Flow Rate (kg/h)

Temp ( C)
Pressure (kPa.abs)
PA (%)
MA (%)
Benzoic Acid (%)
O Toluic Acid (%)
Phthalic Acid (%)
Phthalide (%)
SUM

Molar Quantities
Nomalized (kmol, h)
36.90781012
225
25
0.97949
0.01502
0.00000
0.00000
0.00000
0.00549
1

Component

Dew Point Temperature

Distillate Normalized (kmol/h)

98.96072
0
0.01199
0.98801
0.00000
0.00000
0.00000
0.00000
1
Antoine's Vapor Pressure of
Component

225.00000
PA
MA
Benzoic Acid
O Toluic Acid
Phthalic Acid
Phthalide

Component
PA
MA
Benzoic Acid
O Toluic Acid
Phthalic Acid
Phthalide

0.24799
1.77967

0.20677

Bubble Point
Temperature
222

Clausius- Reduced Vapor

Pressure of Component
0.24382
0.11926

0.18382

Purification Column
Forrunnings Normalized
(kmol/h)
148.069976

Residue Normalized (kmol/h)

145.306

0.99909
0.00091
0.00000
0.00000
0.00000
0.00000
1

0.78368
0.00000
0.00000
0.00000
0.00000
0.21632
1

0.007858221
-0.091893902
0
0
0
0.000949421

Equilibrium Constant, Ki =
Pi*/Pt

Yi = Zi

Zi/Ki

0.99198
7.11870

0.97949
0.01502

0.98741
0.00211

0.82706

0.00549

0.00664

(Zi/Ki) =

0.99616

Equilibrium Constant, Ki =
Pi*/Pt

Xi = Zi

Zi*Ki

0.99198
7.11870

0.97949
0.01502

0.97163
0.10691

0.82706

0.00549

0.00454

(Zi*Ki) =

1.08309

fication Column

-0.08308626

Xi
0.991218721
0.002117861

0.006663418

Yi
0.897096924
0.098710918

0.004192158

Given
Calculated

Legend

Molecular Weight
(Kg/Kmol)

Feed
Flow Rate (kg/h)

5445.000

Temp ( C)
Pressure (kPa.abs)

225
25

147.530

PA (%)
MA (%)

0.9850
0.0100

148.10000
98.06000

Benzoic Acid (%)

0.0000

122.12000

O Toluic Acid (%)

0.0000

136.20000

Phthalic Acid (%)

0.0000000

166.14000

Phthalide (%)
SUM

0.0050

134.13000

Component

Reduced Temperature (K)

Tbr = Tb/Tc

PA
MA
Benzoic Acid
O Toluic Acid
Phthalic Acid
Phthalide

0.61136
0.68902
0.66366
0.62541
0.66257
0.59846

0.69114
0.65721
0.69563
0.66935
0.74769
0.67775

Zi/Ki

Xi
0.991218721

0.9874133480
0.0021097308

0.002117861

0.0066378361
0.9961609150

0.006663418

2.0792471755

Bubble Point
Dew point

222
225

Molar Quantities Nomalized

(kmol, h)

Critical Temperature,
Tc (K)

0.98121
0.01504

0.97949
0.01502

814.81792
722.98488

0.00000

0.00000

750.61170

0.00000

0.00000

796.51871

0.00000

0.00000

751.84919

0.00550
1.00175

0.00549
1.00000

832.38431

Tao

f(0)

f(1)

0.38864
0.31098
0.33634
0.37459
0.33743
0.40154

-3.39280
-2.42218
-2.71362
-3.19888
-2.72668
-3.57928

-3.69977
-2.44637
-2.80677
-3.43741
-2.82325
-3.95744

Zi*Ki

Yi

0.97163

0.897096924

0.10691

0.098710918

0.00454

0.004192158

Molar Quantities (kmol, h)

36.908

1.08309

Crritical Pressure, Pc
(bar)

Distillate (kg/h)

Distillate (kmol/h)

98.96072
47.82593
59.90664

0.018
0.982

0.01203
0.99102

46.27701

0.00000

40.00703

0.00000

44.92234

0.00000

45.59213

0.00000
1.00305

f(2)

Reduced Vapor Pressure

of Component, Pvpr (bar)

-0.06498
-0.00488
-0.01933
-0.05047
-0.02006
-0.07985

0.59034
1.54733
0.99043
0.66703
0.83047
0.51477

0.003699501
0.001990838
0.004035998
0.004029197
0.006187932
0.003561302

Constants
C1
C2
C3
C4
C5

126.5
-12551
-15.002
0.000007752
2
Antoine's Constants

A
B
C

3.79916
1431.009
-101.093
Clausius Claperyone
498.15 K

Maleic Anhydride

Maleic Anhydride

Phthalic Amhydride

Phthalide

1.0132472
54.8
0.008314
446.15
0.0533288
54.01
0.008314
454.15
0.0533288
52.9
0.008314

bar
KJ.mol
KJ.mol
K
bar
KJ.mol
KJ.mol
K
bar
KJ.mol
KJ.mol

Distillate Normalized
(kmol/h)

