earliest recorded and
the most serious of the accidents triggered by dust explosion
occurred at Leiden, the Netherlands, on 12 January 1807 [13].
A ship with about 85,000 kg of black powder on board had
arrived from Ouderkerk (near Amsterdam) and had moored in
the centre of Leiden against all regulations. It is believed that
the attempts of the four-member crew to prepare their food on
a stove ignited the dust leading to a detonation estimated to be
equivalent to 9000 kg of exploding TNT. The explosion killed
151 and wounded about 2000. Houses collapsed up to a dis-
tance of 155 m from the ship and within the whole city people
were hit by ying debris, glass, and roof tiles. Another catas-
trophic dust explosion of pre-modern era involved grain dust at
the Peavey terminal elevator at Duluth, the USA, in 1916. After
the explosion, the cribbed grain bins caught re, completely
destroying the elevator. It was described as one of the worst
roaring infernos witnessed in a dust explosion [14].
In 1919, a dust explosion occurred in a corn processing plant
in Iowa, the USA, killing 43. Five years later, a dust explosion
at a similar plant in Illinois (the USA) left 42 dead [5].
In 1949, at the Port Colbourne elevator in Ontario, Canada,
an explosion occurred in the steel bins which blew off the entire
roof. The ensuing re also caused signicant damage to the head
house. A grain dust explosion ripped through the grain eleva-
tor no. 4A of the Saskatchewan grain pools on 24 September
1952, killing 6 and injuring 14. The primary explosion in a ship-
ping bin was followed by a secondary explosion involving large
quantities of dust, which had been allowed to accumulate in the
building. The roof galleryabove the bins was alsodestroyed[14].
Dust explosions occur frequently in feed mills. A corn dust
explosion in the Wayne Feeds at Waynesboro, the USA, on
25 May 1955, killed 3 and injured 13. The violence of the
explosion caused extensive property damage. Another severe
explosion occurred in Kansas City, the USA, in 1958, when
the Murray elevator was badly damaged. The head house of
steel construction was completely shattered and its installations
destroyed by re [14].
A dust explosion, which was caused during the welding of
a spout, excessively worn by the ow of grain, occurred in the
Kampffmeyer grain silo at Albern near Vienna, Austria, 4 July
1960. The welding was being performed in the elevator pit, when
a spark ignited the dust in the running bucket elevator. The pres-
sure wave of the explosion went up through the elevator shaft,
ripping the casing of the elevator leg, and continuing up to the
roof, causing severe damage to the building and machinery [14].
At the Sun ourmills in London, UK, on 7 August 1965, 4
men died and 37 were injured when a giant blast shattered and
set ablaze the mill building and a wheat storage silo of cribbed
construction. The explosion is believed to have been triggered
by a welding ame being used on a our bin [14].
A violent dust explosion on 14 December 1970, shattered
the grain silos at Kiel-Nordhafen on the Kaiser Wilhelm ship-
ping canal, connecting the North and the Baltic seas. It was the
worst accident of its kind in Germany. Six men died and 17
were injured. The damage to plant, building and machinery is
estimated at 10 million dollars. At Destrahan near NewOrleans,
USA, a Bunge Corporation terminal elevator with an 8,000,000
bushel capacity was badly damaged in a massive dust explosion.
The entire roof gallery above the storage tanks was blown off.
The heat fromthe explosion and the resultant re badly damaged
the concrete storage bins and the adjacent workhouse [14].
In a dust explosion in a silicon powder grinding plant at Bre-
manger, Norway, in 1972, ve workers lost their lives and four
were severely injured. The explosion, which occurred in the
milling section of the plant, was extensive, rupturing or buck-
ling most of the process equipment and blowing out practically
all the wall panels of the factory building [6,15].
A blast and ame from a primary explosion, which occurred
in a 5.2 m
3
batch mixer when ne aluminum akes, sulphur and
some other ingredients were being mixed at a slurry explosive
factory in Norway in 1973, then generated and ignited a larger
dust cloud. The massive secondary explosion killed half of the
10 workers that were on site at that time, seriously injuring 2
others. A substantial part of the plant was totally demolished
[6].
A catastrophic explosion at a large export grain silo plant
at Christi, TX, USA, on 11 April 1981, killed 9 persons and
injured another 30. The material loss was estimated at $30 mil-
lion [16]. The probable cause of ignition was smoldering lumps
of sorghumthat entered a bucket elevator together with the grain
and ignited the dust cloud in the elevator.
Another catastrophic dust explosion which occurred at the
Harbin Linen Textile Plant, Peoples Republic of China on
15 March 1987, killed 58 persons and injured another 177. It
destroyed 13,000 m
2
of factory area [17,18]. The ignition was
possibly caused by an electrostatic spark in one of the dust col-
lecting units. The explosion then propagated through the other
seven dust collecting units, demolishing most of the plant.
Dry BPO (benzoylperoxide) exploded at a BPO manufac-
turing plant of the Dai-ichi Kasei Kogyo Company, Japan, in
August 1990. Nine workers were killed, and 17 were injured in
the accident. The storage of anillegallylarge quantityof dryBPO
apparently resulted in signicantly more damage than would
otherwise have occurred [19], because BPO can deagrate even
without being dispersed in air.
Adust explosion at the Daido Kako Enka Firework manufac-
turing factory, Moriya, Japan, in June 1992 resulted in the death
of 3 persons and injury to 58, including passers by. The presumed
cause of this accident was the ignition of powdery mixture of
potassium chlorate and aluminum by friction-induced sparks
during a mixing operation [19].
At a textile mill of the Shinko Seishoku Company at Okaharu,
Japan, a re, caused by the ignition of dusty cotton waste as
a result of electricity leak, destroyed the factory in December
1994. In the same year, a large dust explosion at the Kanaya
Shoe making factory, near Tokyo, killed 5 and injured 22. The
cause of the explosion was static electricity generated in the ne
rubber waste dust [5].
Blaye, France, witnessed a massive dust explosion in a grain
storage facility during August 1997. Two towers which housed
bucket elevators and dust collection equipment were totally
destroyed; so were a gallery and 28 silos. The concrete debris
rained down the control room, killing 11 persons. The most wor-
risome aspect of this catastrophe is that the whole grain handled
by the factory is generally regarded as posing low risk. The
explosion properties likewise seemed modest; samples passed
a 500 m sieve; they had P
max
(maximum absolute explosion
pressure) values of just 6 bar and low K
St
(maximum rate of
pressure rise) values as well [20].
A tantalum dust deagration occurred in a bag lter dust
collecting device in April 1997, which resulted in a fatal acci-
dent. One worker was killed, and another seriously wounded. A
MgAl alloy dust exploded in a bag lter dust collecting device
at a manufacturing plant of electronic devices in October 2000.
One worker was killed and another injured [21].
On 1 February 1999, explosions in a powerhouse of the Ford
Motor Company in Michigan caused the death of 6 workers and
injured 14 others. The primary explosion was found to have been
caused due to natural gas build-up in a boiler that was being iso-
lated for maintenance. It has been suggested that it was a result
of the secondary explosions involving coal dust which wrought
the main damage. The powerhouse building and connected
facilities were widely damaged. At over $1 billion, it is one of
the most expensive accidents in the history of the USA [22].
An explosion in a mould fabrication station in the Jahn
Foundry, Massachusetts, injured 12 employees on 25 Febru-
ary 1999, three of whom died later of the burns [23]. Either the
accumulation of natural gas/air mixture in one of the ovens or
the ignition of an airborne cloud of combustible resin dust in the
hot oven is thought to be the cause of the explosion.
Five workers died from severe burns suffered from an
explosion in a rubber recycling plant of Rouse Polymerics
International Inc. in Mississippi on 16 May 2002. Sparks
leaving an oven exhaust pipe are believed to have caused the
initial explosion, which, then, triggered a secondary explosion
of the dust accumulated in the building. The rubber dust was
of very small size (75180 m), contributing to its very high
ignition hazard [24].
On 20 February 2003, an explosion and re damaged the
CTA Acoustics manufacturing plant in Corbin, KY, the USA,
fatally injuring seven workers. The explosion was caused by the
accidental ignition of resin dust accumulated in a production line
that hadbeenpartiallyshut downfor cleaning. Apparentlya thick
cloud of dust dispersed by cleaning activities was ignited by the
ames in an oven whose door had been left open. The resulting
explosion propagated through the facility, causing secondary
explosions as powdered resin dust was dislodged from surfaces,
adding to the airborne fuel loading [25].
An explosion and re involving polyethylene dust killed 6
workers and injured 38 others at the USA-based West Pharma-
ceuticals (Kinston, NC) on 29 January 2003. Two reghters
were among those killed in a massive blast of which impact was
felt over a large area; the burning debris triggered secondary
res up to 2 miles away. Some initiating event caused dust to
become airborne above a suspended ceiling. There it contacted
an ignition source leading to the catastrophic event [25].
According to Marmo et al. [26] a series of very serious dust
explosion accidents occurred in an industrial district in north-
ern Italy over a period of 7 years (19942000) causing deaths,
several injuries, and great material damage.
Schoeff [27] has noted that on an average more than 10 major
dust explosions have been occurring in the agricultural factories
in the USA. In 2005, 13 such explosions took place killing 2
persons, injuring 11, and causing property damage worth $56
million.
An illustrative list of dust explosions is presented in Table 2.
Indeed it is commonly admitted [8] that at least one dust explo-
sion occurs in each industrialized country every day!
Surprisingly, whereas copious information is available on
dust explosions in the developed countries, there is practically
Table 2
Illustrative examples of dust explosion incidents (19112004)
Date Location Material Plant/building Dead/injured Reference
1785 Turin, Italy Wheat our Bakery 2i [6]
1807 Leiden, The Netherlands Black powder Ship 151d/2000i [13]
1911 Glascow, UK
a a
5d/8i [5]
1911 Liverpool, UK
a a
37d/100i [5]
1911 Manchester, UK
a a
3d/5i [5]
1913 Manchester, UK
a a
3d/5i [5]
1916 Duluth, MN Grain Steel bin [14]
1919 Cedar Rapids, IA Corn starch Starch plant 43d [5]
1924 Peking, IL Corn starch Starch plant 42d [5]
1924 USA Sulphide dust
a
1d/6i [5]
1924 USA Sulphide dust
a
1d/1i [5]
1924 USA Sulphide dust
a
2d/1i [5]
1926 USA Sulphide dust
a
3d/1i [5]
1930 Liverpool, UK
a a
11d/32i [5]
1944 Kansas City, KS Grain dust
a a
[5]
1949 Port Colbourne, CA Grain Steel bin [14]
1952 Bound Brook, NJ Phenolic resin dust Hammer mill 5d/21i [5]
1952 Saskatchewan Grain dust Shipping bin 6d/14i [14]
1955 Waynesboro, GA Grain dust Feed plant 3d/13i [14]
1956 South Chicago Grain dust Elevator [14]
1958 Kansas City Grain dust Elevator [14]
1960 Canada Sulphide dust
a
2d/ [5]
1960 Albern, Vienna Grain dust
a
[14]
1962 St. Louis, MO Grain dust Feed plant 3d/13i [5]
1964 Paisley, UK
a a
2d/34i [5]
1965 London, UK Flour Flour mill 4d/37i [14]
1969 Sweden Sulphide dust
a
2d/1i [5]
1970 Kiel, FRG Grain dust Grain silo 6d/18i [5]
1970 Germany Grain dust Silos on shipping canal 6d/17i, loss $10 million [14]
1970 Norway Wheat grain dust Silo
a
[6]
1971 New Orleans Bushel Elevator
a
[14]
1972 Norway Silicon Milling section 5d/4i [6,15]
1973 Norway Aluminum Mixing vessel 5d/2i [6]
1974 Canada Sulphide dust Fox mines
a
[5]
1974 Preska, South Africa Sulphide dust Mines
a
[5]
1975 Norway Fish meal Fish meal grinding plant 1d/1i [6]
1976 Norway Barley/oats dust Silo [6]
1976 Oslo, Norway Malted barley dust Silo [6]
1977 Galvesto, TX Grain dust Grain silo 15d [5]
1977 Westwego, Louisiana Grain dust Grain silo 36d/10i [15]
1979 Lerida, Spain Grain dust Grain silo 7d [5]
1979 Canada Sulphide dust Ruttan mines
a
[5]
1980 Germany Coal Cement factory [6]
1980 Iowa, USA Corn dust Bucket elevator [16]
1980 Minnesota, USA Grain dust Cross tunnel, bucket elevators 13i [16]
1980 Naples, Italy Grain dust Grain silo 8i [5]
1980 Ohama, NE, USA Grain dust Head house Loss $3,300,000 [5]
1980 St. Joseph, MO, USA Grain dust Shipping bin 1d/4i, loss $2,000,000 [16]
Table 2 (Countined)
Date Location Material Plant/building Dead/injured Reference
1981 Canada Sulphide dust Mattabi mines
a
[5,15]
1981 Corpus Christi, TX Grain dust Bucket elevator 9d/30i [16]
Elevator
1981 Bellwood, NE, USA Grain dust Bucket elevator Loss $6,400,000 [5]
1981 Germany Coal Coal dust burner plant, cement works [6]
1982 British Columbia, Canada Coal Silo [6]
1983 Anglesey, UK Aluminum Aluminum powder production 2i [6]
1984 USA Caol Silo [6]
1985 Australia Sulphide dust Elura mines
a
[15]
1985 Canada Sulphide dust Lynn lake
a
[5]
1985 Germany Coal Silo 1i [6]
1985 Norway Rape seed our pellets Silo [6]
1986 Canada Sulphide dust Brunswick mines
a
[5]
1986 Sweden Sulphide dust Langsele mines
a
[5]
1986 Canada Sulphide dust Dumugami mines
a
[5]
1986 Australia Sulphide dust Woodlawn
a
[5]
1987 Canada Sulphide dust GECO mines
a
[5]
1987 China Textile dust Dust collection system 58d/177i [17,18]
1987 Oslo, Norway Malted barley dust Silo [6]
1988 Norway Wheat grain dust Silo [6]
1988 Sweden Coal Silo [6]
1989 Sweden Palletized wheat bran Silo [6]
1990 Japan Benzoylperoxide Storage 9d/17i [19]
1992 Moriya, Japan Potassium chlorate and
aluminum dust
Mixing operation 3d/58i [19]
1994 Okaharu, Japan Cotton waste Textile mill
a
[5]
1994 Tokyo, Japan Rubber waste Shoe factory 5d/22i [5]
1997 Japan Tantalum dust
a
1d/1i [21]
1997 Blaye, France Grain Storage 11d [20]
1999 Michigan Coal dust (cause for secondary
explosion)
Powerhouse 6d/14i [22]
1999 Massachusetts Resin Oven 3d/12i [23]
2000 Japan MgAl alloy 1d/1i [5]
2000 Modesto California Aluminum dust
a a
[15]
2002 Mississippi Rubber Recycling plant 5d/
a
[24]
2003 Kentucky Resin Production line 7d [25]
2003 Kinston, NC Polyethylene Pharmaceutical plant 6d/38i [25]
2004 Avon, OH Lacquer dust
a a
[15]
a
Details not available.
no material in printed or electronic form on dust explosions in
the developing countries. This is surprisingly so even in case
of a technologically advanced country like India from where,
otherwise, signicant original contributions have come to loss
prevention R&D [28].
Indeed when the subject of accidents in chemical process
industries is discussed in the third world, the focus is mainly
on toxic releases such as the one that occurred in Bhopal in
1984 [29,30] or on res caused by vessel bursts such as the ones
that occurred in 1996 at the HPCL renery in Vishakapatnam
[31] and in 2004 at Libya. The terms vapour cloud explosion
(VCE), boiling liquid expanding vapour explosion (BLEVE),
pool re, ash re, reball are heard most of the time during dis-
cussions on process industry accidents [3236]. In comparison,
the phenomena of dust explosion is much less deliberated upon
or cognized in the third world. This is highly worrisome because
some of the most damaging accidents in chemical and agro pro-
cessing industries have been caused not by ammable liquids or
gases but by dusts. As would be reected fromthe case studies
reported later in this paper, multiple fatalities and catastrophic
damage to property is a common feature of accidents involving
dust explosions.
Even though, as stated earlier, India is among the most
advanced countries in terms of technological competence, infor-
mation pertaining to dust explosions occurring here is almost
non-existent [37] solely because in most accidents that occur
in India, the broad term explosion is used and recorded while
the type of explosion generally goes unreported. Also, in pub-
lic perception, explosions are what occur in pressurized vessels
containing gases or liquids, or by the operation of explosives.
Dust is seldomperceived as a cause for explosions. This appears
to be typical of the third world. This situation is quite differ-
ent from the one existing in developed countries where dust
explosions are recognized as very major industrial hazards that
can match or exceed the ferocity of well-known industrial
disasters like the one that occurred in Flixborough [38], and
meticulous attention is paid towards their analysis, prevention,
and control.
Fig. 1. The dust explosion pentagon [39].
3. The dust explosion pentagon
While re is caused when three factors fuel, oxidant, and
ignition come together to make what has been called the re
triangle, a dust explosion demands two more factors: mixing
(of dust and air), and connement (of the dust cloud). The dust
explosion pentagon [39] is formed when these ve factors occur
together (Fig. 1):
(i) presence of combustible dust in a nely divided form;
(ii) availability of oxidant;
(iii) presence of an ignition source;
(iv) some degree of connement;
(v) state of mixed reactants.
A point to be noted here is that even partial connement of
an ignited dust cloud is sufcient to cause a highly damaging
explosion. In this sense, too, dust clouds behave in a manner
similar to clouds of ammable gases [8].
4. Sources and triggers of dust explosions
The industries prone to dust explosions are:
(i) wood processing and storage;
(ii) grain elevators, bins and silos;
(iii) our and feed mills;
(iv) manufacture and storage of metals such as aluminum and
magnesium;
(v) chemical production;
(vi) plastic production;
(vii) starch or candy production;
(viii) spice sugar and cocoa production and storage;
(ix) coal handling or processing area;
(x) pharmaceutical plants.
In addition, dust collection bins or bags, shelves, nooks, cran-
nies, inside of equipment, and above the false ceilings, in all the
aforementioned facilities, are prone to dust explosion.
In recent years explosion hazard from polyurethane dust
generated in the course of recycling depreciated electronic appli-
ances has increased owing to the increasingly large volumes
being recycled [40,41].
4.1. Operations involving dusts
The operation in which dusts are generated or handled, com-
prise of:
(i) size reduction;
(ii) conveyingmanual or mechanical;
(iii) pneumatic separation;
(iv) settling chambers;
(v) cyclones;
(vi) lters;
(vii) scrubbers;
(viii) electrostatic precipitator;
(ix) driers;
(x) tray driers;
(xi) rotary driers;
(xii) uidized bed driers;
(xiii) pneumatic driers;
(xiv) spray driers;
(xv) screening and classifying operations;
(xvi) mixing and blending operations;
(xvii) storage;
(xviii) packing;
(xix) dust red heaters.
Charge chutes are often used to feed powder into process
vessels by manually tipping the powder from sacks or bags into
the charge chute. In the event of a dust explosion occurring in
the vessel during the lling operation, a ame could propagate
up the charge chute, impinge on the operator, and cause serious
injury [42].
4.2. Classication of dusts
A dust layer is deemed combustible if it can be ignited with
a foreign source and the local re thus generated propagates
sufciently after the outside source is taken away [43].
All explosible dusts ought to be combustible, but not all com-
bustible dusts are easily explosible [5]. For example, anthracite
and graphite are not easily explosible, although they have high
heats of combustion. As of now sufciently rigorous theory is
not available to forecast explosibility of combustible dusts and
recourse has been taken to experiments. If the composition of
the dust is known, one may check whether it is explosible by
consulting the list of experimentally tested dusts, published by
HM Factory Inspectorate of the Department of Employment,
UK. According to this classication [20], dusts, which propa-
gated a ame when ignited have been classied under Group A.
The dusts, which did not propagate a ame have been classied
under Group B. This classication is applicable to dusts which
are at or near the atmospheric temperature (25

