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Iit Paper II Solutions

The document provides solutions to 20 questions from a chemistry model paper for IIT-JEE. It includes the answers and short explanations or working for multiple choice and numerical questions covering topics like reactions, stoichiometry, gas laws, properties of ions in solution, and graphs of functions. The highest number of questions answered correctly was for question 5 with 4 options being the right answer. The document provided full solutions for questions 2, 3, 11, 14, 20 and partial solutions for other questions to explain the reasoning behind the answers.

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0% found this document useful (0 votes)
66 views

Iit Paper II Solutions

The document provides solutions to 20 questions from a chemistry model paper for IIT-JEE. It includes the answers and short explanations or working for multiple choice and numerical questions covering topics like reactions, stoichiometry, gas laws, properties of ions in solution, and graphs of functions. The highest number of questions answered correctly was for question 5 with 4 options being the right answer. The document provided full solutions for questions 2, 3, 11, 14, 20 and partial solutions for other questions to explain the reasoning behind the answers.

Uploaded by

RajeshKP65
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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SOLUTIONS FOR IIT-JEE MODEL PAPER -2

PUBLISHED ON 04-04-2011 IN EENADU PRATIBHA PAGES.


CHEMISTRY
1.
Ans. : C
2.
Sol.

Ans. : A
(MH4)2Cr2O7 Cr2O3 + N2 + 4H2O.

3.

Ans. : B

Sol.

TC =

4 x2
8a
= 282
(1 x )( 2 x ) 27 Rb

a
= 50
27b 2
282 R
Divide; b =
= 0.0578 L mole-1.
50 8

PC =

4.

Ans. : A

Sol.

K = 50 =

5.
Sol.

Ans. : ABCD

4 x2
2x = 1.87.
(1 x )( 2 x )

Fe2+
White ppt
No change
White ppt
Deep blue

NaOH
KCNS
K4[Fe(CN)6]
K3[Fe(CN)6]

Fe3+
Red-brown ppt
Blood red solution
Dark blue ppt
Brown solution

6.
Ans. : ACD
7.
Ans. : ABCD
8.
Ans. : ABCD
9.
Ans. : ABCD
10.
Ans. : A PQ; B PQ; C PQS; D PR;
11.
Ans. : A Q B PR; C QS; D PR;
12.
Ans. : 6
13.
Ans. : 1
14.
Ans. : 5
15.
Ans. . 12.5 ml
16.
Ans. : 0
17.
Ans. : 2
Sol. m = 0, n = 2
18.
Ans. : 8
19.
Ans. : 6
Sol. 1s2, 2s2, 2p6, 3s2p6, 3d6
Sol. Paper - 2
20.
Ans. : C
Sol. f is continuous throughout on (3, 2)
3(2 + x) 2 ; 3 < x < 1
4R
f(x) =
i + j k 2 a1/3
14
; 1 < x < 2
{0}
x
x
f is not differentiable at x = 1, and x = 0
f(x) > 0 / x (3, 1)
------increasing function
f(x) < 0 / x (1, 0)
------decreasing function
f(x) > 0 / x (0, 2)
-------increasing function
f(x) = 0 only at x = 2, which is a point of inflexion.
At x = 1, f takes max. value.
At x = 0, f takes min. value.

21.
Sol.

Ans. : B
The number of zeros at the end of the product = the power of S in the product
= 6 + 11 + 16 + 21 + 52 + 31
= 137

22.
Sol.

23.
Sol.

Ans. : C
3
The graphs of y = tan x and y = x intersect at x = 0 and in the intervals x ,
2

2 ,
,
2

Ans. : D

uuur

i + 3 j 2k 3i + j 2k
OC = R OA + OB = R
+

14
14

R
4R
=
4i + 4 j 4k =
i + jk
14
14

24.
Sol.

25.
Sol.

Ans. : AC
f(x) = |2 x| + (2 + x)
f(2) = |2 2| + (2 + 2) = 4
f(2) = 0 + (2 + 2 h) = 4
f(2+) = 0 + (2 + 2 + h) = 5.

f is not continuous at x = 2, and therefore


not differentiable at x = 2

Ans. : BC
px
qx
qx
cos 2
= 1 cos 2
= sin 2
2
2
2
px
qx
2 cos 2
1 = 2sin 2
1 cos px = cos qx
2
2
cos px + cos qx = 0
p+q
pq
cos
x cos
x = 0
2
2
p+q

either
x = odd multiples of
= ( 2k + 1)
2
2
2
x = ( 2k + 1)

p+q

or x = ( 2k + 1)

pq

26.
Sol.

Ans. : BC
If m is fixed then the set of lines are parallel.
If x1 is fixed, all parallel lines cut x = x1.

27.

Ans. : ACD
m n +1

Sol.