Forrunnings (kg/h)

Forrunnings (kmol/h)

148.06998
0.01199
0.98801

0.9994
0.0006

0.99920
0.00091

0.00000

0.00000

0.00000

0.00000

0.00000

0.00000

0.00000
1.00000

0.00000
1.00010

Vapor Pressure (bar)

0.176932052
0.119264411
0.186773926
0.161196167
0.277976365
0.162367357

Clausius-Reduced Vapor
Pressure (bar)
0.243816674
0.119264411

2.479943E-01
1.7796746105

0.277976365
0.183820269

0.0000000006
0.206765032

Omar's Vapor Pressure

Equation
23214.27474

(317 - 475)

Antoine's Vapor Pressure (bar)

Antoine's Constants
0.232142747

A
B
C
D
E
F
Min ( C)
Max( C)

Forrunnings
Normalized (kmol/h)

Residue (kg/h)

Residue (kmol/h)

145.30600
0.99909
0.00091

0.8
0

0.78491
0.00000

0.00000

0.00000

0.00000

0.00000

0.00000

0.00000

0.00000
1.00000

0.2

0.21666
1.00157

Phthalic Anhydride

Maleic Anhydride

Phthalic Acid

68.5201
-8930.18
0
-7.86708
5.96E-06
2
131
516.9

43.1052
-7473.19
0.00E+00
-3.70E+00
3.55E-18
6.00E+00
5.26E+01
4.48E+02

134.551
-30440.9
0
-14.507
8.37E-20
6
191
196.9

Residue Normalized (kmol/h)

0.78368
0.00000
0.00000
0.00000
0.00000
0.21632
1.00000

Phthalide
4.8302
2515.221
-42.058

95.55
289.85

Critical Temperature and Pressure Properties

Phthalide
Groups
(= CH-(ring))
(= CH< (ring))
(>C=O (ring))
(-O- (ring))
(-CH2- (ring))
Sum
Total Number of Atoms
Critical Temperature (K)
Critical Pressure (bar)

Number
of Groups
4
2
1
1
1

Tc (K)

Pc (bar)

Tb (K)

0.0328
0.0286
0.0284
0.0098
0.01
0.1096
16

0.0044
0.0016
0.0028
0.0048
0.0025
0.0161

106.92
62.02
94.97
31.22
27.15
520.28
564.15

Tc (K)

Pc (bar)

Tb (K)

0.041
0.0143
0.0791
0.1344
15

0.0055
0.0008
0.0077
0.014

133.65
31.01
169.09
531.75
522.15

832.3843 559.2343
45.59213

Benzoic Acid
Groups
(= CH-(ring))
(= CH< (ring))
(-COOH (acid))
Sum
Total Number of Atoms
Critical Temperature (K)
Critical Pressure (bar)

Number
of Groups
5
1
1

750.6117 477.4617
46.27701

Phthalic Acid
Groups
(= CH-(ring))
(= CH< (ring))
(-COOH (acid))
Sum
Total Number of Atoms
Critical Temperature (K)
Critical Pressure (bar)

Number
of Groups
4
2
2

Tc (K)

Pc (bar)

Tb (K)

0.0328
0.0286
0.1582
0.2196
18

0.0044
0.0016
0.0154
0.0214

106.92
62.02
338.18
705.12
562.15

Tc (K)

Pc (bar)

Tb (K)

0.0328
0.0286
0.0568
0.0098
0.128
15

0.0044
0.0016
0.0056
0.0048
0.0164

106.92
62.02
189.94
31.22
588.1
563.15

751.8492 478.6992
44.92234

Phthalic Anhydride
Groups
(= CH-(ring))
(= CH< (ring))
(>C=O (ring))
(-O- (ring))
Sum
Total Number of Atoms
Critical Temperature (K)
Critical Pressure (bar)

Number
of Groups
4
2
2
1

814.8179 541.6679
47.82593

O-Toluic Acid
Groups
(= CH-(ring))
(= CH< (ring))
(-COOH (acid))
(-CH3 (Non ring))
Sum
Total Number of Atoms
Critical Temperature (K)
Critical Pressure (bar)

Number
of Groups
4
2
1
1

Tc (K)

Pc (bar)

Tb (K)

0.0328
0.0286
0.791
0.0141
0.8665
18

0.0044
0.0016
0.0077
-0.0012
0.0125

106.92
62.02
169.09
23.58
559.61
533.15

Tc (K)

Pc (bar)

Tb (K)

0.0164
0.0568
0.0098
0.083
9

0.0022
0.0056
0.0048
0.0126

53.46
189.94
31.22
472.62
475.15

796.5187 523.3687
40.00703

Maleic Anhydride
Groups
(= CH-(ring))
(>C=O (ring))
(-O- (ring))
Sum
Total Number of Atoms
Critical Temperature (K)
Critical Pressure (bar)