C) at the time of
ignition. At higher temperature some of the Group B dusts can
become explosible. Dusts which are ignitable but not explosible
can become explosive if admixed with fuel dust; for example the
ignitable but non-explosible y ash becomes explosible when
spiked with pulverized coal or petroleum coke [44]. This occurs
due to increased volatile matter provided by fuel dusts.
Another measure of the ignitability of a dust layer and inten-
sity of burning of a dust layer is the Combustion Class [45,46].
This classication is based on the behavior of a dened heap
when subjected to a gas ame or hot platinum wire:
(i) CC1: no ignition; no self-sustained combustion.
(ii) CC2: short ignition and quick extinguishing; local combus-
tion of short duration.
(iii) CC3: local burning or glowing without spreading; local
sustained combustion but no propagation.
(iv) CC4: spreading of a glowing re; propagation smoldering
combustion.
(v) CC5: spreading of an open re; propagating open ame.
(vi) CC6: explosible burning; explosive combustion.
A third categorization of dusts is based on K
St
value; the
term represents the maximum rate of pressure rise in 1 m
3
ves-
sel when a dust is ignited; in other words the dust explosion
violence [47]. The K
St
concept was introduced by Bartknecht
[48,49] who reported that the so-called cube root law:
_
dP
dt
_
max
V
1/3
= constant K
St
,
seemed to hold for numerous dusts in vessel of volumes from
0.04 m
3
and upward. The K
St
value (bar m/s), being numerically
identied with the (dP/dt)
max
(bar/s) in the 1 m
3
standard Inter-
national Standards Organization (ISO), test [50] was denoted a
specic dust constant.
The abbreviation St has its origin in the German word staub,
meaning dust.
The explosibility is ranked as under:
But it must be emphasized that the cube root law is valid
only in geometrically similar vessels, if the ame thickness is
negligible compared to the vessel radius, and if the burning
velocity as a function of pressure and temperature is identi-
cal in all volumes [6]. Hence, K
St
is bound to be an arbitrary
measure of dust explosion violence as the state of turbulence
to which it refers is arbitrary. This fact has sometimes been
neglected when discussing K
St
in relation to industrial practice
and is therefore understood here. Indeed K
St
values of a given
material, determinedindifferent apparatus, maydiffer byseveral
orders-of-magnitude, even by factors more than 20 [6].
It follows that when using K
St
values to size vent areas and
for other purposes according to various codes, it is absolutely
essential to use only data obtained fromthe standard test method
specied for determining K
St
. Normally this is the method of the
ISO [50] or a smaller-scale method calibrated against the ISO
method. In addition, it is necessary to appreciate the relative and
arbitrary nature even of these K
St
values.
The Bureau of Mines has developed an index of explosibil-
ity which ranks dusts relative to Pittsburgh coal. The index of
explosibility IE is the product of the explosion severity ES and
the ignition sensitivity IS:
IE = IS ES
IS =
(MIT MIE MEC)
Pc
(MIT MIE MEC)
sample
ES =
(MEP MRPR)
Pc
(MEP MRPR)
sample
where MEC is the minimum explosive concentration, MEP
the maximum explosion pressure, MIE the minimum ignition
energy, MIT the minimum ignition temperature, and MRPR is
the maximum rate of pressure rise; the subscripts Pc and sample
denote Pittsburgh coal and sample. This index of explosibility is
a relative one, and is to this extent less dependent on the appa-
ratus used, but its determination requires the conduct of the full
range of tests [2,12].
4.3. Tests to determine the explosibility of dusts
As all the initiatives on the understanding, prevention, and
control of dust explosions revolve round dust explosibility,
minimum explosible dust concentration, minimum ignition
energy, and minimumignition temperature, it may be relevant
to dwell upon how these parameters are measured and what are
the uncertainties involved in the measurements.
The two apparatus most often used for dust explosibility test-
ing have been the Hartmann vertical tube and the 20 l sphere.
Of, these the Hartmann tube was the rst to be commonly used
and a great deal of data exists which has been generated in the
pre-1980 era by this apparatus [2,12]. A Hartmann apparatus
consists of a 1.2 l vertical tube in which dust is dispersed by an
air blast. A hot wire or a spark igniter serves as ignition source
(Fig. 2). Flame propagation is observed as a function of dust par-
ticle size, dust concentration, ignition energy, temperature, etc.
Even as the Hartmann vertical tube and its variants the
horizontal tube, and the inammatory apparatus have been
extensively utilized in the past, it has been increasingly realized
that the Hartmann tube is not apt to give uniform conditions
for dust dispersion and turbulence. Further, it is subject to wall
effects; after the ame goes throughinitial spherical expansion, it
travels as two fronts up and down the tube. These conditions give
a lower rate of combustion and of pressure rise than the actual;
consequently the strength of the pressure rise one records with
the Hartmann bomb is less than one gets from more advanced
apparatus. The Hartmann tube may also yield false negatives for
dusts that are difcult to ignite with a spark but are ignitable by
stronger ignitionsources [7]. Choi et al. [203,204] have proposed
a new apparatus, as a modication of the Hartmann tube, in
which an ultrasonic vibrator, a sieve, and a specially designed
dust hopper are used to generate dust cloud and to ignite it. But
the apparatus is yet to be rigorously tested.
These problems have been largely overcome by the use of
sufciently large spherical test vessels. In such vessels a dust
cloud is simulated better than in tubular apparatus. The two
principal vessels adopted are the nearly spherical 20 l sphere
Fig. 2. Hartmann vertical tube apparatus.
introduced by Siwek [51,52] and the standard closed 1 m
3
ISO
vessel [6,50]. It has been shown that the former is close to the
critical size belowwhich vessel size begins to seriously inuence
the explosibility measurements and above which such inuence
is less pronounced. A large number of studies continue to be
done on the comparison of results obtained with 20 l and 1 m
3
vessels [7,5358] and the 20 l sphere is being used increasingly
as a standard with or without minor modications in the appa-
ratus introduced by Siwek [5962]. In the spherical vessels the
ignition source is located in the centre of the sphere and the dust
is injected from a separate container (Fig. 3). As with the mod-
ied versions of the Hartmann vertical tube [203,204], the 20 l
and 1 m
3
spheres are used to determine whether a dust is explosi-
ble and to measure the maximum explosion pressure as also the
rate of the pressure rise. The minimum explosible dust concen-
tration and the minimum explosion energy are also determined
using 20 l/1 m
3
spheres.
The experimental conditions required to obtain agreement
with the 1 m
3
ISO vessel were specied in a standard issued by
the American Society for Testing and Materials (ASTM) in 1988
[6]. The ignition source has to be the same type of 10 kJ chemical
ignitor as used in the 1 m
3
ISO test but the ignition delay can be
shorter (60 ms) because of the smaller vessel size. The ignitors
with metal capsules could give signicantly different K
St
values
from those obtained for the same dusts with plastics capsules.
Withdusts of small particle size, Siwek[51,52] obtainedquite
good correlations between data from the 1 m
3
ISO vessel and
that from his 20 l sphere. It was however seen that many cohe-
sive dusts, in particular those of brous particles, can easily get
packed and trapped inside the perforated dispersion tube of the
original dust dispersion system (Fig. 3b). This led to the devel-
opment of an open nozzle system named rebound nozzle, which
has gradually replaced the original perforated ring in the Siwek
20 l spheres [6]. The rebound nozzle produces both maximum
pressures and K
St
values in reasonable agreement with those
generated by the original perforated-ring system [6,43].
Besides the size and the geometry of test vessel which, as
stated above, should be at least 20 l and spherical, respectively
the ignition source strength should also be appropriate if realistic
estimates of dust explosibility are to be obtained. If the ignition
source is too large compared to the vessel volume, overdriv-
ing of the explosion may occur. Overdriving may increase the
temperature of the dust cloud, rendering a non-explosible dust
explosible. It may also result in burning of the dust within the
igniter ame, but with no real propagation beyond the ignition
source [63]. The large volume of the ignition source in the con-
text of the vessel volume may make the dust appear to explode,
and result in the overestimation of the overpressure as well as
the rate of pressure rise.
For several dusts, Going et al. [57] found that best agreement
occurred between 20 l vessel data with 2.5 kJ igniters and 1 m
3
vessel data with 10 kJ igniters. In a series of studies on explosion
suppression by Amyotte [63] it was noted that the results from
20 l vessel begin to approach those measured in 1 m
3
chamber
when the ignition energy is decreased below 5 kJ in the former.
Whereas a large amount of the earlier work on dust explosi-
bility was done using the Hartmann apparatus, most later work
has been with the 20 l and 1 m
3
vessels. Unfortunately, the results
obtained from the two types of apparatus often do not agree and
may even give different rankings. For example the Hartmann
vertical tube overestimates the minimum ignition energy by a
factor of between 2 and 5, and is therefore not conservative.
The ignition source in the Hartmann tube is a capacitive spark
igniter, which has two disadvantages: the spark energy tends to
be less than the theoretical energy (1/2VC
2
) due mainly to loss
in the transformer, and it is not possible to control the duration
of the spark, which is a signicant variable. Due to these reasons
nearly all of the very considerable explosibility data generated
earlier with the original Hartmann apparatus is not utilizable.
4.4. Safety codes
Anumber of safety codes nowaddress the dust/vapour explo-
sion potential depending on the type of industry or operations
[64]. An illustrative example, are the National Fire Protection
Association (NFPA) codes:
(i) Combustible metals and metal dusts (NFPA 65, 480, 481).
(ii) Explosion protection systems (NFPA 68, 69).
(iii) Handling and conveying of dusts, vapour, and gases (NFPA
91, 650, 654, 655).
(iv) Prevention of sulphur res and explosions (NFPA 655).
(v) Prevention of res and explosions in wood processing and
woodworking facilities (NFPA 664).
The Atex 100a Directive of the European Parliament [65]
provides the conceptual basis for the European apparatus stan-
dards for prevention and mitigation of accidental gas, vapour,
mist, and dust explosion. It has also had a major impact on the
Fig. 3. Spherical vessels for P
max
and K
St
testing: (a) ISO 1 m
3
vessel and (b) 20 l spherical vessel.
International Electrotechnical Commission (IEC) effort to har-
monize dust standards with gas standards. But the Directive
pays only modest attention to the very different physical and
chemical properties of dust clouds and layers, and needs to be
suitably revised [6].
The IEC [66] subscope for standardization of uniform
practices in areas where combustible dusts are present contains
the following two points specifying the basic objectives, which
are to
address situations where the presence of dust presents a risk
of re or explosion with respect to use of electrical apparatus;
test the properties of dusts relating to the risk of re or explo-
sion.
However, in the revised global scope of IECs [67] Ex-
standardization work, res are not included, only explosions.
Hence, there is discrepancy between the two scopes; the confus-
ing situation can be resolved by including dust res even in the
global scope [6].
The IEC [68] has produced a standard, the International Pro-
tection (IP) code, which denes various degrees of protection
against ingress of solid objects, including dust particles and
water. It is specied by two digits, the rst referring to ingress
of solid objects, the second to ingress of water. For solid objects
six levels of protection are dened, ranging from objects larger
than 50 mm (digit 1) to dusts (digits 5 and 6). For water, the cor-
responding range is from gentle dripping (digit 1) to continuous
complete immersion (digit 8). The code also species the test
methods by which enclosures can be checked for compliance
with the requirements of the various degrees of protection. But
the code does not cover protection against ingress of explosive
gases.
4.5. Dust explosion triggers
As we have described later in this paper, in theory, the dust
explosionhazardcanbe eliminatedbyprocess modications but,
in practice, few industries can maintain their economic viability
if such modications are executed. So the dust explosion hazard
is here to stay. What is currently within our means [69] is to
reduce the hazard drastically by identifying ash points and
covering them with more and more layers of protection (LOP).
The rst LOP against dust explosion is to identify factors
which trigger it and prevent those factors fromcoming into play.
A number of causes can trigger a dust explosion:
(i) ames and direct heat;
(ii) hot work;
(iii) incandescent material;
(iv) hot surfaces;
(v) electrostatic sparks;
(vi) electrical sparks;
(vii) friction sparks;
(viii) impact sparks;
(ix) self-heating;
(x) static electricity;
(xi) lightning;
(xii) shock waves.
These ignition sources differ in terms of temperature, energy
and power; the dusts can be ignited by lowenergy as well as high
energy ignition sources. Of these, the ignition sources which
can occur inside the plant are of particular importance, and
include incandescent material, hot surfaces, sparks, self-heating
and static electricity.
Abrief description of the ignition sources is presented below.
4.5.1. Flames and direct heat
This obvious trigger can be eliminated by using indirect heat-
ing methods like circulating hot water or steam through pipes
and using hot water/steam baths.
4.5.2. Self-heating
Self-heating or spontaneous combustion may occur due to
exothermic reactions. Awide variety of reactions can give rise to
self-heating. These include oxidation reactions as well as reac-
tions of certain dusts with water or wood. In most cases the
reaction rate accelerates with temperature, but there are also
autocatalytic reactions which may accelerate due to produc-
tion of a catalyst or removal of an inhibitor. Induction times
may be long and the self-heating may be slow to start but may
then proceed undetected for a long period. Contaminants such
as oil and products of thermal degradation can also contribute
to self-heating.
The dust should be screened to determine whether it is prone
to self-heating. The dust temperature during the process and in
storage should be controlled. One aspect of this is control of hot
surfaces, whichmayarise innormal operation. Unintendedaccu-
mulation of dust deposits, which could undergo self-heating,
should be avoided.
Situations in which there is a large mass of dust stored at
a high initial temperature (to keep the dust dry) are hazardous.
Dust ina pile has a highsurface area andsufcient air circulation,
both of which favor self-heating. The risk of accident is further
enhanced during the discharge of hot dust from a drier into a
hopper. It may be necessary to cool the dust prior to storage.
Another measure which is sometimes used is to recirculate the
hot dust through a cooling system prior to its further use.
4.5.3. Hot work
Excessive heat generated during operations such as welding
and cutting is another obvious trigger more so when a dust of
lowignitionthreshold(100200

