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Phy Chem

This document contains 7 chemistry problems involving calculations of molar mass, freezing point depression, ionic strength, dissociation, vapor pressure, and normal boiling point for various solutions. The problems provide data on changes in vapor pressure, freezing point, or osmotic pressure when compounds are added to solvents like benzene, CCl4, naphthalene, or water. The goal is to use this data to calculate values like molar mass, freezing point, vapor pressure, and dissociation percentage.

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435 views

Phy Chem

This document contains 7 chemistry problems involving calculations of molar mass, freezing point depression, ionic strength, dissociation, vapor pressure, and normal boiling point for various solutions. The problems provide data on changes in vapor pressure, freezing point, or osmotic pressure when compounds are added to solvents like benzene, CCl4, naphthalene, or water. The goal is to use this data to calculate values like molar mass, freezing point, vapor pressure, and dissociation percentage.

Uploaded by

anon_632542580
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
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Phy Chem

1. The vapour pressure of benzene is 400 Torr at 60.6C, but it fell to 386 Torr when 19.0
g of an involatile organic compound was dissolved in 500 g of benzene. Calculate the
molar mass of the compound.
2. The addition of 100 g of a compound to 750 g of CCl4 lowered the freezing point of the
solvent by 10.5 K. Calculate the molar mass of the compound.
3. The addition of 5.00 g of a compound to 250 g of naphthalene lowered the freezing
point of the solvent by 0.780 K. Calculate the molar mass of the compound.
4. The osmotic pressure of an aqueous solution at 300 K is 120 kPa. Calculate the
freezing point of the solution.
5. Compare the ionic strengths of 0.1 N solutions of HCl, SrCl2, AlCl3, ZnSO4, and
Fe2(SO4)3.
6. A 0.01 molal solution of K3Fe(CN)6 freezes at -0.062 C. What is the apparent
percentage of dissociation?
7. A 0.4 molal aqueous solution of K2SO4 freezes at -1.52 C. Assuming that i is constant
with temperature, calculate the vapor pressure at 25 C and the normal boiling point of
the solution.

Phy Chem
1. The vapour pressure of benzene is 400 Torr at 60.6C, but it fell to 386 Torr when 19.0
g of an involatile organic compound was dissolved in 500 g of benzene. Calculate the
molar mass of the compound.
2. The addition of 100 g of a compound to 750 g of CCl4 lowered the freezing point of the
solvent by 10.5 K. Calculate the molar mass of the compound.
3. The addition of 5.00 g of a compound to 250 g of naphthalene lowered the freezing
point of the solvent by 0.780 K. Calculate the molar mass of the compound.
4. The osmotic pressure of an aqueous solution at 300 K is 120 kPa. Calculate the
freezing point of the solution.
5. Compare the ionic strengths of 0.1 N solutions of HCl, SrCl2, AlCl3, ZnSO4, and
Fe2(SO4)3.

6. A 0.01 molal solution of K3Fe(CN)6 freezes at -0.062 C. What is the apparent


percentage of dissociation?
7. A 0.4 molal aqueous solution of K2SO4 freezes at -1.52 C. Assuming that i is constant
with temperature, calculate the vapor pressure at 25 C and the normal boiling point of
the solution.

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