Number
of Groups
2
2
1

722.9849 449.8349
59.90664

Mass Flowrate
(Kg/h)
Flow Rate (kg/h)
Temp ( C)
Pressure (kPa.abs)
PA (%)
MA (%)
Carbon Monoxide (%)
Carbon Dioxide(%)
Nitrogen (%)
Oxygen (%)
Water (%)
Phthalide (%)
SUM
Rachford Rice (V/F)
Dew Point Temperature ( C )

131.000
1.800
42.36150723
3.010961595
8.289374529
42.14682527
4615.531664
1085.903346
135.9939451
0.219091084
5933.456715

Molar percentage(Fraction
)

0.00714
0.00051
0.00140
0.00710
0.77788
0.18301
0.02292
0.00004
1.00000

0.9978
133

Antoine's Constants

Phthalic Anhydride

Maleic Anhydride

A
B
C
D
E
F
Min ( C)
Max( C)

68.5201
-8930.18
0
-7.86708
5.96E-06
2
131
516.9

43.1052
-7473.19
0.00E+00
-3.70E+00
3.55E-18
6.00E+00
5.26E+01
4.48E+02

Mass Flowrate
(Kg/h)

Molar percentage(Fraction
)

Flow Rate (kg/h)

Temp ( C)
Pressure (kPa.abs)
PA (%)
MA (%)
Carbon Monoxide (%)
Carbon Dioxide(%)
Nitrogen (%)
Oxygen (%)
Water (%)

70.000
1.800
31.8787163
2.914204104
8.285847573
42.12889267
4613.567852
1085.441317
136.0417501

0.00537
0.00049
0.00140
0.00710
0.77755
0.18294
0.02293

Phthalide (%)
SUM
Rachford Rice (V/F)
Dew Point Temperature ( C )

0.144530818
5933.456715
0.9978
133

0.00002
0.99780

Vapor Pressure (bar)

Equilibrium Constant, Ki = Pi*/Pt

Yi = Zi

0.01198
0.11326

0.00666
0.06292

2.78232393797
0.00765316477

1.54574
0.00425

0.00714
0.00051
0.00140
0.00710
0.77788
0.18301
0.02292
0.00004

Phthalic Acid

Water

Phthalide

134.551
-30440.9
0
-14.507
8.37E-20
6
191
196.9

65.9278
-7227.53
0
-7.17695
4.03E-06
2
1.85
374.1

4.8302
2515.221
-42.058

Vapor Pressure (bar)

Equilibrium Constant, Ki = Pi*/Pt

Yi = Zi

0.00065
0.00768

0.00036
0.00427

0.31185422442

0.17325

0.00537
0.00049
0.00140
0.00710
0.77755
0.18294
0.02293

95.55
289.85

0.00029959691

0.00017

0.00002

Zi/Ki

Xi

1.07243
0.00806

0.97140
0.00730

Rachford Rice
Procedure 1

-0.802017651
-0.007317291

Xi

0.807392643
0.007808648

0.001400137
0.007118911

0.01483
0.00868
1.10401

0.01343
0.00787
1.00000

0.779597534
0.18341713
0.008098345
-0.00570714
0.164589976

Phthalic Anhydride
Condensed
PA
MA
Water
Phthalide

12.61035656
0.121960287
0.231769693
0.089518238
13.05360477

Zi/Ki

Xi

14.85088
0.11516

0.97417
0.00755

0.13234

0.00868

Rachford Rice
Procedure 1

-2.097150216
-0.075755225
0.001399541
0.007115882
0.779265831
0.18333909
-0.108273634

0.014839322
0.005731509
0.835772122

Phthalic Anhydride
Non Condensed
31.8787163
2.914204104
136.0417501
0.144530818

Xi

2.097909191
0.076079712

0.13096334

0.14635
15.24472

0.00960
1.00000

-0.010293228
-1.320351959

0.010294942
2.315247185

Normalized Xi

Yi

0.966043999
0.009343035

0.017755225
0.006857741
1

Normalized Xi

0.906127521
0.032860298

0.056565597

Normalized Yi

0.005375
0.000491

0.005384552
0.000492231

0.001397
0.007103

0.001399541
0.007115882

0.777882
0.183014
0.022938
0.000024
0.998225

0.779265831
0.18333909
0.022978461
2.44123E-05
1

Yi

Normalized Yi

0.000759
0.000324
0.001396
0.007100
0.777551
0.182936
0.022690

0.000764511
0.000326853
0.001406648
0.007152017
0.783222951
0.184270088
0.022855206

0.001376 0.056303
0.000588
0.002532
0.012874
1.409801
0.331686
0.041139

0.004446584
1

0.000002
0.992759

1.72602E-06
1

3.11E-06

7.50642E-05