C) is present nearby. Accidents

often occur because this hazard is not appreciated and the dust
is not cleaned out of the equipment before hot work is started.
4.5.4. Incandescent material
Smoldering particles or other incandescent material can
trigger a dust explosion inside dust handling equipment. The
explosion may then travel through the ducts and connected ves-
sels. Direct ring systems are potential sources of incandescent
particles. In direct-red driers the air inlet should be protected
by a ne screen to prevent ingress of such incandescent material.
4.5.5. Hot surfaces
Equipment with a hot surface such as steam pipe or electric
lamp, or overheated moving equipment such as distressed bear-
ing, falls under this category of triggers. The surface temperature
that can cause ignition of a dust layer is frequently in the range of
100200

C. The ignition temperature moves closer to the lower

limit of this range as the thickness of the layer increases. Find-
ings from investigations of dust related accidents often reveal
that ignitions occur at unexpectedly low temperatures. A dust
may contribute to its own ignition; dusts being poor conductors
of heat, a layer of dust on the equipment may prevent heat loss
to the atmosphere and thus raise the temperature below the sur-
face of the dust heap to the point of ignition. A smoldering or
burning layer can act either directly as an ignition source for a
dust cloud or by means of agglomerations or nests of burning
material that break away from deposits and ignite a dust cloud
in another part of the plant [46].
When dusts accumulate on hot surfaces, they may go through
different and complex stages before combusting. Some dusts
burn directly in solid phase with a ame or by smoldering, others
melt and burn as liquids. Some dusts can give off large amounts
of ammable gases. The size of the ames produced by different
dusts also vary.
Hot-surface ignition is a particular problem with driers of
various types. According to the IChemEDrier Guide [70,71], the
inlet temperatures should be at least 50

C below the minimum

ignition temperature of the dust suspension and 20

Cbelowthat
of any dust layer likely to occur. Hot surfaces may also occur as a
result of distress in machinery such as pumps and motors. It may
be necessary in some cases to monitor features such as bearing
temperatures. Anumber of incidents have occurred, particularly
insilos, involvingthe use of wander lamps suppliedbythe mains.
These shouldbe avoidedandportable batterylamps usedinstead.
4.5.6. Electrostatic sparks
Electrostatic discharge from electrical equipment may cause
a spark which in turn may ignite a dust cloud. Protection against
such discharges is based on hazardous area classication and
the associated safeguarding. Electrical equipment is designed
so that incendive capacity or inductive discharges cannot occur.
4.5.7. Electrical sparks
Electrical sparks occur in the normal operation of switches
and relays and in malfunctioning electrical equipment.
To protect against electrical sparks hazardous area ought to be
classied and safeguarded. In particular, ameproof equipment
must be used, and should exclude dusts. A distinction may be
drawn between equipment which is dust tight and excludes dust
entirely and equipment which is dustproof and lets in only an
insignicant amount of dust [72].
4.5.8. Friction sparks and hot spots
Frictional sparks can occur wherever there is rubbing of one
solid with another or during grinding. Foreign materials such as
tramp iron can also cause sparks. The dust itself may block the
equipment and cause overloading, leading to spark generation.
To prevent frictional sparks, dust ow should be controlled and
machine overload trips should be installed. Removal of foreign
objects should be effected by magnetic or pneumatic separation,
especially when the material is to pass through a mill.
Friction-induced heating can also raise dust temperature.
Pulling the dust through drag conveyer heats it up a bit, so
do mixing operations. But more serious friction-induced heat-
ing can occur when hot spots are formed in localized areas of
blenders due to the blenders shearing action.
A thermal runaway reaction which occurred during the
mixing of an oxidizer (sodium dichloroisocyanurate), some
organic compounds, and inert compounds, in a 500 kg batch was
attributed to such hot spots [73]. The accident generated toxic
gas release and extensively damaged the blender. The ejected
material also caused thermal damage to nearby objects.
4.5.9. Impact sparks
Hand tools may create an incendive impact spark, although
there is little evidence from incidents of single impact ignition.
The incendive potential of an impact such as that of a metal tool
on a metal surface arises from the heating of that surface. The
ignition source is not the spark itself but the heated surface, and
the heat is transferred from the metal surface to the dust.
4.5.10. Static electricity
Static electricity may turn to sparks when an object moves
rapidly into or out of its eld. It is more strongly inuenced by
the process than by the material. For sieving and pouring the
charges are low, but for size reduction they are much higher. In
certain types of dust handling plants static electricity is readily
generated. These include mills, conveyor belts and pneumatic
conveyingsystems. As withliquids, static charge canaccumulate
at the center of a large storage hopper. It may then be discharged
by an earthed probe. But there is also a hazard unique to dusts
that of sliding of highly charged material towards an earthed
container wall [12].
The ignition of a dust cloud by static electricity is inuenced
considerably by particle size distribution, and the duration and
the rate of the application of ignition energy [74]. The capaci-
tance of the electrical discharge system may also inuence the
minimum ignition voltage and the minimum ignition energy.
According to Matsuda [75], 25.7% of dust explosions
recorded in Japan between 1952 and 1990 were triggered by
static electricity. Nifuku and Enomoto [76] consider agricul-
tural products as being at high risk of dust explosion due to
static electricity.
Plastic surfaces such as those used in chutes may give rise
to sparks. Bags used for transporting dusts can also create
sparks. Sparks generated during the pouring of powder from
polyethylene bags into ammable solvents have led to several
accidents.
Charge accumulation can occur on non-conductive materials
which are being increasingly used in the process industry. When
such a charged isolator comes in the neighborhood of a blunt
earthed conducting object, it may lead to a brush discharge. In
controlled experiments, Larsen et al. [77] were able to observe
ve instances when such brush discharges ignited dust clouds
of sulphur dispersed in oxygen-enriched air.
The human body can generate charge intense enough to make
it a potential ignition source. In the manual handling of dusts,
the hazard of static electricity from the human body becomes
signicant if the dust has a minimum ignition energy less than
25 mJ.
Fortunately, the generally high minimum ignition energy
of dusts and the tendency of dusts to give corona discharge,
contribute towards reducing the risk fromstatic electricity. Mod-
ication in the processing conditions of the plant and generating
a humid atmosphere can signicantly reduce the dust explosion
hazard due to static electricity. Earthing may be provided in the
form of wire meshes on the walls of storage bins and of earthed
rods in the bulk powder. Passive dischargers on the material
entering storage bins can also reduce the ignition hazard.
To prevent the human body from generating sparks, con-
ducting antistatic footwear and conductive ooring should be
employed. If the minimum ignition energy of the dust being
handled is less than 10 mJ it is imperative that antistatic ooring
is installed and antistatic clothing and footwear are used.
4.5.11. Lightening, shock waves
Lighteningcaninitiate dust explosions [5,6]. Initiationof dust
explosions by shock waves has also been studied [78,79].
In the records of dust explosion incidents the exact trigger is
often not mentioned either due to oversight or because it was
not known with certainty (Table 2). But accidents of which trig-
gers were clearly identied reveal that welding and cutting, re,
friction, electrical sparks and lightening are among the major
causes of dust explosions (Table 3).
Table 3
Major dust explosion triggers
Ignition source Proportion found responsible (%)
Primary
explosions [187]
Elevator
incidents [188]
Feed mills
[189]
Welding and cutting 10 24.3 12
Fire 7.8 NRA 12
Friction 8.5 NRA 4
Electrical 4.3 6.0 4
Lightning 2.8 1.5 NRA
Static electricity 4.5 1.5 NRA
Unknown 60 25.7 34
NRA: no record available.
4.6. Domino effect
4.6.1. Primary explosions
The dust concentrations adequate for an explosion rarely
build-up outside of process vessels, hence most severe dust
explosions start within a piece of equipment (such as mills, mix-
ers, screens, dryers, cyclones, hoppers, lters, bucket elevators,
silos, aspiration ducts, and pneumatic transit systems). These
are called primary explosions even though, in reality, all dust
explosions are events which occur after an initiating accident.
It is important to note that one of the main differences between
the dust explosion and ammable gas hazard is that gas/vapour
explosions rarely happen inside vessels due to a lack of air to
support explosions. However, the dust is generally suspended in
air in process equipment, which can allow dust explosion con-
ditions to occur. This can then cause the vessel to rupture if it
has insufcient pressure release devices/venting or if its design
pressure is too low.
Even as it is important to attempt eliminating the possibility
of primary dust explosions, it is even more important to reduce
the possibility of the rst explosion setting off a series of other
explosions; in other words to prevent domino effect. More so
because secondary dust explosions are often more violent than
the primary explosions [2,12,80].
4.6.2. Secondary explosions
A primary explosion can disturb settled dust lying nearby,
forming a cloud which may then be ignited by the heat released
from the primary explosion (Fig. 4). The settled dust occupies
very little space, but once disturbed can easily form dangerous
clouds. A 1 mm layer of dust of 500 kg/m
3
can give rise to a 5 m
deep cloud of 100 g/m
3
dust.
A dust explosion in one part of a powder handling system
can cause pressure and/or ames to propagate to other vessels
via connecting pipes. For example, in an explosion in a vented
bag lter, where typically the reduced explosion pressure is less
than 500 mbar, tests have shown that the explosion can propagate
into the inlet pipe. This could lead to an explosion propagating
with increasing violence throughout the system [43], because
the ame propagating in the duct tends to accelerate due to tur-
bulence. It results in a jet ame entering the second vessel. As
a result, high combustion rates are obtained at high pressures,
even if the second vessel is vented and the amount of dust it
contains does not present much danger in itself [11].
Fig. 4. Domino effect in dust explosions.
If we go by the analogy of the behavior of gas explosions in
interconnected enclosed vessels, which has been studied exten-
sively [8,81], pressure-piling is likely to occur as secondary
and higher order explosions are caused by the primary explo-
sion propagating through interconnected vessels and pipes. The
turbulence generated as the rst explosion passes through an
interconnected pipe into another vessel increases the rate of the
dust combustion, hence the rate of pressure rise. As the pressure
wave enters the second vessel, it compresses the dust contained
in that vessel which then gets ignited by the ame propagated
by the rst explosion. In this pre-compressed dust cloud, the
explosion begins at higher than ambient pressure and the result-
ing peak pressure of the secondary explosion is correspondingly
higher. The energetic nature of the ame jet coming fromthe rst
explosion through the interconnecting pipe also contributes to
the severity of the second explosion [20].
Lunn et al. [81] produced explosions in coal dust and toner
dust in a number of linked systems using vessels ranging in size
from 2 to 20 m
3
and connected by 5 cm long pipes with diame-
ters of 0.15 m, 0.25 m, and 0.5 m. They record that the degree of
pressure-piling resulting from dust explosions in linked vessels
depends on the ratio of the vessel volumes and the diameter of
the connecting pipe. Generally an explosion which initiated in
a larger vessel and traveled to a smaller one led to very high
explosion pressures. Transmission of dust explosions between
vessels did not always occur; the narrower the connecting pipe,
the lower the probability of a secondary explosion. No transmis-
sion of explosion occurred during the experiments of Lunn et al.
[81] with a pipe diameter of 0.15 m.
The authors opine that to reduce the hazard of domino effect,
volume of the connecting pipe should be added to the volume
of the vessel in which initial ignition occurs. The pipe lengths
should not be so long that detonation-type explosions can occur
in them, nor the pipe volume should be large relative to the vessel
volumes.
Of course, as observed by Lunn et al. [81] and others [2,12]
the explosive atmosphere in one vessel does not necessarily
ignite the dust in the second vessel. It has been found experimen-
tally that the likelihood of ignition breakthrough to the second
vessel is a function of the dust properties, the dust concentra-
tion, the type of venting of the secondvessel, the ducts diameters,
the severity of the primary explosions and the presence of any
obstructions in the connecting duct [82]. The probability of sec-
ondary explosion generally increases with increasing K
St
value
and the amount of ame produced in the primary explosion [20].
If an obstruction, such as a bafe plate, happens to come in
the way of the ame propagating due to the primary explosion,
the ame gets distorted, distributing the burning material over
a larger area. This increases the size of the potential ignition
source.
Proust [83] has developed a software, EFFEX, which mod-
els dust ame propagation into a succession of interconnected
vessels. At each step of the propagation, the turbulence ahead
of the ame is due to the jets coming from the neighboring
explosion pressurized rooms. This code implements the ame
propagation theory, the turbulence combustion models and the
basic combustion parameters reported by earlier authors.
5. Frequency of dust explosions
Not all dust explosion events get counted as several, espe-
cially the minor ones, are not reported in the media. Hence the
historical accounts of dust explosion frequencies are indicative
rather then quantitative.
Vijayaraghavan [5] has given an analysis of dust explosions,
excluding those in coalmines, in the period 19001959. He has
listed 1110 explosions and 648 fatalities. Studies by Lunn [84]
reveal that during a 10-year span (19581967) in the UK, there
were 247 reported explosions with 9 fatalities and 324 non-fatal
injuries. In the period 19681979 there were 474 explosions
reported with 25 fatalities and 633 non-fatal injuries; 10 of the
25 fatalities in this latter period occurred in two incidents.
According to the information culled from the UK-based
Health & Safety Executive (HSE) by Vijayaraghavan [5], there
were 36 dust explosions with injury, and 123 explosions with
no injury, during 19791988. The principal items of equipment
involved were mills, grinders, lters, driers, silos/hoppers and
ducts with 51 (17%), 47 (16%), 43 (14%), 19 (6%), and 15
(5%) events, respectively; 95 (31%) events were classied in
the category other. In another survey conducted by the Beruf-
sgenossenschaftliches Institut fur Arbeitssicherheit (BIA) 1120
explosions have been identied as having occurred in the United
States and Germany (Fig. 5) during the period 19001956, of
which 536 (48%) have involved industries handling grain, feed
and our [14]. In these 536 explosions, 392 persons were killed,
1015 were injured and the material losses amounted to over $75
million. The high frequency of explosions in the grain industry
occur because grain products can ignite and propagates ames
easily, the source of heat required being small.
Eckhoff [85] has examined the details of 75 dust explosions
which occurred in the USA from 1900 to 1956, covering a wide
range of dusts: wood, food and feed, metal, plastic, coal, paper
and chemical. This study, and another by Jeske and Beck [86]
which had studied 426 dust explosion occurring between 1965
and 1985, indicated that only about 15% of the dust explosions
get recorded. Inother words the actual number of dust explosions
occurring in the world is over six times higher than the records
suggest.
Illustrative example of dust explosions that have occurred
in different parts of the world during 19112005 have been pre-
sented in Table 2. It may be seen that a record is available of only
one event from a developing country (China, 1987). This sub-
stantiates the fear expressed by us earlier that the dust explosions
occurring in the developing world are rarely, if ever, recognized
as such but get reported alongside other types of explosions.
Matsuda [75] compiled a report on the dust explosion acci-
dents that occurred in Japan in the period 19521990. A total
of 248 cases were reported, of which agricultural products were
involved in 44 incidents, coal in 13, inorganic materials in 29,
metals in 60, chemicals in 32, intermediates and additives in 46
and cellulose materials in 23 instances.
Proust [87] has complied statistics for dust explosion acci-
dents in ve developed countries. According to his estimates,
about 160dust explosions per year occur inGermany. Inthe USA
more than a thousand dust explosion accidents were reported
Fig. 5. Frequencies of dust explosion accidents involving different types of dusts (at the USA and Germany).
in the years between 1900 and 1956. Of these, 501 accidents
occurred in the food industry during 19581978. In Japan, 187
dust explosions occurred in gramstorage facilities between 1969
and 1973. In the UK, more than 400 dust explosions were
reported during 19691976.
A study by Schoeff [27], covering 106 major dust explo-
sions that occurred in agricultural factories in the USA during
19962005, indicates that 51 of these occurred in grain eleva-
tors and 25 in feed mills. Corn industry accounted for 54%of all
accidents in this sector followed by 8.5% in wheat processing
facilities.
5.1. Historical overview of dust explosion causes
The possible dust explosion triggers have been listed in the
previous section. A survey of past dust explosion accidents
indicates that of all the triggers of dust explosions, friction,
mechanical failure and ames are the ones most often involved.
Abbott [71] and Porter [88] carried out survey of 303 dust
explosions that occurred in the UK between 1979 and 1988.
Their studies revealed that friction and mechanical failure trig-
gered 18% of the dust explosions surveyed. Flames and aming
material were responsible for 15% of the accidents. Overheat-
ing and spontaneous heating were the triggers in 17% of the 303
accidents.
Gummer and Lunn [46] report that a survey on dust explosion
triggers carried out by Berufsgenossenschaftliches Institut fur
Arbeitssecherhet (BIA) identied friction-induced sparks to be
the most frequent source of ignition (26%). The BIAreports that,
at 11%, smoldering nests were the next most frequent triggers.
Mechanical heating caused 9% of the accidents surveyed.
Mechanical sparks have been found to be the most fre-
quent dust explosion ignition source in dust collectors, mills,
and grinding plants. Electrostatic discharge caused ignition is
responsible for most of the plastic dust explosion accidents in
mixers.
Fig. 6. Frequencies of dust explosions caused in different type of industries in
Germany.
Fig. 6 depicts the frequency of explosion in the various pro-
cessing equipment used in industries processing coal and wood
dusts in the Federal Republic of Germany.
Nifuku et al. [89] provide a brief summary of death and injury
caused by 269 dust explosions that occurred in Japan between
1952 and 1995 (Table 4). The material-wise inventory and the
gures of death or injury per event of these accidents is given in
Table 5.
It has been estimated [90] that an average manufacturing
facility will have dust explosion once every 20 years, while the
probability of such accidents occurring in chemical, pharmaceu-
tical, and milling plants are much higher.
Table 4
Dust explosion accidents that occurred between 1952 and 1995 in Japan [89]
Year Explosions Dead Injured
1952 6 7 26
1953 9 1 16
1954 9 1 19
1955 4 0 0
1956 7 7 14
1957 4 2 6
1958 8 4 18
1959 7 3 9
1960 6 0 1
1961 3 0 6
1962 8 3 23
1963 11 2 30
1964 7 2 9
1965 12 1 41
1966 6 3 20
1967 8 9 39
1968 12 4 17
1969 8 6 11
1970 6 7 5
1971 7 2 12
1972 7 6 22
1973 12 2 53
1974 7 3 10
1975 9 3 14
1976 4 0 3
1977 6 2 2
1978 8 3 9
1979 9 2 26
1980 3 0 8
1981 2 0 7
1982 3 3 2
1983 3 0 6
1984 3 0 0
1985 5 3 6
1986 8 3 12
1987 1 0 0
1988 3 0 9
1989 1 0 0
1990 6 0 11
1991 4 1 7
1992 4 3 3
1993 1 1 1
1994 6 7 26
1995 6 0 8
Totals 269 106 567
Table 5
Materials involved in dust explosions and consequent injuries/fatalities [89]
Dust type Number of
accidents
Deaths Injuries
Total Per
accident
Total Per
accident
Cellulosic materials 28 7 0.3 84 3.0
Chemical synthetic
materials
36 12 0.3 79 2.2
Coal 13 7 0.5 41 3.2
Food and feed 46 17 0.4 109 2.4
Inorganic 31 9 0.3 28 0.9
Intermediate additives 50 13 0.3 69 1.4
Metals 64 41 0.6 153 2.4
Miscellaneous 1 0 0.0 4 4.0
6. Dust explosion mechanism
As explained earlier, when a ammable cloud, formed by the
mixing of dust and air in the right proportion and in a conned
space, is ignited, a rapid combustion of the fuel takes place,
with the propagation of the ame across the cloud. The rate
and the extent of ame propagation depend on factors such as
nature of dust, dust particle size, and nature of combustion by-
products formed. A dust explosion is a complex phenomenon in
the sense that it involves simultaneous momentum, energy, and
mass transport in a reactive multi-phase system [91].
In order to model the dust explosion phenomenon, assess the
dust explosion impacts, and devise prevention and control strate-
gies, a precise understanding of the dust explosion mechanism
is required.
6.1. The dust combustion process
How similar and how different is the dust combustion pro-
cess from the combustion of premixed gases? This question has
engaged great attention because if the extent of similarity can
be established, the dust explosion phenomena can be analyzed
using the concepts and tools which exist for studying explosions
involving gases.
In the following respects explosive dust clouds behave in a
manner similar to explosive gas mixtures [92]:
(1) ammability/explosibility limits;
(2) laminar burning velocities and quenching distances;
(3) the response of the burning velocity to cloud turbulence;
(4) detonation phenomena;
(5) adiabatic constant-volume explosion pressures of similar
magnitudes;
(6) well-dened minimum ignition energies;
(7) minimumignition temperatures for given experimental con-
ditions.
However, there are two basic differences between dusts and
gases which are of substantially greater signicance in design of
safety standards than these similarities [92]. Firstly, the physics
of generation and up-keeping of dust clouds and premixed
gas/vapour clouds are substantially different. This means that
in most situations where accidental explosive gas clouds may
be produced quite readily, generation of explosive dust clouds
would be highly unlikely. Secondly, contrary to premixed gas
ame propagation, the propagation of ames in dust/air mix-
tures is not limited only to the ammable dust concentration
range of dynamic clouds. The state of stagnant layers/deposits
offers an additional discrete possibility of ame propagation. In
the context of these observations, Eckhoff [92] has opined that
a revision of the existing European Directives 94/9/EC [93] and
1999/92/EC [94] to clarify important basic differences between
dusts and gases/vapours is urgently needed.
In dust clouds inertial forces can produce fuel concentration
gradients (displacement of particles in relation to gas phase).
Furthermore, thermal radiation may contribute signicantly to
the heat transfer from the ame to the unburnt cloud, depending
on the type of particle material (e.g. light metals).
It has often been assumed that the laminar burning velocity
of a given dust cloud is a basic combustion property of the cloud,
which is closely related also to the burning velocities at various
levels of turbulence, and hence to the ame propagation through
that type of cloud at large [95]. A burner apparatus was used by
Dahoe [96] and Dahoe et al. [58] to produce stable cornstarch
ames in air, and the laminar burning velocity was measured
via laser Doppler anemometry (LDA). It was found that the
laminar burning velocity varied with ame shape, and this was
accounted for by introducing the Markstein length of a dust/air
ame. This parameter is specic for any given dust cloud. It has
a magnitude of the order of the laminar ame thickness of that
specic dust cloud, and serves as a measure of the sensitivity of
the laminar burning velocity to changes in the ame shape.
When considering turbulent ame propagation in dust clouds,
ame distortion and turbulence produced by the propagating
explosion itself is central for understanding both dust and gas
explosions in practice. Rzal and Veyssiere [97] report possible
differences between turbulent combustion of premixed gases
and dust clouds. They investigated the interaction of a laminar
maize starch/air ame with an obstacle, viz. a sphere, a disk or
an annulus. With the annulus, ame quenching phenomena were
observed, which were attributed to centrifugal separation of dust
particles and air in the turbulent eddies. This is a very important
observation, indicating that the burning rate of a dust cloud may
not necessarily respond to turbulence in the same way as the
burning rate of a premixed gas. Signicant differences also exist
on the microscopic scale. For example, the basic microscopic
turbulence mechanisms that promote the combustion process
must be identied. The results of Mitgau [98] and Mitgau et al.
[99] indicate that more efcient replacement of gaseous reaction
products by fresh air round each particle may be a strong basic
turbulent combustion enhancement mechanism.
6.2. Role of dust particle size in the combustion process
Flame propagation across a dust cloud occurs in two ways:
(i) By the combustion of ammable gases emitted by particles
heated to the point of vapourization or pyrolysis [100,101].
(ii) Through direct oxidation at the dust particle surface [102].
Fig. 7. (a) Cumulative dust particle size distributions. (b) Differential distribu-
tion of dust particle size: (A) surface area weighted and (B) mass or volume
weighted.
In either case, the particle size plays an important role in the
combustion process.
Larger dust particles participate inefciently in the ame
propagation process, whereas ner dust particles of the same
material are likely to react faster and more efciently during
combustion [7,103]. This is so because the ner particles have
greater surface area per mass, are more easily dispersed in air and
remain airborne for longer periods. Fig. 7 shows the cumulative
and differential particle size distribution of a typical dust.
Such differential curves are useful in visualizing the dust
particle size distribution.
The dust particle size can be calculated from the surface
mean diameter (D
s
<30 m) and the mass mean diameter
(D
w
<50 m) provided by Fig. 7. But, since it is the surface
area of the dust particles that plays a major role in the com-
bustion process, the mean particle diameter which reects the
surface area is a more appropriate characteristic than the one
based on mass. The minimum explosible concentration (MEC)
are size-independent for very ne powders but begin to increase
for particles above 30 m until a size is reached that cannot be
easily ignited [7].
Experimental evidence gathered over the last two decades
support the idea that the basic ame propagation mechanism
in dust clouds has a general similarity with premixed gaseous
ames [8] even though differences also exist because a dust par-
ticle must rst volatilize before catching re. The microscopic
turbulence mechanism is also different for dust suspensions in
comparison to gaseous mixtures [95]. For particles able to gasify
at low temperature (below 1000