28.
Sol.

29.
Sol.

n+2

m n +1

f (n) = n ! (n + 1)! (n + 2)! = n ! = 1


1
1
1
1
2
= n! (n + n + 1).

n+2

n + 1 (n + 2)(n + 1)
1
1

Ans. : AD
If n is even,
Sn = (12 + 22 + 32 + .. + n2) + (22 + 42 + .. n2)
2

n(n + 1)(2n + 1)
n
2 2
2
2
=
+ 2 1 + 2 + 3 + ....

6
2

nn
2
+ 1 ( n + 1)
n ( n + 1)
n(n + 1)(2n + 1)
22
=
+4
=
6
6
2
If n is odd, then (n 1) is even,
(n 1)n 2
n 2 (n + 1)
2
2
Sn = Sn 1 + n =
+n =
2
2
Ans. :A Q, B S, C P, D R.
A.. a2 b2 c2 + 2bc
1
bc sin A = 2bc cos A + 2bc 4 cos A + sin A = 4
2
tan A/2 = tan A = 8/15
B. tan A = 3k, tan B = 4k, tan C = 5k

In ABC, tan A = tan A 12 k = 60k3 k =


tan A =

1
5

3
4
5
, tan B =
. Tan C =
5
5
5

3
4
5
2 5

=
7
14
21
30
1 sin 2 + cos 2
5
C. f ( ) =
and + =
then value of f( ) f()
2 cos 2
4
1
f ( ) =
(upon simplification)
1 + tan
tam + tan
tan( + ) = 1 =
1 tan tan = tan + tan
1 tan tan
1 + tan + tan + tan tan = 2
(1 + tan ) (1 + tan ) = 2
Tanking reciprocals, f() f() =
1
2
4
D. S = tan 1 + tan 1 + tan 1 + .....
3
9
33
n
n 1
2 1
1 4 2
1 8 4
1 2 2
Sn = tan 1
+
tan
+
tan
+
....tan

1 + 2n.2n1
1 + 2.1
1 + 4.2
1 + 8.4

-1
-1
-1 2
-1
-1 3
-1 2
-1 n
= tam 2 tan 1 + tan 2 tan 2 + tan 2 tan 2 + .. + tan 2 tan-1 2n 1
= tan-1 2n tan-1 1.
sin A sin B sin C =

S =

30.
Sol.

Ans. : A P, B S, C R, D Q
2
log log x
log log x
(Note : Domain log2x > 0)
A. 9 3 ( 2 ) = 3 3 ( 2 ) = (log2x)2
Given equations is 2(log2x)2 log2x 1 = 0
(log2x 1) (2log2x 1) = 0
log2x = +1, log2x = (ve not acceptable)
x = 2.
B. The chord of contact is drawn from a point on the director circle x2 + y2 = 16 + 9 = 25
From any point on this circle (5 cos , 5 sin ) the chord of contact to the ellipse is
5x
5y
cos + sin 1 = 0
16
9
1
Distance from the centre =
25
25
cos 2 + sin 2
256
81
16 9
1

=
5
256 175cos 2
Max. distance (when cos2 = 1) =
C. x +

1
=1
x

p = x 4000 +

16 9 1
16

=
5
81 5

x = , 2
1

= +

= 1

x
n
this, 2n = 4k (for n > 1); 22 = 24 k = (16)k = a no. with write digit 6.
4000

22 + 1 = no. with units digit 7.


q=7
p + q = 1 + 7 = 6.
D. f(x) = x(2x2 + ax + 6)
Q f has 3 distinct roots, 2x2 + ax + b = 0 has 2 real and distinct roots
a2 8b > 0
a>2 2 b
for a + b > 2 2b + b a + b > 3.828b

For b = 1, min. (a + b) = 4.
31.

Ans. : 3

Sol.

32.
Sol.

x3 ;
x 1

0 x <1
x ;
f ( x) = max x, x3 =
3
x ; 1 x < 0
x ; < x < 1

Not differentiable at x = 1, 0, 1.

{ }

Ans. : 2
5
3 + 4m
For x to be an integer, 3 + 4m = 1, 1, 5, 5
m = 1, , 2,
Integer m = 2 values.

3x + 4mx + 4 = 9

x=

33.
Sol.

Ans. : 5
1 2 sin2 x + a sin x = 2a 7
2 sin2 x a sin x + 2a 8 = 0 2(sin x 2) (sin x + 2) a (sin x 2) = 0
For solution to exist, (2(sin x + 2) a ) (sin x 2)
a = 2(sin x + 2)
Q 1 sin x 1
2 2(sin x + 2) 6
a = 2, 3, 4, 5, 6
(5 integer values)

34.

Ans. : 4
1

Sol.

Graphically, area = 4 l ln x dx = 4 1 = 4 sq. units.


0

35.

Ans. : 2

Sol.

(1 + 0.0001)1000 = 1 + 0.1 +

36.
Sol.

Ans. : 5
one-one function is only possible when f(0) 2 is true statement
and (f(2 ) = 1 and f(1) 1) are false statements.
f(2) = 2, f(1) = 1 and f(0) = 3 is the one-one mapping.

