Abellar, Rodgie John
Aries, Allen Jerry
Belnas, Katrina Lyn
BSChE-4
Assignment
ChE Thermodynamics 2
January 27,2014
Problem:
Calculate the enthalpy and entropy of saturated isobutene vapor at 360 K from the following
information:
1. compressibility-factor data for isobutene vapor.
2. The vapor pressure of isobutane at 360 K is 15.41 bar.
ig
1
ig
1 1
3. H 0 =18,115.0 J mo l and S 0 =295.976 J mol K
for the ideal gas reference state at
300 K and 1 bar.
4. The ideal-gas heat capacity of interest is:
C igP
3
=1.7765+ 33.037 10 T (T / K )
R
Solution:
Compressibility Factors Z for
Isobutane
P
(bar)
0.1
0.5
2
4
6
8
10
12
14
15.41
R
H
Z
=T
RT
0 T
( ) dPP
P
340 K
0.997
7
0.987
45
0.958
95
0.924
22
0.887
42
0.845
75
0.796
59
350 K
0.997
19
0.988
3
0.962
06
0.930
69
0.898
16
0.862
18
0.821
17
0.773
1
360 K
0.997
37
0.989
07
0.964
83
0.936
35
0.907
34
0.875
86
0.840
77
0.801
03
0.755
06
0.717
27
370 K
0.997
53
0.989
77
0.967
3
0.941
32
0.915
29
0.887
45
0.856
95
0.823
15
0.785
31
380 K
0.997
67
0.990
4
0.969
53
0.945
74
0.922
23
0.897
43
0.870
61
0.841
34
0.809
23
Abellar, Rodgie John
Aries, Allen Jerry
Belnas, Katrina Lyn
BSChE-4
R
S
Z
=T
R
0 T
Assignment
ChE Thermodynamics 2
January 27,2014
dP
dP
(Z1)
P
P P
0
( )
Solving for (Z 1)/ P in every pressure at 360 K:
*Value(s) in parenthesis are
Plotting Z vs .T
At
at each
P=0.1 bar,
Graphing from 350 K to
P
(bar)
0
0.1
0.5
2
4
6
8
10
12
14
15.41
(Z 1)/ P
(bar-1)
(0.031500)
0.026300
0.021860
0.017585
0.015913
0.015443
0.015518
0.015923
0.016581
0.017496
0.018347
found by extrapolation
pressure:
remove decreasing side:
Abellar, Rodgie John
Aries, Allen Jerry
Belnas, Katrina Lyn
BSChE-4
Assignment
ChE Thermodynamics 2
January 27,2014
1
1
f(x) = - 0x^2 + 0x + 0.98
R = 1
1
1
1
Z
1
1
1
1
1
345
350
355
360
365
370
375
380
385
T(K)
P=0.50
At
bar,
0.99
0.99
0.99
0.99
f(x) = - 0x^2 + 0x + 0.92
R = 1
0.99
0.99
Z
0.99
0.99
0.99
0.99
0.99
0.99
335
340
345
350
355
360
T(K)
365
370
375
380
385
Abellar, Rodgie John
Aries, Allen Jerry
Belnas, Katrina Lyn
BSChE-4
Assignment
ChE Thermodynamics 2
January 27,2014
P=2 bar,
At
0.97
0.97
0.97
0.97
f(x) = - 0x^2 + 0x + 0.68
R = 1
0.96
Z
0.96
0.96
0.96
0.96
0.95
0.95
335
340
345
350
355
360
T(K)
At
P=4 bar,
365
370
375
380
385
Abellar, Rodgie John
Aries, Allen Jerry
Belnas, Katrina Lyn
BSChE-4
Assignment
ChE Thermodynamics 2
January 27,2014
0.95
0.95
f(x) = - 0x^2 + 0x + 0.3
R = 1
0.94
0.94
Z
0.93
0.93
0.92
0.92
0.91
335
340
345
350
355
360
T(K)
At
P=6
bar,
365
370
375
380
385
Abellar, Rodgie John
Aries, Allen Jerry
Belnas, Katrina Lyn
BSChE-4
Assignment
ChE Thermodynamics 2
January 27,2014
0.93
0.92
f(x) = - 0x^2 + 0.01x - 0.22
R = 1
0.91
0.9
0.89
0.88
0.87
335
340
345
350
355
360
T(K)