C for instance), ame propa-

gation results from a heat balance between upstream thermal
conduction, inducing intense gasication of the particles, and
heat release in gaseous phase. Most industrial dusts fall into
that category. But, for other powders which have high gasica-
tion temperature like aluminum, particles present in the burnt
products may radiate strongly towards the reactant in such a
way that the heat balance will be between thermal radiation and
heat release by some heterogeneous combustion process. The
interaction between turbulence and combustion in dust clouds
is possibly of a lower degree than in gaseous ames, but still
roughly of the same nature, with similar correlations linking the
turbulent burning velocity to the parameters of the turbulence
and of the laminar ames.
Experiments by Chatrathi and Going [104] show that a
ammability curve can be created for fuel/inert dust mixtures.
This ammability curve for dusts has the same characteristics
as a ammability curve for gas mixtures, and is characterized
by a lower ammable limit, an upper ammable limit, and a
minimum inerting concentration.
It must again be emphasized that the processes leading up
to the point of ignition of dusts are different from the ones
associated with the ignition of ammable gases. An example is
organic dusts (most common in industry) where the actual com-
bustion only starts after a slow devolatilization process. Pilao et
al. [105,106] studying cork dust, report that the mechanism of
ame propagation in that dust followed the known pattern for
organic dusts in which gas phase combustion was preceded by
devolatilization of dust particles. This is one of the reasons why
the ignition delay for such dusts may be of the order of tens of
milliseconds. During this time, a pressure wave would have cov-
ered a distance of more than 1 m [11]. The ame consumes the
combustible mixture with a speed corresponding to a burning
velocity, which is determined empirically, depending on kind of
mixture, its concentration, turbulence and temperature.
6.3. Factors inuencing dust explosibility
A number of factors inuence dust explosibility; in order
to assess the dust explosion hazard posed by a substance, it is
necessary to quantify the factors that inuence it. They are:
(i) particle size;
(ii) dust concentration;
(iii) oxidant concentration;
(iv) ignition temperature;
(v) turbulence of the dust cloud;
(vi) maximum rate of pressure rise;
(vii) admixed inert dust concentration;
(viii) presence of ammable gases.
A ready reckoner of the forces and counter-forces that inu-
ence dust explosibility is presented as Table 6.
6.3.1. Particle size
As explained in Section 6.2, larger the surface area per unit
mass of a dust particle, greater is the hazard it poses. However, in
some cases, there is a likelihood of very small particles agglom-
erating into lumps. If this happens, the explosibility of the dust
Table 6
Inuence of dust properties/characteristics on dust explosion parameters [12]
Parameter Increases with Decreases with
Explosibility of the dust 1. Lower explosible concentration 1. Presence of chemical groups such as
Cl, Br, F
2. Minimum ignition temperature 2. Presence of inert material at
concentrations above 1020%
3. Lower minimum ignition energy 3. Dust moisture content above 30%
4. Burning velocity
5. Maximum rate of pressure increase
6. Presence of chemical groups such as COOH,
OH, NH
2
, NO
2
, C N, C N, N N
7. Presence of volatile matter in the dust at levels
above 10%
8. Relatively small proportion of nes
9. Increasing oxygen concentration
Effect of particle size on the likelihood of
explosion initiation
5070 m<particles size (m) <500 m 500 m<particles size (m) <5070 m
Minimum explosive concentration 1. Increasing moisture content 1. Decreasing particle size
2. Increasing admixed inert dust concentration 2. Increasing volatile matter
3. Increasing oxygen concentration
Minimum ignition temperature 1. Increasing moisture content 1. Decreasing particle size
2. Increasing admixed inert dust concentration 2. Increasing volatile matter content
3. Increasing oxygen concentration
4. Increasing thickness of the dust layer
Maximum permissible oxygen concentration Decreasing dust temperature Increasing dust temperature
Maximum explosion pressure Decreasing particle size, though weakly
Maximum rate of pressure rise 1. Decreasing particle size 1. Increasing moisture content
2. Increasing volatile matter content 2. Increasing concentrations of admixed
inert dust
3. Increasing oxygen concentration
decreases and when the particle size increases beyond 500 m,
it may even become non-ignitable.
The explosibility of dusts does not vary linearly with parti-
cle surface area although it depends on it. This dependence is
dictated by the actual speed of combustion of volatiles and the
concentration of dusts.
6.3.2. Dust concentration
A dust cloud would explode only if the dust concentration is
within certain limits. These generally are:
50100 g/m
3
: lowest concentration;
23 kg/m
3
: maximium concentration.
According to Hertzberg et al. [100] a certain stoichiomet-
ric concentration of volatiles in air of the solid phase fuel must
be generated for a ame to propagate rapidly through the mix-
ture before more fuel volatiles are produced. This indicates that
the lower concentration limit is determined by the minimum
quantity of fuel particles that must exist in order to sustain
combustion. A near parabolic relationship exists between dust
concentration and ignition energy. The latter is high at high dust
loadings and decreases to a minimumvalue with decreasing con-
centrations. A further decrease in dust concentrations result in
an increase in the ignition energy [64].
The upper concentration limits are dictated by the minimum
amount of oxygen needed for explosion.
As is the case with ammability characteristics, data on the
explosibility of the same dust differs from test to test [12,107].
The considerable progress made in dust explosibility testing
(summarized in Section 4.3) has reduced this variability, but still
signicant differences exist and utmost care must be exercised
in developing control strategies on its basis.
6.3.3. Oxidant concentration
One of the sides of the dust explosion pentagon is the oxi-
dant, which usually is oxygen in air. Oxygen inuences the dust
explosion process to a very large extent. Oxygen concentration
greater than 21% tends to increase the burning velocity of the
fuel. But for concentration less than 21% the burning velocity
is reduced. This happens because oxygen is consumed by the
fuel in the combustion process, thereby decreasing the oxygen
concentration. As a consequence of this, the rate of combustion
of the dust comes down. Eventually, the combustion may die
down, or, if an explosion occurs, it may be less severe. Fire is
sustained only if the oxygen concentration in air is greater than
10%.
6.3.4. Ignition temperature
If a mixture of ignitable dust and air gets heated, it would
catch re at some point. The lowest temperature at which such
ignition occurs is characterized as minimum ignition temper-
ature (MIT). As summarized in Table 6, MIT increases with
the presence of moisture or other inertants in dust cloud but
decreases with decreasing particle size and increasing volatile
matter, oxygen concentration, and thickness of dust layer.
Measurement of MIT is essential for eliminating ignition
sources and for designing explosion suppression systems.
When dust-oxidant clouds are subjected to temperatures
higher than MIT, the lower ammability limit and the minimum
explosible concentration of the clouds expectedly decrease. But
the maximum absolute explosion pressure, P
max
, also decreases
[56,108]. For coal dusts, Cashdollar [56] has explainedthis effect
to be occurring because at elevated temperatures fewer oxi-
dant molecules are available to react with the coal. The author
measured the MEC at 60