1000 999
( 0.0001)2 + ........
2
= 1 + 0.1 + 0.00499 + = 1.104 ..
required Ans. 2.

Distance between points =


37.
Sol.
38.
Sol.

Ans. : 5
C3 = nC2

( 4 )2 + 0 + ( 0.3)2

= 5.

n = 5.

Ans. : 4
a b c a b c
T
A A = b c a b c a = = I
c a b c a b
Where = a2 + b2 + c2 = 1
= ab + bc + ca = 0
(a + b + c)2 = 1 + 2(0) = 1
3
3
a + b + c3 3abc = (a + b + c) (a2 + b2 + c2 ab bc ca)
abc =1
Q
a3 + b3 + c3 3 = 1 (1 0)

a + b + c=1
a3 + b3 + c3 = 4.

Sol. Phy. P-2


39.

Ans. : C

Sol.

v = v0 +

2v0 x
x0

2v x
dx
= v0 + 0
dt
x0

x0

40.

dx
=
2v0 x
v0 +
x0

dt

T=

x0
ln 3
2v0

Sol.

Ans. : D
V
E=
i = ( 6 x 4 ) i
x
Planes parallel to OYZ plane.

41.
Sol.

Ans. : B
Plate charge = CV

42.

Ans. : C

Sol.

1.5
1
=
100 + 300 + 30 300
Both S1 and S2 closed. 1.5 100i 300i = 0
1.5 R (i i ) 300i = 0
R = 600

Both S1 and S2 open i =

43.

Ans. : BCD

Sol.

Oa = Oc =

B00 2l 2
2

Oac = 0

=0

B00n l2
2

B00l2
2

44.

Ans. : ABCD

Sol.

Z=R 2
VOL = I)XL =

I0 =
V0
2

V0
R 2

cos =

1
2

V0 V0

sin t +
4
2

i = 0 sin t +
4
2R

V I cos
V2
Power = 0 0
= 0
2
4R
VR =

45.
Sol.

V0

Ans. : CD
4
P = P0 +
R

P = P0 +

4
2R

P < P.
P > P/2.

46.
Sol.

sin t + +
2
2 2

V
3

= 0 sin t +

4
2

vL =

Ans. : ABC
When the block reaches the lowest position.
1 2 1
2mg
k + ( 2k ) 2 mg = 0 =
2
2
3k
mg
Equilibrium =
3k
mg
Amplitude of SHM =
3k
3k
M
c =
T = 2
M
3k
2 2
2M g
Maximum spring PE =
3k
Maximum acceleration = g.
M
Maximum velocity = g
3k

47.

Ans. : BC

Sol.

P0V0 = ( kP0 ) Vb

Vb =

k
1

PV k
Tb = 0 0
NR

V
( kP0 ) 01

k

V0

Wbc = NRTb ln
1

= P0V0 k

=
48.
Sol.

= NRTb

P0V0 k

V k
ln 0
V0

Ans. : A Q, B R, C S, D T
3l
l

N1 = mg co 60
4
2

mg
N1 =
f
3
N 2 + N1 cos 60 mg = 0
mg
5mg
N2 = mg
=
6
6
mg
3
mg
f = n1 sin 60 =

=
3
2
2 3
For static friction S

Vc
Vb

ln k

mg

N1

60o

N2

f
3
=
N2
5

49.

Ans. : A PR, B QS, C QS, D PR

50.

Ans. : 5
a la 1
na va
n v
na
= S S
=
=
2la
2lS
ns
s ls 3
One loop in aluminium wire and 3 loops in steel wire for minimum frequency of
excitation.
Number of nodes = 5.

Sol.

51.

Ans. : 2

Sol.

= 10 log

I
I0

2 1 = 10 log

I2
I1

I 2 r1
1
= =
I1 r2
4

2 1 = 10 log
4
= 20 log 2
= 10(2) log 2

52.

Ans. : 8

53.
Sol.

Ans. : 4
Wg + We = (U k ) = 0

mgh + q V p V0 = 0
q
2 0

R R 2 + h 2 + h = mgh

4R
h = 0,
3

54.

Ans. : 8

Sol.

55.
Sol.

1
1
1

=
v=4
v ( 12 ) 6
1
1
1

=
d = 8 cm.
( d + 4 ) 12
Ans. : 6
x 2 + 9 2 = x =

n
2

n = 1, 3, 5, 7, ..

9 n
x = > 0 n < 6
n = 1, 3, 5
n 4
from < x < 0
3 minima.
6 minima.

56.
Sol.

Ans. : 4
Energy of the incident photon = 0.73 + 1.82
= 2.55eV
For hydrogen atom
E1 = 13.6eV, E2 = 3.4eV,
E3 = 1.51eV,
Note : that 0.85 (3.4) = 2.55eV
n = 4.

57.

Ans. : 6

Sol.

1
Z 1
=
Moseley law -

4
11 1

Z = 6.

E4 = 0.85eV

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