Homework+ 1 Solution
Homework+ 1 Solution
Solution
ECE 3040 C Fall 2014
Microelectronic Circuits
School of Electrical and Computer Engineering
Georgia Institute of Technology
1. Diamond Lattice (20 points)
a. The lattice constant of Ge at room temperature is a = 5.65 . Determine the
number of Ge atoms per cm3.
b. Calculate the density of crystalline silicon at room temperature using the lattice
constant a = 5.43 , the atomic weight m = 28.09 g/mol, and the Avogadros
number 6.023 * 1023 mol-1.
Each diamond type crystal (e.g. Si and Ge) has 8 atoms per unit cell:
1) 8 atoms at the corners each of them shared between 8 unit cells
2) 6 atoms on the faces each shared between 2 cells
3) 4 atoms at inside locations, e.g. (, , ) and similar.
So, 8* (1/8) + 6*(1/2) + 4 = 8.
(a) Number of Ge atoms per cm3 = Number of atoms per unit cell divided by unit
cell volume a3:
# of Ge atoms
8
4.4 1022 cm3
3
a
(b) Density of silicon = # of atoms per cm-3 (= 5 * 1022 cm-3 from class, or
calculated similar to part (a)) * weight of 1 mol (28.09g/mol) / # atoms per mol (6
* 1023 mol-1)
5 10 22 m
8 28.09 g
g
2.33 3
23
3
Navogadro
6.023 10 cm
cm
(d) Probability that a state is occupied by a hole is 1 f(E), i.e. the probability for
a state being occupied with a hole at EF kT is
1 f(EF kT) 1
1
1 e
E kT E /kT
F
F
1
0.269
1 e1