C and 80

C using a 20 l chamber
test apparatus. Applying the modied BurgersWheeler law for
hydrocarbons, he has extrapolated the two data points to obtain
a curve correlating temperature and MEC.
Typical ignition temperatures of common dusts in air of rel-
ative humidity 3090% are:
wheat our: 410430

C;
corn starch: 410450

C;
rye dust: 430500

C.
Indeed most grain and our dusts can be ignited if they are
blown against hot surfaces bearing temperatures of the order
of 400500

C. Even at temperatures of 200

C dusts can
be ignited under favorable conditions (low relative humidity,
small particle size, high turbulence) and begin to smolder. The
smoldering nests can then cause explosion [46].
6.3.5. Role of turbulence
The rapid, more or less random, movement of small ele-
ments constituting the dust cloud in three-dimensional space
generates turbulence. A highly turbulent cloud will have evenly
distributed dust in it. When such a cloud catches re, the turbu-
lence will cause a mill-like effect: mixing the hot burnt/burning
parts of the cloud with the cold unburnt parts, generating a three-
dimensional laminate of alternating hot burnt/burning and cold
unburnt zones. In short, a ame will propagate very quickly
through a dust cloud if the latter has high degree of turbulence,
resulting in a violent explosion. Turbulence affects the rate of
pressure rise much more than the peak pressure [109].
On the other hand, when ignited, a less turbulent cloud
releases an initial large amount of heat which is locally concen-
trated due to its lowrate of heat dissipation. Further propagation
of any ame produced in the dust cloud is due entirely to the
degree of dust dispersion. A more evenly dispersed dust burns
more easily.
There are two kinds of turbulence, differing in their origin,
that are generated by industrial process involving dusts. The rst
one is generated by the dust production operations such as by air
jet mill, mixer, bag lter, pneumatic transport pipe and bucket
elevator. This type of turbulence is often called initial turbulence.
The second kind of turbulence is generated during the
combustion process after the dust cloud has ignited. It is an
expansion-induced ow of unburnt dust cloud ahead of the
propagating ame. The speed of the ow and the geometric
constrictions present at the operation site govern the degree of
turbulence generated. For example, vent openings and obstacles
like buckets in a bucket elevator, enhance the turbulence gen-
eration process. By and large, the turbulence generated by the
ame front is much greater than the initial turbulence [110].
Given that the rate of combustion and other chemical reac-
tions associated with dust explosions are characterized through
a set of fundamental properties such as burning velocity, turbu-
lence has been regarded by some authors [111] as the single
most important factor whose effects need to be incorporated in
a model of dust explosions.
6.3.6. Maximum rate of pressure rise
The rate of pressure rise, when a dust is ignited, is not only a
measure of the explosibility of a dust but is also a key property
on which the design of several explosion detection systems and
vents are based.
According to the classical combustion theory [112], for the
ideal case, the absolute pressure as a function of time, P(t), in
a constant volume, spherical explosion, is related to the frac-
tional volume, V(t), occupied by the reball during the time of
propagation, t, as follows [113]:
P(t) P
0
P
max
P
0
= k
V(t)
V
0
(1)
where P
0
is the initial absolute pressure, V
0
the chamber volume,
and k is a correction factor related to the difference in com-
pressibility between burned and unburned gases. For spherical
propagation from a point source:
V(t)
V
0
=
_
r(t)
r
0
_
3
=
_
S
b
t
r
0
_
3
(2)
where r(t) is the reball radius, r
0
the chamber radius, and S
b
is
the ame speed given by
S
b
=
dr(t)
dt
=
_

b
_
S
u
(3)
where
u
/
b
is the density ratio of unburned to burned gases
(at constant pressure). The burning velocity, S
u
, is the rate of
ame propagation relative to the unburned gas ahead of it. The
ame speed, S
b
, is relative to a xed reference point. Note that
both S
b
and S
u
are for turbulent non-laminar conditions for dust
explosions. For spherical propagation in a spherical chamber,
the maximum pressure is reached just as the ame contacts the
wall. At that instant, k =1. Differentiating Eq. (1) with respect
to time and substituting Eqs. (2) and (3) yields:
dP(t)
dt
= 3(P
max
P
0
)
_

b
_
S
u
r(t)
2
r
0
3
(4)
Setting
r(t) = r
0
=
_
3V
0
4
_
1/3
and letting

T
b
T
0

P
max
P
0
,
we get
K
St
=
_
dP(t)
dt
_
max
V
0
1/3
= 4.84
_
P
max
P
0
1
_
P
max
S
u
(5)
K
St
is the size normalized maximum rate of pressure rise. As
stated earlier, the subscript St refers to staub, the German word
for dust.
Bartknecht [114] and Wiemann [108] who studied the effect
of initial pressure on the P
max
and K
St
values found that P
max
increases linearly with increase in initial pressure, over the range
of 14 bar. They also found that K
St
increases with initial pres-
sure.
Even though the K
St
concept has its limitations, as elaborated
in Section 4.2, it nevertheless remains a key parameter for the
design of explosion vents [115]. It has also been used in expert
systems developed for assisting in vent design [116].
6.3.7. Admixed inert dust concentration
Experiments byChatrathi andGoing[104] onthe suppressing
effect of sodium bicarbonate, potassium bicarbonate, mono-
ammonium phosphate, and calcium carbonate on the dusts of
coal, cornstarch, polyethylene, anthraquinone, etc. showed that
ammability curves can be created for fuel/inert dust mixtures.
The ammability curves for dusts had the same characteristics
as the ammability curves for gas mixtures, and were charac-
terized by a lower ammable limit, an upper ammable limit
and a minimum inerting concentration. The suppression results
showed that high K
St
deagrations and metal dust deagrations
can be extinguished and the maximum explosion pressure can
be reduced to an acceptable level. The effectiveness of the extin-
guishing agent used was dependent upon the compatibility of the
fuel dust with the inert dust. Specic heat, thermal conductiv-
ity, absorptivity, particle geometry and particle decomposition
seemed to play a critical role in the effectiveness of suppres-
sants. These factors along with ame temperature and heat of
combustion may explain the variation in explosion severity and
extinguishment effectiveness.
6.3.8. Presence of ammable gases
If a ammable gas is also present in the midst of the dust, the
explosibility of the latter is enhanced. The minimum explosive
concentration, minimum ignition temperature, and minimum
ignition energy are all reduced, and the increase in maximum
rate of pressure rise goes up. Thus a ammable gas can render
explosive a dustgas mixture at a dust concentration which is
below the normal lower explosive limit for the dust and at a
gas concentration below the normal lower explosive limit for
the gas [117]. It may also make explosive a dust of such large
particle size which would otherwise have been non-explosive.
For example dust of class St 0 changes to classes St 1, 1/2,
2 and 3 at methane concentrations of 1%, 3%, 5% and 7%,
respectively, and to classes 1, 2/3 and 3 at propane concentra-
tions of 0.9%, 2.7% and 4.5%, respectively [2,12]. For hybrid
air/methane-cork dust mixtures Pilao et al. [105] observed that
the risk of explosion rises with the increase of methane con-
centration. Hybrid mixtures of polyurethanecyclopentane and
plastic dustcyclopentane were two times more sensitive to dust
explosion than the dust without the cyclopentane gas [40]. For
mixture of hydrocarbon dusts and gases, the mixing law of Le
Chatelier is applicable [7,118,119].
The minimum ignition energy of the dustammable gas
mixtures is also lower than that of the dust alone.
7. Prevention of dust explosion
7.1. Dust explosion prevention strategies
The right conditions that must prevail for a dust explosion to
occur is summed up under the dust explosion pentagon (Sec-
tion 3). The most obvious way to prevent a dust explosion from
happening is to not allow the dust pentagon to be closed. This
can be attempted in the following ways:
(i) Effectively modifying the process to reduce dust handling
hazards.
(ii) Preventing suspensions of ammable dusts.
(iii) Completely removing or minimizing the presence of igni-
tion sources.
(iv) Inerting.
7.1.1. Process modication
The most obvious and fool-proof way to prevent dust explo-
sions is to replace existing processes with the ones which do not
deal with combustible dusts. But, sadly, it also happens to be a
strategy conrming to the axiomeasier said than done because
considerations of process economics, not to speak of viabil-
ity, may drastically reduce the options of process modications
available to existing industries.
Inherently safe process design to prevent or reduce dust
explosion hazard involve use of such production, treatment,
transportation and storage operations where dust cloud gener-
ation is kept at a minimum. One example is use of mass ow
silos and hoppers instead of the frequently used funnel ow
types. Eckhoff [120] has emphasized the importance of know-
ing powder science and technology when striving for inherently
safe process design in industries having a dust explosion hazard.
Amyotte and Khan [121] have proposed a framework for direct-
ing the concept of inherently safe process design specically
towards reducing the dust explosion hazard in industry.
Amyotte et al. [122] have identied the following four ele-
ments associated with inherently safe design which may reduce
the risk of accidents:
(1) Minimize (intensication): use smaller quantities of haz-
ardous materials when the use of such materials cannot be
avoided.
(2) Substitute (substitution): replace a hazardous substance with
one that is less hazardous or a hazardous process route with
one that does not involve hazardous material.
(3) Moderate (attenuation/limitation of effects): use hazardous
material in their least hazardous forms or identify options
that involve less severe operating conditions.
(4) Simplify (simplications/error tolerance): design processes
and equipment to eliminate opportunities for errors by iden-
tifying ways to eliminate excessive use of add-on safety
features and protective devices.
Amyotte et al. [122] present the following recommendations:
Use nitrogen as a conveying gas instead of air.
Use nitrogen sealing in silos.
Fill silos using a cyclone to reduce dust cloud dispersion.
Carefully control the particle size.
Reduce electrostatic problems with silos and bag lters by
checking the relative potential of metal construction parts.
Control moisture in pipes and silos.
Use lower mass ow rates.
Use online monitoring of the electric eld of compacted pow-
ders in silos.
Use conduction of the electric eld, if required.
Design silos and explosion isolation valves between silos for
explosion venting, so that sequential dust explosion will be
avoided.
Keep the dust concentration below the minimum explosible
concentration.
Design and test explosion blocks in conveying pipes.
7.1.2. Preventing ammable dust suspensions
It is difcult to keep the ammable dust cloud concentrations
below certain levels in order to prevent an explosion, because
the minimum explosive concentration is usually far below the
economic operational conditions [41].
The following measures may be effective:
(i) In cases where high dust concentration may be unavoidable,
it would be appropriate to work with smaller piles of dust
than with one large one.
(ii) Situations such as the free fall of dust from a height into a
hoper, which may encourage dust cloud formation, should
be avoided.
(iii) The dust removal process, say from a gas stream, must be
done at as early a stage as process considerations permit in
order to avoid dust suspensions.
(iv) Plants handling ammable dusts should be appropriately
designed to minimize the accumulation of dusts. Cleaning
of dusts collected in places like ducts should be facilitated
as often as permissible.
It must be emphasized that even if a dust suspension within
the explosive range is not present during normal operations, it
may be so during startup, shutdown or fault conditions. It may
not cause what we normally call primary explosion yet it may
trigger a secondary explosion by disturbing the nearby dust
heaps.
By adhering to certain safe housekeeping practices, the pres-
ence of dust can be limited to controlled locations thereby
reducing the potential for the formation of hazardous dust
clouds. Once a dust explosion is initiated, the expanding gases
behind the ame of such incipient dust explosion can whirl-
up the otherwise settled dust lying nearby, thus feeding the
explosion. NFPA 654 [123] provides guidance on housekeeping
practices which maintain that: (a) dust layers 1/32 in. (0.8 mm)
thick can be sufcient to warrant immediate cleaning of the
area; (b) a dust layer this thick can create a hazardous condi-
tion if it covers more than 5% of the building oor area, with
1000 ft (93 m
2
) of dust layer as the upper limit for large facili-
ties; (c) dust accumulations on other surfaces, such as overhead
beams and joists, ductwork, conduit and cabling, piping, light
xtures, or tops of equipment, can also contribute signicantly
to the secondary dust cloud potential, and should be considered
in estimating the dust loading in a room; (d) dust adhering to
walls and other vertical surfaces should also be considered.
These are non-mandatory recommendations but NFPA 654
does stipulate the dust layer thickness of 0.8 mm as a basis for
dening dust explosion hazardous areas in the main (mandatory)
portion of its standard. Considering that the measure of 0.8 mm
represents extreme thinness, NFPA654 has strongly emphasized
the necessity of reducing dust accumulation.
Physical barriers to limit dust migration have been permit-
ted in NFPA 654 to minimize the extent of the housekeeping
zone, but, expectedly it has also stipulated that all penetrations
of oors, walls, ceilings, and partitions dening such barriers be
dust tight. The standard also stipulates that all surfaces where
dust might accumulate be designed and constructed to minimize
dust accumulations and to facilitate cleaning (for example, inte-
rior window ledges can be sloped, beams can be boxed in, and
concrete walls can be painted to limit dust adherence). The stan-
dard also requires sealing of spaces that may be inaccessible for
cleaning and the installation of localized dust collection systems
to limit dust migration. Such systems, however, must be care-
fully designed, operated, and maintained to control their own
inherent dust explosion hazards. For example a small explosion
inside a lter or a pressure wave arriving at the lter bag from
the connecting pipe work can rupture the lter, blow the con-
tents of the lter into open space and cause a violent secondary
explosion.
One of the most effective ways of limiting the spread of
dust through a facility is to keep it inside the equipment. Proper
design, maintenance, and operation of equipment to minimize
dust emissions is, therefore, of prime importance.
Unsafe housekeeping such as vigorous sweeping or the use of
steam or compressed air to blow down equipment in dusty areas
may lead to the formation of combustible dust clouds. NFPA654
permits the use of steamor compressed air only when (a) the area
and equipment have been vacuumed before blowdown; (b) elec-
trical power and other sources of ignition have been shut down
or removed; (c) the steam or air pressure is limited to 15 psig;
(d) there are no hot surfaces in the area capable of igniting a dust
cloud or layer.
If vacuuming is intended as part of the housekeeping pro-
gram, NFPA requires either the use of a xed-pipe (house)
system with a remotely located exhauster and dust collector
(properly protected against explosions), or a portable vacuum
cleaner listed for use in Class II hazardous locations. Other
commodity-specic standards generally parallel the require-
ments in NFPA 654. More restrictive requirements, however,
may exist for certain commodities, for example, NFPA 484
(combustible metals, metal powders, and metal dusts) addresses
the ease with which aluminum dust can be ignited and requires
that: (a) the Preliminary cleanup. . . shall be accomplished by
using conductive, non-sparking scoops and soft brooms, as well
as brushes that have natural ber bristles; (b) very stringent con-
trols on the design and use of vacuum cleaners; (c) restrictions
on the use of water due to the reaction of water and aluminum
to produce ammable hydrogen gas.
Based on an analysis of six past accidents which have
occurred between 1995 and 2003, Frank [25] has identied the
following housekeeping imperatives:
(1) Specic characteristics of the dust involved (such as MIE,
conductivity, chemical incompatibilities) must be consid-
ered in planning safe housekeeping procedures.
(2) Housekeeping programs must comprehensively address all
areas where combustible dust may accumulate.
(3) One must strive to limit the production of dust clouds dur-
ing housekeeping, after rst de-energizing or removing all
ignition sources.
(4) Regular cleaning frequencies must be established (an NFPA
654 requirement) and complied with; cleaning may be done
if dust accumulations necessitate.
(5) Extreme caution must be exercised when using compressed
air for cleaning.
(6) One must learn from near misses, and treat them as fore-
warnings.
7.1.3. Elimination of ignition sources
A brief description of the various types of dust triggers was
given in Section 4.4. In situations where the minimum electrical
spark ignition energy of the working dust is considerably greater
than 10 mJ, elimination of ignition sources would provide ade-
quate protection against dust explosions.
The ignition sources, which are traceable to routine opera-
tions or worker habits such as smoking, open ames, open light
(bulbs), welding, cutting, and grinding, can be eliminated by
sufcient staff training and enforcement of discipline.
The ignition sources that originate in the process itself involve
factors such as open ames, hot surfaces, self-heating, smoulder-
ing nests and exothermic decomposition, heat from mechanical
impacts, exothermic decomposition of dust via mechanical
impacts, and electric sparks and electrostatic discharges. As
these ignition conditions are inherent in the actual process, the
hazard can be reduced by employing the right precautionary
measures like regular cleaningof accumulateddust at the process
site, earthing of equipment that may develop charges, inspec-
tion of odd noises; and strict adherence to the process operation
norms.
Which ignition sources have greater probability of initiating
combustion and which have lesser?
Hesby [124] reports that the number of sparks from single
accidental impacts of steel objects is too low to be able to cause
ignition of the layers of organic dusts studied. According to
the studies of Gummer and Lunn [46], smoldering nests are
poor ignition sources for most dust clouds, whereas, aming
nests cause ignition more readily. Further work is needed to
clarify both the conditions under which smoldering or aming
nests of various materials are generated in industrial plant, and
the circumstances under which such nests will ignite explosive
clouds of various dusts [95].
The minimum hot-surface temperature for ignition of a dust
cloud varies with scale as well as the geometry of the hot surface
in relation to the dust cloud. Consequently, results from small-
scale laboratory tests ought not to be directly applied in design of
large-scale industrial plants. Development of numerical models
for dynamic simulation of hot-surface ignition processes would
be helpful in this regard [95].
The parameters inuencing the minimum energy required
for igniting a dust cloud by an electric spark include voltage and
current characteristics across the spark gap, spark gap geometry
and electrode material, as well as all the dust cloud parame-
ters. The latter include particle material and particle size/shape
distributions, dust moisture content, dust concentration, and the
dynamic state of the dust cloud with respect to the spark gap.
Minimum ignition energies (MIE) of clouds of a given dust
material decreases strongly with the neness of the dust [95].
Randeberg and Eckhoff [125] have investigated an alternative
methodfor measuringMIEs of explosive dust clouds, whichmay
approximate accidental electrostatic spark ignition in industrial
plant better than other methods. In the conventional method a
special electronic system is employed for optimal synchroniza-
tion of the dust cloud and the spark discharge. Randeberg and
Eckhoff [125] have used the transient dust cloud itself to initiate
spark breakdown between a pair of electrodes pre-set at a high
voltage somewhat below the breakdown voltage in dust-free air.
Using this method, the MIEs of three dusts were determined.
The results were of the same order, although somewhat higher
than those obtained using the conventional method.
The issue of whether one-electrode discharges such as brush
discharge can ignite dust clouds was examined by Larsen et al.
[77]. They were able to ignite clouds of sulphur dust in oxygen-
enriched air by true brush discharges. However, ignition in air
only was never observed. Because of the very lowMIEof clouds
of sulphur dust in air, this indicates that ignition of even the most
sensitive dust clouds by brush discharges in air is unlikely.
7.1.4. Inerting
Inerting refers to ways and means by which the oxygen
concentration in a process area or a vessel is reduced by adding
an inert gas to a level at which the dust cloud can no longer
propagate a self-sustaining ame. Such inerting would slow
down or totally prevent the dust explosion pentagon (Section 3)
fromtakingshape, therebyreducingthe explosionhazard. Inert-
ing is also practiced, though much less frequently, by mixing a
combustible dust with a non-combustible one.
7.1.4.1. Use of inert gases. The gases commonly used for inert-
ing of hazardous dusts are nitrogen, carbon dioxide, water
vapour and rare gases. Selecting a suitable gas depends on var-
ious factors the principle one being the reactivity (or rather the
lack of it) of a gas with the dust for which it is used. For example,
CO
2
, which is otherwise a useful inerting gas for several dusts,
cannot be used with aluminum dust as it reacts violently with
it. At high temperatures, nitrogen reacts strongly with magne-
sium dust and hence cannot be used in process involving the
latter. Other factors are the availability and cost of supply of
the relevant gas. In situations where nitrogen or carbon dioxide
is incompatible with some powders, it is advisable to use rare
gases. Applying water spray or increasing the relative humid-
ity in the work area are the practical ways of inerting the dusts
during open operations such as shredding [41].
Inerting is done in the following way. The system is slightly
evacuated and then ushed with the inert gas until the original
pressure is regained. This is repeated until the desired level of
inerting is accomplished. If a high pressure systemis being used,
the inert gas may simply be pumped into the process vessels until
the desiredpressure is reached. Once inertinghas beendone, care
must be taken that no air leaks into the process. If a new gas is
introduced with the feed, it should also be inerted.
Often partial inerting is used where total inerting may be too
costly; this does not eliminate the chance of explosion, but limits
it substantively.
To accomplish partial inerting the gas (most often air) in
which the explosible dust is dispersed is mixed with a frac-
tion of inert gas (e.g. nitrogen) considerably smaller than that
required for complete inerting. This reduces both the explosibil-
ity and the ignition sensitivity of the dust cloud. The effects on
K
St
(explosion violence) and MIE (minimum ignition energy)
are particularly pronounced. This can facilitate the implemen-
tation of conventional protective methods that would otherwise
have been difcult to use. By using published data for coal dust
and the new European CEN standard for vent sizing, Eckhoff
[47] has shown that the minimum required areas for explosion
venting are reduced considerably, due to reduced K
St
and P
max
values, by even a moderate reduction in the content of oxygen
in the atmosphere. The author has also shown, using a quali-
tative probabilistic argument, how the marked increase of MIE
obtained by partial inerting would justify a further reduction of
minimum required vent areas.
In many cases the explosion hazard may be reduced markedly
by only a moderate reduction of the oxygen content. It has been
shownexperimentallybyGlor andSchwenzfeuer [126] that even
modest reductions of the oxygen content, can increase the mini-
mum ignition energies of dust clouds substantially. Devlikanov
et al. [127] report that K
St
is a linear function of the percentage
of oxygen in the gas phase (mixture of nitrogen and oxygen).
The IChemE Guide provides information on the factors gov-
erning the selection of a suitable gas for a process involving dust.
The IChemE Guide also cites certain rules of thumb relating the
maximum permissible oxygen concentration for carbon dioxide
(C
0
) and nitrogen (N
0
):
N
0
= C
0
2 = 1.3C
0
6.3
These rules are attributed to Germany and NFPA 69: 1978,
respectively. The maximum permissible oxygen concentrations
to prevent ignition, which are reported in the literature, are nor-
mally measured at ambient temperature. If it is proposed to use
inerting for dust at high temperatures (>100