At
P=8
bar,
365
370
375
380
385
Abellar, Rodgie John
Aries, Allen Jerry
Belnas, Katrina Lyn
BSChE-4
Assignment
ChE Thermodynamics 2
January 27,2014
0.91
0.9
0.89
f(x) = - 0x^2 + 0.01x - 0.97
R = 1
0.88
0.87
Z
0.86
0.85
0.84
0.83
0.82
0.81
335
340
345
350
355
360
365
370
375
380
385
T(K)
P=10 bar,
At
0.88
0.86
f(x) = - 0x^2 + 0.01x - 2.16
R = 1
0.84
0.82
Z
0.8
0.78
0.76
0.74
335
340
345
350
355
360
T(K)
365
370
375
380
385
Abellar, Rodgie John
Aries, Allen Jerry
Belnas, Katrina Lyn
BSChE-4
Assignment
ChE Thermodynamics 2
January 27,2014
P=12 bar,
At
12
10
8
6
4
2
0
335
340f(x) =345
R = 0
350
355
360
T(K)
At
P=14
bar,
365
370
375
380
385
Abellar, Rodgie John
Aries, Allen Jerry
Belnas, Katrina Lyn
BSChE-4
Assignment
ChE Thermodynamics 2
January 27,2014
12
10
8
6
4
2
0
335
340f(x) = 345
R = 0
350
355
360
365
370
375
380
T(K)
Differentiating each trend line equation at T =360 K
and dividing each by corresponding
pressure gives:
P
(bar)
0
0.1
0.5
2
4
6
8
10
12
14
15.41
*Value(s) in parenthesis are
( TZ ) / P
P
(1.757
1.700
1.474
1.320
1.342
1.446
1.608
1.838
2.093
2.387
(K-1bar-1)
x
x
x
x
x
x
x
x
x
x
10-4)
10-4
10-4
10-4
10-4
10-4
10-4
10-4
10-4
10-4
(2.594 x 10-4)
found by extrapolation
385
Abellar, Rodgie John
Aries, Allen Jerry
Belnas, Katrina Lyn
BSChE-4
( TZ ) / P
Plotting
Assignment
ChE Thermodynamics 2
January 27,2014
vs.
P :
x=P ,
y=
( TZ ) /P
P
0
0
f(x) = 0x^6 - 0x^5 + 0x^4 - 0x^3 + 0x^2 - 0x + 0
R = 1
0
0
0
0
0
10
12
14
16
18
( TZ ) / P=4.51210
10
P62.3218 108 P5 + 4.6323 107 P 44.5265 106 P3 +2.3141 105 P25.4059
Z
T
( )
dP
=
P P
15.41
( 4.512 1010 P62.3218 108 P5 + 4.6323 107 P 44.5265 106 P 3+2.3141 105 P25.4
Abellar, Rodgie John
Aries, Allen Jerry
Belnas, Katrina Lyn
BSChE-4
Assignment
ChE Thermodynamics 2
January 27,2014
( TZ ) dP= 26.67 10
P
K 1
Graphing (Z 1)/ P vs .
P :
x=P and
y=( Z1)/P
0.04
0.03
0.03
0.02
y
0.02
0.01
0.01
0
0
10
x
12
14
16
18
Abellar, Rodgie John
Aries, Allen Jerry
Belnas, Katrina Lyn
BSChE-4
Assignment
ChE Thermodynamics 2
January 27,2014
0.01758
5
2
2
2
2
2
2
1.41
0.016
0.0155
0.0155
0.016
0.0165
0.0175
0.01834
7
yx
0.03517
0.032
0.031
0.031
0.032
0.035
0.025869
y x=0.255039
= y x=0.2550
(Z1) dP
P
0
H
Z
=T
RT
0 T
( ) dPP
P
H R =R T 2
0
( TZ ) dPP =8.314 ( 360 ) (26.67 10
2
H R =2873.7 J mo l1
S
Z
=T
R
T
0
dP
dP
(Z1)
P
P
P
0
( )
S R =RT
0
Z
T
( )
dP
dP
R ( Z1 )
P
P
P
0
S R =8.314 ( 360 ) ( 26.67 104 ) +(8.314 )(0.2550)
S R =5.862 J mo l1 K1
T
H=H ig0 + CigP dT +H R
T0
360
H=18,115.0+ 8.314 ( 1.7765+33.037 103 T ) dT 2873.7
300
H=21566 J mol
T
ig
ig
S=S 0 + C P
T0
dT
P
R
R ln + S
T
P0
1.7765+33.037 103 T
dT
15.41
() 8.314 ln
5.862
T
1
360
S=295.976+
300
S=269.68 J mol 1 K1
Summary:
H=21570 J mol 1
S=269.7 J mo l1 K1