C), the maximum

permissible oxygen concentration to prevent ignition should be
determined by tests. Likewise tests are called for if there is a
hybrid vapourdust mixture. With regard to the safety margin to
be employed, the IChemE Guide suggests a minimummargin of
2%. Thus if the maximum permissible oxygen concentration to
prevent ignition is 11%, the oxygen concentration should be kept
below9%. It alsorecommends partial inertingof larger plant vol-
umes, extended hot surfaces or high explosibility dusts (St 3).
There should be continuous monitoring of the oxygen content
of the gas in the plant and a trip system to shut the plant down
if the concentration rises towards a hazardous level. Since the
gas contains dust, there may be problems in the measurement
of the oxygen level. Experiments by Wilen et al. [128] reveal
that with the increasing initial pressure in the range 518 bar,
the limiting oxygen concentration (LOC) for inerting biomass
dust cloud goes up.
Schwenzfeuer et al. [129] have observed that LOC for igni-
tion of dust clouds by electrostatic discharges, or metal sparks
frommechanical impact, were signicantly higher than the con-
servative limit determined in standard tests, using a very strong
pyrotechnical ignition source.
Even as a reduction in the oxygen level at the process site
can prevent dust explosions, it may introduce a suffocation risk.
Adding a few vol.% of CO
2
to the gas mixture reduces the criti-
cal oxygen threshold for suffocation considerably. An inert gas
mixture utilizing this effect has been reported [130].
7.1.4.2. Use of particulate or liquid inertants. Use of
solid/liquid inertants can be made to achieve two objectives:
prevention of dust explosion or mitigation/control of dust explo-
sion. To achieve the rst objective, non-gaseous inertants must
be added to an otherwise explosible dust in sufcient quanti-
es to render the latter non-explosible. To achieve the second
objective a non-gaseous inertant should be quickly released
in adequate quantities in a process vessel, as soon as dust in
that vessel catches re to prevent the ame from propagating
further.
Solid/liquid inertants are extensively used to realize the sec-
ond of these objectivesthis aspect has been dwelt upon at
some length in Section 8.3. But the use of non-gaseous inertants
in dust explosion prevention is limited. It is principally done
in coal mines were rock dust (calcium carbonate, with or with-
out magnesium carbonate) is often sprayed in mine galleries to
reduce the explosion hazard posed by coal dust. The rock dust
acts as a thermal inhibitor by absorbing heat fromthe ame front
of an explosion. This quenches the ame and arrests its propaga-
tion. Smaller particles of rock dust are more effective than larger
particles though very ne particles suffer from the disadvantage
that agglomeration can occur [54]. Similar correlation between
the size and the effectiveness of an inertant has been observed
in several cases [117].
Inertant dusts are rarely used outside coal mines in prevent-
ing explosions. This is to prevent contamination of the original
material. Attempts to develop inertant dusts which can go on
with the main material through the process have been made;
for example Mintz et al. [131] have patented a system which
uses nely powdered refractories like MgO to completely inert
highly explosible dusts such as a 50:50 AlMg alloy.
7.2. Preventive steps for specic dusts/operations
7.2.1. Explosion protection when handling metal dusts
[132]
Metal dusts suspended in air during operations like grinding
pose explosion hazard which can be mitigated by the use of wet
grinding or the collection of the grinded dust by a wet medium.
In the manufacturing of metal powders such as aluminum or
magnesium, the process of inerting technique may be employed
to reduce the oxygen concentration present at the process site.
Nitrogen may be used as the inerting gas in the manufacture
of aluminum, and helium or argon may be used for magne-
sium. Other prevention practices, such as good housekeeping,
grounding/bonding, hot work permits, etc. should be routinely
observed. In addition, protective measures must also be taken.
7.2.2. Explosion protection when handling carbonaceous
dusts [133]
It is very difcult to prevent formation of an atmosphere
which is not susceptible to explosion hazard, in processes involv-
ing carbonaceous dusts. In theory, an explosive atmosphere can
be avoided by reducing the oxygen concentration using inerting
techniques. Inpractice, however, the verynature of the givenpro-
cess using carbonaceous dust may preclude inerting. For such
situations, the only options are avoiding ignition sources or using
explosion proof equipment.
If a mixer is closed, the circumferential speed of the mixing
element need not be limited. Circumferential speeds up to 10 m/s
can be tolerated during lling and emptying with a mixer not
lled to less than 70% of its volume, provided that the MIT of
the processed product lies above the limit values.
7.2.3. Precautions during dust separation
Dust separation may cause electrostatic charging which must
be inhibited by the following measures:
(i) Grounding of all conductive parts.
(ii) Use of electrically conducting ller material in the case
where the MIE<3 mJ; or there is a presence of ammable
gas; or vapours in the air are being cleaned.
(iii) Ensuring that all inner walls on which dust can impact at
high speed do not have any insulating inner coatings with
a high electrical break down strength.
8. Dust explosion damage control
Due to the myriad and complex ways in which dust explo-
sions can occur, it is more or less impossible to eliminate the
dust explosion hazard [90]. But control measures can drastically
reduce the damage caused by the explosions, both in terms of
lesser property losses and trauma, and lesser process shutdown
time.
The dust explosion damage control strategies revolve round:
(i) explosion containment;
(ii) explosion isolation;
(iii) explosion suppression;
(iv) explosion venting.
8.1. Explosion containment
If a dust explosion can be contained within a designated
space, much of the damage it may cause to the surroundings
can be controlled.
Containment is an attractive option, since it is an essentially
passive method and avoids the problem of relief disposal. It is
not usually practicable, however, to design the whole of a dust
handling plant so that it can withstand the pressures generated by
dust explosions. This is particularly the case with large plants.
Nevertheless containment is practicable in small-scale units
and on certain equipment. A grinding mill, for example, can be
made strong enough to withstand a dust explosion. The maxi-
mum explosion pressure for most ammable gases and dusts is
in the range 710 bar(g) [2,12]. But the static pressure is not the
sole criterion; the rate of pressure rise in a dust explosion being
high, the equipment must be able to withstand this dynamic load-
ing. The equipment should be designed on the basis of rotational
symmetry and avoid large at surfaces and angular parts. Partic-
ular attention should be paid to the points at which dust is fed or
withdrawn from the plant and to the connections between units.
When the powder/dust is highly toxic, complete and reliable
connement is absolutely necessary.
8.2. Explosion isolation
The objective of explosion isolation is to prevent dust explo-
sions from spreading from the primary explosion location to
other process units, workrooms, etc. As described earlier in
Section 4.6.2, due to pressure-piling, jet-initiated high initial
turbulence and turbulent jet ignition, very high pressure peaks
can be generated even in generously vented vessels necessitat-
ing effective means of explosion isolation in inter-connected
systems. Two approaches are commonly adopted: use of quick
acting shut-off valves, and material chokes.
For explosion isolation involving quick acting shut-off
valves, the valves are installed in pipes connecting one vessel
with another. The valves are activated by explosion detectors
which are equipped with pressure and/or optical sensors. The
former type is usually preferred, since an optical detector can be
blinded. But a pressure sensor may not detect very weak pressure
waves which an optical sensor is capable of detecting.
The time required for the valve to close depends on the dis-
tance between the remote pressure or ame sensor and the valve.
Also on the type of dust. The valve must close within 50 ms
or even quicker. This level of swiftness can be achieved by
using an electrically triggered explosive charge for releasing
the compressed air or nitrogen that operates the valve. The slide
valve must be sufciently strong to resist the high pressures of
510 bar(g) that can occur on the explosion side after the valve
closure. The pressures may even have a higher peak than this in
the event of pressure-piling or detonation [6,134].
Fig. 8. Explosion isolation devices: (a) worm (screw), conveyor and (b) rotary
valve.
Bartknecht [135] has discussed the ability of various types of
fast-closing slide valves to interrupt dust explosions in ducts.
The required closing time depends on the distance between
the remote pressure or ame sensor and the valve and on the
type of dust. This most often is obtained by using an electri-
cally triggered explosive charge for releasing the compressed
air or nitrogen that operates the valve. The slide valve must be
sufciently strong to resist the high pressures of 510 bar(g)
that can occur on the explosion side after valve closure (in the
case of pressure-piling effects and detonation, the pressures may
transiently be even higher than this).
Isolation can also be effected with a material choke and may
be consideredwhere it is necessarytohave a owof dust between
units. Two commonly used chokes are rotary valves and worm
conveyors (Fig. 8). Of these, a rotary valve, which is installed
vertically and is driven by a motor, is generally designed to act
as a dust explosion choke even in the absence of a head of dust
above it. If the valve is installed on the inlet of a hopper, there
should be arrangements to prevent the former from continuing
to turn if the hopper becomes overlled, since this could cause
ignition by overheating the dust or overloading the motor.
Schuber [136] and Siwek [137] have conducted extensive
studies of the conditions under which a rotary lock is capa-
ble of preventing transmission of dust explosions. Schuber has
provided a nomograph by which critical design parameters
for explosion-transmission-resistant rotary locks can be deter-
mined. The minimum ignition energy and minimum ignition
temperature of the dust must be known. However, the nomograph
does not apply to metal dust explosions. Moreover, explosions
of ne aluminum are difcult to stop by rotary locks.
A worm conveyor may be installed horizontally, vertically,
or inclined, and is driven by a motor. One turn of the helix is
removed to prevent the choke emptying if the feed is interrupted.
If the conveyor is mounted horizontally, a bafe plate is also
necessary.
There have not been many tests of the effectiveness of rotary
valves and worm conveyers as dust explosion chokes. Since the
residence time in a worm conveyor is much longer than that in
a rotary valve, the former may be expected to be more effective
as a dust explosion choke, but smoldering dust could still pass
through unless the motor is tripped [2,5,12].
8.3. Explosion suppression
If, in process equipment which harbor dust explosion hazard,
a system can be put in place which gets activated as soon as
an explosion begins to occur, suppresses it by swiftly adding
suitable inertants, and prevents it from re-building (Fig. 9), the
risk of explosions can be greatly reduced. Automatic explosion
suppression devices aim to achieve this objective.
An explosion suppression system must have four basic
attributes:
(i) It should respond to an explosion with minimumtime delay
by getting activated quickly.
(ii) It should inject a suppressant in adequate quantities within
a very short time in a manner as to counter the incipient
explosion and arrest the propagating ame.
(iii) To shut down the plant.
(iv) To prevent the plant from getting restarted until the explo-
sion hazard has been mitigated.
The effectiveness of suppression system depends on how
quickly the sensors respond to the emerging explosion and also
on the efciency of the suppressant injection system. The latter
should be capable of injecting a large quantity of suppressant in
a very short time and with adequate reach to all parts of the space
being protected. It should be capable of a high mass discharge
rate, a high discharge velocity and hence good throw and good
angular coverage.
The explosion detectors in suppression systems are similar
to the ones described in the preceding section. Innovations are
also done from time to time; for example Cybulski et al. [138],
addressing the problem of coal dust explosions in coal mines,
used solar panels for automatic detection of the coal dust ame
and simultaneous actuation of water barriers. The water was
contained in plastic bags, which were opened by a detonating
cordtriggeredbythe ame generatedpower fromthe solar panel.
Attempts to develop ever more quick explosion detection and
suppression systems also continue [79,95,117].
Detectors are available which are robust to most materials,
to condensation and corrosion, and to shock. In some cases use
is made of two detectors oriented in different planes. Activation
occurs when the pressure reaches its threshold value, typically
of the order of 0.05 bar. In some systems use is also made of the
rate of pressure rise.
The mechanisms of suppression of the explosion are: (1)
quenching, (2) free radical scavenging, (3) wetting and (4)
inerting. Of these the principal mechanisms are quenching, or
Fig. 9. Automatic suppression of an explosion in a vessel adapted from Barton
[20] and Lees [12].
abstraction of heat. The contribution of free radical scaveng-
ing is specic to the particular explosion reaction. Wetting of
unburned particles is applicable to liquid suppressants. There is
also some inerting effect.
The response time of the sensor to the explosion depends on
the size of the vessel. The explosion will propagate at the speed
of sound, giving a delay, or equalization time, of the order of
4 ms/m distance between the ignition source and the detector.
The response of the suppression system must be very rapid; the
time taken for the suppressant to reach the ame depends on the
discharge velocity, which initially is of the order of 40 m/s.
Two injection devices are in common use. One is a hemi-
spherical suppressor with chemical detonator installed inside the
vessel. This type is used with a liquid suppressant. It has a lim-
ited throw of about 2.5 m, and contains only a small quantity of
suppressant. The time to complete discharge is about 1030 ms.
It is suitable for protection of smaller vessels. Multiple injection
points can be more effective in containing the pressure build-up
than single injection ports.
The other injection device is the high discharge rate (HDR)
bottle, installed on the outside of the vessel and pressurized
with nitrogen at 20100 bar. This type is much more versatile,
being able to handle most common suppressants and available in
capacities from 0.003 to 0.1 m
3
. The time to complete discharge
is about 100 ms.
There are limits to the size of vessel which can be protected
by suppression; for very large vessels it may not be possible to
douse propagating ames or enfeeble emerging explosions by
suppressant injection. Over the years various gures have been
quoted for the limiting size. The gure given in FS 6016: 1974
was 115 m
3
. That quoted in the IChemE Guide is about 10 times
bigger: 1000 m
3
[139].
The design of a suppression systembeing a complex function
of the triggering pressure, geometry of the area to be protected,
nature of suppressant, the suppression system hardware, etc.,
computer-aided design (CAD) is being increasingly utilized to
cognize and balance various contributing factors, including, of
course, the costs. CAD also provides a means of quantifying
the effectiveness of a deployed explosion suppression system.
Likewise, insights for system design, operation, and control can
be obtained through mathematical modeling [11,110,140,141]
Simple design nomograms and equations, based on the cubic
law of the maximum rate of pressure rise (Section 6.3.6), have
also been derived to aid the design engineer in assessing the
effectiveness of explosion suppression in practice [139].
The common inertants. Halons have been widely deployed in
the past as both re extinguishing agents and explosion suppres-
sants. When released into processing equipment, halons could
suppress the explosion and then provide an inert blanket of gas
to preempt risk of re-ignition.
However, use of halons was fraught with the danger that if
the quantity deployed was insufcient, it would not only fail to
suppress an explosion but, instead, would enhance the latters
severity. There was also a toxicity hazard because halogen acid
gases would be generated as the consequence of halon dissoci-
ation [139]. For these reasons, as also their role as depletors of
stratospheric ozone layers, halons have been more or less phased
out of use.
Water, deployed as a rapidly injected water spray is an
efcient suppressant, particularly of explosions occurring in
hydrophilic dust. Water is ineffective against ammable gas
explosions and against hybrid gas/dust explosions. However,
if deployed very early in an explosion, water can have certain
degree of effectiveness in diffusing an incipient explosion. Water
has no chemical specicity and acts strictly as a thermal quench-
ing agent. It provides minimal post-explosion inerting, save that
it effectively wets hydrophilic materials rendering them less
ignitable. If injected in a super-heated state, water can be more
effective because steam provides a degree of post-explosion
inerting. The effectiveness of water can also be enhanced by
spiking it with suitable additives.
With the passage of time, powders such as the proprietary
mono-ammonium phosphate (MAP) are being increasingly pre-
ferred in explosion suppression systems. They have superior
suppression effectiveness to both halons and water and have
been shown to suppress even intense St
3
organic dust explo-
sions and also provide protection against metal dust explosion
hazards.
Dry chemical suppressants basically act as post-explosion
inerting agents provided that they remain in suspension in the
transport medium. They mitigate the primary explosion but do
not prevent a second or subsequent ignition of ammable gases
or of dust/gas hybrid explosion threats.
For the use of food processing industry, which cannot
use MAP due to its potential for product contamination,
effective water-soluble and food-grade-compatible inertants
such as sodium bicarbonate-based dry powder suppressant
(Dessikarb
TM
) have been developed.
The other two features associated with dust explosion sup-
pression systems shutting down the plant, and preventing it
from restarting till it is safe to do so are plant-specic. Stan-
dard techniques of instrumentation and control are used to link
these with the pressure sensors.
Attempts to standardize the design of explosion suppression
systems have led the European benchmark organization, CEN,
to propose a draft guideline [142] which, apparently, provides
greater exibility than the traditional approach [95].
8.4. Explosion venting
When all attempts to prevent a dust explosion have failed, the
explosionwouldoccur. If the explosioncanbe ventedeffectively,
its adverse impact can be minimized. Except when toxic dusts
are involved, venting can signicantly reduce the destructive
potential of a dust explosion.
At rst glance venting appears a rather simple operation to
execute. If a portion of the structure, prone to dust explosion,
is made considerably less pressure-resistant than the rest of the
structure by using members or thinner panels, the portion may
fail inthe earlystages of anexplosion. Bysizingsucha vent prop-
erly, it may be ensured that the vent becomes operative as soon as
the overpressure exceeds a certain safe threshold and sufcient
quantities of gas (and particulates) are let off quickly to pre-
vent the pressure in the protected area from reaching destructive
levels.
To size the vent area one needs an understanding of all the
factors which determine the severity of a dust explosion, includ-
ing inter alia, the geometry of the unit in which the provision
of explosion venting is being made, dust concentration, initial
pressure, initial temperature, initial turbulence, ignition source,
presence of ammable gas or inert gas/dust (Table 7). All these
factors inuence the explosion pressurein terms of rate as well
as extent of pressure rise. In addition one needs to consider the
reduced explosion pressure, vent opening pressure, vent area,
vent distribution, vent opening, and vent panel. If a duct is to
Table 7
Inuence of various factors on two key parameters associated with the design of dust explosion vents
Factor Effect on maximum explosion pressure Effect on maximum rate of pressure rise
Vessel size and shape Independent of vessel size, provided heat effects are disregarded. For
elongated vessels, heat loss is signicant and the maximum explosion
pressure less
Follows the cube root law, it is inversely proportional to
V
1/3
, and proportional to the surface area/volume ratio
Dust concentration Increasing concentration leads to higher explosion pressures, up to the
maximum explosion pressure after which it starts to fall
Up to the maximum rate of pressure rise, the rate of
pressure rise increases with concentration, after which it
decreases with further increase in concentration
Initial pressure There is little information on the effect of initial pressure, perhaps
because most dust handling plants operate at atmospheric pressures
a
There is little information on the effect of initial
pressure, perhaps because most dust handling plants
operate at atmospheric pressures
a
Initial temperature Net effect of higher initial temperatures is to reduce the maximum
explosion pressure
Increasing initial temperatures increase the maximum
rate of pressure rise (due to effect on combustion rate
and reduction in the moisture content)
Initial turbulence Weak effect on maximum explosion pressure Strong effect on maximum rate of pressure rise
Ignition source Effect of ignition source is complex and depends essentially on the
nature and strength of the ignition source
Effect of ignition source is complex and depends
essentially on the nature and strength of the ignition
source
Presence of ammable gas Not much data is available on the effect of presence of ammable gas Not much data is available on the effect of presence of
ammable gas
Presence of ammable gas
or an inert gas/dust
Not much data is available on the effect of presence of ammable gas Increasing concentration of inerts decreases the
maximum rate of pressure rise
a
For starch dusts, the maximum explosion pressure and the maximum rate of pressure rise is proportional to the initial pressure, for initial pressures up to 2 bar.
be xed to the vent, its impact on the explosion venting pro-
les is to be considered, too. But, in spite of extensive R&D, the
basic understanding of these processes inside and outside vented
enclosures is still incomplete; the ways in which the dust clouds
are generated or the manner in which the clouds burn, are not
clearly understood either [95,143].
Furthermore, protecting the vented enclosure is not the only
important concern in dust explosion venting. The blast waves
and ames which are emitted into the surroundings by the vent
can be hazardous, not to speak of the risk posed to the per-
sonnel by unburned dust, smoke and soot which may suddenly
spewfromthe vent in copious manner [144146]. The maximum
ame length emitted from a vent can be up to 10 times the cube
root of the vented vessel volume [147]. If too much unburned
ammable material is ejected by a vent it may even get ignited by
the vented ame to cause a secondary explosion [148,149]. The
challenge of vent design thus extends to eliminating hazardous
effects of vented material, especially the ames. Then, again,
care has to be taken so that the provisions for safe venting do
not interfere with the effectiveness of the venting. For example a
duct if tted to a vent may safely discharge the vented mass and
energy but may, in the process, prevent sufcient dampening of
the explosion pressure [95,150,151].
These perils notwithstanding, venting is arguably the most
widely used method for mitigating dust explosions.
8.4.1. Approaches to vent design
The design of dust explosion venting has been approached
in a manner similar to the one for gas explosion venting. How-
ever, certain essential differences between gas explosions and
dust explosions are cognized: whereas a gas explosion can occur
even when the gas mixture is initially quiescent, a dust explo-
sion can occur only if there is turbulence. Also, dust clouds are
rarely uniform unless they are formed under highly turbulent
conditions [12].
The design approaches may be empirical (Table 8a) or the-
oretical (Table 8b). Future work in this eld may include
development of methods based on computational uid dynamics
and other computer-aided mathematical modeling techniques.
Empirical approaches, summarized in Table 8a, suffer from
difculties inherent in characterizing dust explosibility. Further-
more, dust explosions are sensitive to so many factors (Table 6)
that it is very difcult to reproduce them experimentally. Never-
theless protocols for scaling up experimental studies have been
developed leading to the several empirical methods summarized
in Table 8a. Comparative studies on the efcacy of these meth-
ods [2,12,152] reveal that: (a) the vent ratio method tends to
overestimate the explosion pressure while the vent coefcient
method underestimates it; (b) the K
St
method gives good pre-
dictions in its low ignition energy source nomographs but tends
to underestimate the explosion pressure; (c) if reliable Hartman
bomb data are available, the method of Schwab and Othmer
yields good results. The K
St
method can yield vent areas up
to three times larger than the experimentally determined values
but it has been argued that this provides a valuable safety fac-
tor, more so when the standard test conditions under which the
experimental results are generated can differ substantially from
the happenings in an actual plant [149]. Eckhoff and Fuhre [153]
and others have shown that in most industrial processes the dust
clouds produce less violent explosion than those to which the
monographs apply, but the method continues to be favored due
to the safety margin it generates.
Table 8a
Empirical methods for dust explosion vent design
Method Formula/procedure Description References
Vent ratio method Graphical correlations are developed between explosion pressure in vessels
and the vent ratio, f, required to dampen the explosion, Where,
Plots of required vent area vs. the reduced explosion pressure, covering a
wide range of vessel volumes have been published. This can be used under
the following conditions:
[4,6,152,190,191]
f =
Av
V
1. P
red
0.14 bar(g)
A
v
is the vent area and V is the volume of the enclosure. 2. Opening pressure and vent inertia are small
Vent coefcient method The vent coefcient, K, is given by The results from the experiments conducted on St 2 dusts give a good t
for K=3, when vent area is plotted vs. vessel volume.
[192]
K =
Ac
Av
A
c
=L
1
L
2
where A
c
is the area of the smallest cross-section of the enclosure, and L
1
and L
2
are the two smallest dimensions of the enclosure.
K
St
method for vessels
without ducts
Nomographs for calculating vent area are developed, based on the cube
root law.
Three separate nomographs have been made, for vent opening pressures
P
stat
values of 0.1, 0.2 and 0.5 bar(g) and reduced pressure P
red
range from
0.2 to 2 bar(g). The K
St
used here has to be measured using the 1 m
3
ISO
standard apparatus. The nomographs can be used for the following
conditions:
[114,193,194]
1. Dusts with K
St
300 bar m/s, P
max
10 bar(g)
2. Dusts with 300 <K
St
600 bar m/s, P
max
12 bar(g)
3. Vessel volume V1000 m
3
4. P
stat
1.1 bar(a)
5. P
red
1.2 bar(a)
6. 10 bar m/s K
St
600 bar m/s
7. Vessel length to diameter ratio less than 5:1
8. No ducts tted to the vents
K
St
nomograph method
for vents with ducts
Four sets of graphs are used in conjunction with the K
St
nomograph
method described above
The method enables the following assessments: [144]
1. Effect on the reduced explosion pressure of straight vent ducts
2. Effect on the reduced explosion pressure of vent ducts having a 45

bend
3. Effect on the reduced explosion pressure of vent ducts having a sharp
90

bend
4. Effect on the reduced explosion pressure of straight vent ducts for
metal dusts in the St 3 group
The graphs are valid for vent ducts of circular cross-section, lengths less
than 16 m, and the vent cross-section area equal to the ducts.
The draft European standard
equation for single
enclosures, for
P
red
0.1 bar(g)
A
v
= [3.264 10
5
P
max
K
St
P
0.569
red,max
+0.27(P
stat
0.1)P
0.5
red,max
]
V
0.753
_
1 +(4.305 logP
red,max
+0.758) log
_
L
D
_
This equation is valid only if: [175,195]
Table 8a (Continued)
Method Formula/procedure Description References
Where A
v
is the vent area, P
max
is the maximum explosion pressure,
P
red,max
is the reduced explosion pressure, L is the enclosure length and D
the enclosure diameter.
1. 0.1 m
3
V10,000 m
3
2. 0.1 bar(g) P
stat
1 bar(g)
3. P
stat
<P
red,max
2 bar(g)
4. 5 bar(g) P
max
10 bar(g) for K
St
300 bar m/s
5. 5 bar(g) P
max
12 bar(g) for 300 bar m/s <K
St
800 bar m/s
6. Dust cloud is homogenous
7. L/D20, or minimum vent area greater than the cross-sectional area
of the vessel for end venting
The draft European standard
(prEN) method for vent
with ducts
P
red,max
P

red,max
= 1 +17.3
_
A
V
0.753

1.6
L This method is applicable under the following conditions: [195]
Where A is the vent area (m
2
), V is the vessel volume (m
3
), L is the vent
duct length to diameter ratio, P
red,max
is the reduced explosion pressure
without a vent duct (bar), and P

red,max
is the reduced explosion pressure
with a vent duct (bar)
1. The initial sizing of the vent, before the duct is tted, should have
been done by using the method described above
2. The duct is straight, without any bends
3. The duct is tted to an isolated enclosure
4. 0.1 bar P
red,max
2 bar
5. The vessel is cubicle
6. Dustair mixture is homogenous
NFPA formula for dust
explosions in buildings
A
v
=
C
1
As
P
0.5
red
This formula applies principally to buildings, but also to low-strength dust
handling plants and similar enclosures [20], P
red
<0.1 bar
[196]
Where A
v
is the vent area, A
s
is the total internal surface area of the
enclosure and C
1
is a factor whose value depends on the K
St
of the dust
Schwab and Othmer method Y =
A
10
KX
Nomographs have been developed based on this method to determine vent
ratio, given the maximum explosion pressure, maximum explosion
pressure in vented explosion and the maximum rate of pressure rise.
[197]
Where A is the maximum pressure in the unvented explosion (psi), X is the
vent ratio (ft
2
/100 ft
3
), Y is the reduced pressure in the vented explosion
(psi) and K is the slope of the line of the maximum pressure (A) vs. vent
ratio (X)
Runes method This is not a strictly empirical method but has some theoretical basis: the
rate of volume increase is equated with volumetric vent outow, leading to
the Runes equation:
NFPA (1978) has reported Runes constant for organic dusts and high
ame speed metal dusts. Later in 1994, NFPA (1994) has given a
relationship similar to Runes equation containing a constant, C, of which
values for different St dusts have been reported.
[191,193,198]
A
v
=
CAc
(P)
1/2
Where P is the explosion overpressure, A
c
is the area of the smallest
cross-section of the enclosure and C is the Runes constant
Swedish method A =
0.019V
0.635
P
0.5
red
for
_
dP
dt
_
max
300 bar/s, and hinged vent panels have a
maximum mass of 20 kg/m
2
The
_
dP
dt
_
max
to be used in this method has to be determined from standard
1.2 Hartmann bomb tests.
[6,199]
A =
0.044V
0.685
P
0.5
red
for 300 <
_
dP
dt
_
max
<600 bar/s, and hinged vent panels
have a maximum mass of 12 kg/m
2
Where A is vent area (m
2
), V is volume (m
3
) and P
red
is in bar (g)
Table 8b
Theoretical methods for dust explosion vent design
Method Formula/procedure Description Reference
Heinrich method The vent area, A
v
, is given by: This formula has been derived by equating the rate of generation of burned
gas to the mass velocity of vent outow, assuming isothermal conditions.
Nomographs have been developed based on this approach.
[200]
A
v
=
V
2/3
V
1/3
L
(dPex/dt)
P
red
,V
L
C
d
(2RT/M)
1/2
P
1/2
red
(P
red
Pa)
1/2
Where V is the volume of the vessel to be vented, V
L
is the volume of the
test vessel, C
d
is the coefcient of discharge, M is the molecular weight of
the gas, T is the absolute temperature of the burnt gas, P
a
is the
atmospheric pressure, P
red
is the reduced pressure and P
ex
is the pressure
due to the explosion.
Palmers method For the case when the venting pressure is close to atmospheric pressure
(low pressure case):
[201]
P P
0
=
2.3P
0
c
C
2
d

2
P
3
max
_
V
Av
_
2
_
dP
dt
_
2
max
For the high pressure case:
1
PP
0
=
1
PmaxP
0
+
KAvPmax
0.8Vc(dP/dt)
max
K = C
d
_

P
0
_
2
+1
_
(+1)/(1)
_
1/2
Where P
0
is atmospheric pressure,
c
is the density of the unburned gas at
P
0
, C
d
is the coefcient of discharge,
0
is the density of the gas at
atmospheric pressure, is the ratio of specic heats, P
max
is the maximum
unvented explosion pressure, V is the volume of the enclosure, A
v
is the
vent area
Rusts method A
v
=
kF(PmaxV)
2/3
K
1/3
D
P
1/2
red
This method was derived for the venting of dust explosions in low-strength
plants, for a dust mixture initially at atmospheric pressure.
[202]
Where A
v
is the vent area, K
D
is an explosion parameter which can be
determined from the pressure rise in tests, F is a shape factor to take into
account non-spherical vessels, k is a constant (=8.35 10
5
,
when A
v
is
expressed in FPS units), P
max
is the absolute maximum pressure of the
unvented explosion and P
red
is the reduced pressure (gauge).
Nagy and Verakis method For the case of dust explosion in a cylinder with an open vent, assuming
that the ignition takes place at the closed end and there is subsonic ow of
the vented burnt gas:
This model has been adapted from the one developed by the authors for gas
explosion.
[107]
P
red
(P
red
P
0
)
1/2
=
RTuk
v1
P
0
L(Av/V)
T
1/2
b
Su(PmP
0
)
For the case of initially closed vent, with all the other assumptions same as
above, the equation is:
P
red
+Pv
(P
red
P
0
)
1/2
=
RTuk
v1
P
0
L(Av/V)
T
1/2
b
Su(PmP
0
)
Where T is the absolute temperature, P is the absolute pressure, V is the
vessel volume, A
v
is the vent area, L is the length of the cylinder, k
v1
is a
constant, S
u
is the burning velocity, is the coefcient of turbulence, the
subscripts b, m, o, u denote burned, nal, initial and unburned,
respectively, P
v
is the vent opening pressure.
Note: P
red
the residual overpressure from a vented explosion, P
stat
is the static activation gauge pressure.
The theoretical methods for dust explosion vent design
(Table 8b) also rely heavily on experimental data [2,12]. The
Heinrich method gives upper limits of the reduced pressure for
St 1 and 2 dusts, but should not be used for St 3 dusts. The Palmer
method gives good predictions for St 1 and 2 dusts, but tends
to underestimate the reduced pressure for St 3 dusts in larger
vessels. The Rust method is better for St 1 dusts than for St 2
and 3 dusts, and can be highly inaccurate in some cases. The
Pittsburgh method requires information on the burning veloc-
ity and turbulence factor which are generally not available; the
method is therefore, of limited application [2,12]. Tamanini
[154], in the course of a comparative study of scaling parameters
of vented gas and dust explosions has recorded that different
vent sizing formulae (tables) lead to proportionality between
the reduced pressure and the peak unvented pressure raised to a
power between 5/3 and 1.
An excellent do-howmanual on dust explosion control, espe-
cially vent design, has been produced by Barton [20].
8.4.2. Factors inuencing the venting process
Several factors, besides the dimension of the vent opening,
inuence the effectiveness of dust explosion venting.
8.4.2.1. Vent ducts. Ducts have to be attached with most vents
so that the blast waves, unburnt material, and ame exiting from
a vented dust explosion do not injure staff working outside the
vented enclosure, damage other units, or cause secondary explo-
sion. But ow through the vent is impeded to some extent by
ducts, causing an increase in the explosion overpressure inside
the vented plant. The increased overpressure may be due to a
secondary explosion in the duct (burn-up) [155,156], frictional
drag and inertia of the gas column in the duct [157], acoustic
[158] and Helmholtz oscillations [159].
The turbulent mixing of hot and fresh gases in the initial
section of the duct after the ame entrance promotes a violent
burning therein (an explosion-like combustion or burn-up).
The resultant pressure impulse in the duct induces backow of
gases from the duct to the vessel with the possible consequent
turbulization of residual combustion in the vessel and the block-
age of the gas efux. Some authors have singled out burn-up
as the main factor responsible for the dramatic increase of the
pressure in the vented vessel [160,161]. Some others believe
that the additional pressure drops due to the resistance of the gas
owin the vesselduct assembly is the main cause for the higher
pressure rise in the ducted vessel with respect to simply vented
vessels [162,163]. Substantial pressure drops may occur due to
the very high ow velocities attained at the duct entrance and
the concentrated losses in the sudden ow area changes at the
duct exit. Zero-dimensional and one-dimensional mathematical
models [155,162] suggest that the enhancement of the burning
rate through turbulization and the friction losses are the most
important phenomena affecting overpressure [164].
Ferrara et al. [165], using a CFDmodel based on the unsteady
Reynolds Averaged Navier Stokes (RANS) approach for the
numerical simulation of a ducted explosion, saw that the burn-
up related effects are the key phenomena in determining the
pressure rise in the ducted venting conguration. This was in
agreement with the experimental ndings of Ponizy and Leyer
[156] and Molkov [166,167]. It was seen that the reduction of
venting rate (mechanical effect) rather than the burning rate
enhancement through turbulization (combustion related effect)
was responsible for the recorded overpressure. Simulation, car-
ried out by varying the duct diameter and length and the ignition
position revealed that the latter affected strongly the vessel over-
pressure through the combustion of the residual unburnt mixture
in the vessel after burn-up. With respect to geometrical param-
eters, numerical ow eld representations indicated that larger
duct sections are not a priori benecial to relieve the pressure
in the vessel, due to the ame distortion effects [165].
In a study with four types of dusts varying widely in explosion
characteristics, and ducts of two sizes, Lunn et al. [149], have
observed that the difference between the vent duct area and the
effective vent area, and the explosion characteristics of the dusts
are important factors in decreasing the effect of vent ducts below
the levels predicted by theory. The logistics of an industrial unit
often makes it necessary for the ducts to have one or more bends.
Such bends hamper reduction in the explosion pressure; closer
a bend from the vent, greater the effect.
Design considerations for vents with and without ducts have
been reviewed by Barton [20]. Vent ducts with area less than, or
much greater than, the vent area are forbidden. Gradual bends
are recommended instead of sharp bends as their interference in
the venting efciency is lesser. Multiple bends must be avoided
as far as possible; their effect on the reduced explosion pressure
is far greater than a single bend. No bend should be located closer
than 2 m from the vent opening. Explosion pressure in the vent
duct can be as high as that in the explosion vessel; some pressure
pulses inthe duct canevenbe higher. The ductingshouldbe made
correspondingly strong to withstand these pressure loads.
Even light-weight weather-protection devices tted to vent
ducts can hamper the vents action but a grating over the end of
a vent duct (to keep out pests) does not have a noticeable effect
on the explosion pressure.
8.4.2.2. Recoil. When a dust explosion is being vented, the ow
exiting from the vent produces reaction forces in the direction
opposite to that of the ow. If there is a resulting imbalance, a net
force would develop in the nature of a recoil which needs to be
counteracted by providing appropriate supports to the structure.
Expressions correlating maximum recoil force developed,
vent area, maximum pressure rise inside the vented enclosure,
andother relatedparameters have beendeveloped byFaber [168]
and Harmanny [169]. Building upon this work, Tamanini and
Valiulis [151] have developed a new correlation which links the
average recoil force, F
R
, the duration, t
D
, and the impulse, I, of
vented explosions as under:
I = F
R
t
D
, F
R
= 0.6(p
r
p
c
)A
v
andt
D
=
v(p
m
p
1/2
0
)
a
cd
A
v
(p
r
p
0
)
where p
0
, p
c
, p
m
, and p
r
are initial pressure,
external pressure, maximum pressure, and maximum unvented
pressure, respectively; V (m
3
) the volume of the vented enclo-
sure, and a
cd
is a dimensional constant equal to 232.5 m/s.
According to the authors, their correlation has a surer theoreti-
cal foundation and has been more rigorously validated than the
earlier treatments.
Their preliminary results have shown that the correlations
also apply to situations where nal inertia effects are present,
provided that such effects are contained.
If a vent is tted with a duct, the recoil is experienced by
the duct as well. Lateral reaction forces also occur if the duct
contains a bend. Hence provision for withstanding the reaction
forces must be made for ducts as well as the vents.
8.4.2.3. Venting devices. Venting devices range from light-
weight burst disks or membranes to much heavier explosion
doors. An ideal device should begin to open only at a predictable
pressure. The inertia of the device should be such that it begins
to open when the overpressure reaches a threshold level.
A venting device should not open inadvertently or leak sig-
nicant quantities of dust but should open quickly enough when
it is supposed to [20].
It is preferable that vent areas are located on different walls of
a building rather than be all placed on the same wall. Restrictive
devices such as a hinge or a chain should be attached to vent
panels to prevent the panels from ying off in the event of a
vented explosion. As the panels can swing outwards violently,
get unhinged and propelled, or even shatter into ying fragments
during the venting process, consideration should be given to the
space into which the panel would open. Materials of a brittle
nature which may shatter into pointed projectiles should not be
used for vent panels.
Vent closures should be pre-tested both for their mechanical
strength and opening pressure, P
star
.
The venting process is strongly inuenced by the inertia of the
vent closure, expressed as kg/m
2
. As this increases, the venting
process is progressively impeded and, for a specied vent area,
the reduced explosion pressure, P
red
, begins to rise.
The effect of inertia is determined by comparing the venting
effectiveness of a given vent closure with one that is essen-
tially inertia free and so has a venting efciency of 100%; for
example, bursting diaphragm. The venting efciency is given
by (A
e
100/A
d
)%, where A
d
is the geometrical vent area of the
vent closure and A
e
is the effective vent area. Thus, in practice,
the geometric vent area necessary to give safe venting of a given
enclosure would be greater than the vent area estimated by the
vent sizing methods to an extent depending on the venting ef-
ciency. If the estimated vent area necessary to protect a given
enclosure was, say, 2 m
2
, then a geometric area of 4 m
2
would
be necessary if the vent closures had a venting efciency of 50%
[20].
It has been experimentally determined that, except at very
small volumes, the effect of panel inertia up to 10 kg/m
2
is
negligible. Thus, for closures with inertia of 10 kg/m
2
, 100%
efciencycanbe assumedinvent area calculations [20,170,171].
8.4.2.4. Turbulence. Effect of turbulence on explosion venting
has been studied extensively [5,121,170,172174]. Three types
of turbulence have been identied:
(i) Turbulent motions which exist before ignition of the
ammable mixture, for example these driven by fans.
(ii) Turbulence generated during ame propagation due to dif-
ferent phenomena like ame wrinkling, expansion of hot
gases, ame stretching, obstacles and others.
(iii) Turbulence created by the ejection of gas during venting.
The interactions between ow eld, turbulence, and ame
are not only complex but very from process equipment to pro-
cess equipment. Even pre-ignition turbulence of a moderate
level (about 0.45 m/s) may lead to a considerable increase in the
reduced explosion pressure and in the maximumrate of pressure
rise during a vented explosion [174].
8.4.2.5. Venting of interconnected vessels. Most industrial dust
handling plant consists of vessels linked by pipelines. As
detailed earlier in Section 4.6.2, if dust explosion occurs in one
of the vessels, there is increased turbulence and pressure-piling
in the other vessels which may cause secondary explosions to
be more severe than the primary explosion.
The Germany-based institution VDI in its guidebook no.
3673 [175] has given the following rules of the thumb:
(i) When the larger of the enclosures cannot be vented, then
the entire system must be designed for full containment.
(ii) When the smaller of the enclosures cannot be vented, then
it must be designed for containment and the vent area of
the larger vessel determined directly from representative
explosion trials or appropriate published data.
(iii) When the enclosures are of equal size, and one enclosure
cannot be vented, (ii) applies.
Holbrow et al. [176] have given guidelines for estimating
the vent areas for some linked systems based on the results of
an experimental investigation. The following rules have been
derived that can be applied up to vessel volumes of 20 m
3
:
(i) For K
St
values of 150 bar m/s or less, a dimensionless vent
area (A
D
) in both vessels of greater than 0.25 will limit the
reduced explosion pressure to 0.5 bar. A
D
=A
v
/V
2/3
, where
A
v
is the vent area and V is the vessel volume.
(ii) For K
St
values between 150 and 250 bar m/s, a value of A
D
in
both vessels of 0.4 will limit the reduced explosion pressure
to 0.5 bar.
The venting area shall be divided between enclosures so that
A
D
is the same in both enclosures. When venting a system of
linked enclosures, the venting devices should be designed for a
low static activation overpressure, P
stat
0.1 bar.
As the vent area decreases, the relative effect of linking the
vessels increases. The increase in pressure is greatest when
primary ignition occurs in the larger of the linked vessels. Gen-
erally, the longer the pipe the less is the effect on the explosion
pressure, but this is not always so [20].
Even as, in recent years, our understanding of the dust explo-
sion venting process has increased considerably, this has not
provided us with simple, rule-of-thumb answers to vent design
problems. On the contrary, more the new experimental evidence
is generated, more we realize that dust explosion venting is an
exceedingly complex process. What may happen with a given
dust under one set of practical circumstances may be totally dif-
ferent from what may happen in others [6]. The classic dilemma
in all safety-related design efforts, viz. how to balance the fear
of failure with the extra cost of over-design continues to dog the
eld of dust explosion venting as well!
8.5. Expert systems
The early attempts to develop expert systems (software) for
dust-explosion vent design included Dust-Expert [177,178] and
ExTra [179]. Over the years newer versions of these software
have been developed [180,181] as also newer systems have
appeared [182,183] but they all continue to be based on K
St
inputs.
Hesener et al. [181] and Kraus et al. [184] have devel-
oped an expert system to be used to identify hazards due to
the possible occurrence of various types of electrostatic dis-
charges in various process situations. The system, using the
CEN-ELECreport R044-001 as its technical basis, covers explo-
sive gases/vapours/mists as well as explosible dusts.
Lorenz [185] has presented an expert system for the design
of explosion venting arrangement based on the VDI 3673 vent-
ing code, which is very close to the new European Union code
produced by CEN TC 305. The system accounts for the iner-
tia of vent covers and doors and assesses forces acting on these
covers and doors. The extent to which debris is ejected into
the surroundings by destructive explosions is also accounted
for. Lorenz and Schiebler [186] have presented an expert sys-
tem incorporating the four programs SIMEK, STS, Vent, and
Vessel dealing with the design of explosion doors and lids,
ejection of debris, venting assuming zero mass vent covers,
and the stability of pressurized enclosures, respectively.
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