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Second Law Analysis Formula Page

This document contains equations related to thermodynamics. It includes: - Equations for the relationship between temperature, pressure, specific volume, and velocity for different states. - Equations for changes in entropy and enthalpy during processes involving changes in temperature, pressure, and specific volume or pressure. - The fundamental thermodynamic equation relating internal energy, enthalpy, entropy, and chemical potentials. - Equations for the dead state, exergy, and chemical exergy. - Equations relating temperature, pressure, specific volume, entropy, and internal energy for processes involving ideal gases and mixtures.

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Fadi W Moussa
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© Attribution Non-Commercial (BY-NC)
Available Formats
Download as PDF, TXT or read online on Scribd
64 views

Second Law Analysis Formula Page

This document contains equations related to thermodynamics. It includes: - Equations for the relationship between temperature, pressure, specific volume, and velocity for different states. - Equations for changes in entropy and enthalpy during processes involving changes in temperature, pressure, and specific volume or pressure. - The fundamental thermodynamic equation relating internal energy, enthalpy, entropy, and chemical potentials. - Equations for the dead state, exergy, and chemical exergy. - Equations relating temperature, pressure, specific volume, entropy, and internal energy for processes involving ideal gases and mixtures.

Uploaded by

Fadi W Moussa
Copyright
© Attribution Non-Commercial (BY-NC)
Available Formats
Download as PDF, TXT or read online on Scribd
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Gen.

Rel'ns :

T2 P2 = T1 P1

k 1 k

v1 = v 2

k 1

P1 Pr 1 = P2 Pr 2

v1 v r 1 = v2 vr 2

sicl = cP ln
P2 P1

T2 T1
o R ln sIG,abs,i = sT,i

s = c V ln

T2 v + R ln 2 T1 v1

s = cP ln

T2 P R ln 2 T1 P1

o s = so 2 s1 R ln

Pi Po

U = TS PV +

nii

G i = Gi = ni T,P,n ji

G = H TS

Note: ( )* = restricted dead state


eph = ( u u * ) T0 ( s s * ) + P0 ( v v * ) eph = ( h h * ) T0 ( s s * )

E = U + Po V To S

nii,o

Ech =

ni ( *i i,o )

ch Eig =

i niRTo ln Pi,o

P*

( ) EL ( T,P ) = hf ( T ) hg ( To ) To sf T sg ( To ) ToR v ln o

T T P Ema 1 + o = c p,a + c p,v 1 ln + (1 + ) Ra ln + Ra (1 + ) ln To 1+ To To Po

+ ln o

C
e

e,k

+C w ,k = Cq,k +
ci =

C
i

i ,k

+Z k
Tdp = TSAT ( PV ) h = ha + hv (Pv , T ) = Pa Pv = Psat ( T ) 0.622Psat ( T )

yi = =

ni ni

mi mi

yiMi yiMi

mV P = 0.622 V mA PA

A,1 m 2 = h3 h2 = 3 A,2 1 2 m h1 h2

1 hv1 hl 2 = cP,a ( T2 T1 ) + 2hfg,2

C14 : A1CxHy + A 2 ( O2 + 3.76N2 ) A 3CO2 + A 4CO + A 5H2O + A 6O2 + A 7CxHy + A 8N2 AFMOLE = nair nfuel AFMASS = mair M = AFMOLE air mfuel Mfuel w FC,Elec,Re v = GRP FC,Re v = = AFS 1 1 = = AF TA Excess Air + 1 =

o hi ( T,Pi ) = hf,i + hi ( T,Pi ) h 25o C, 0.1MPa

GRP HRP

GRP

ne nF F

MT1

ME 476

Spring 2008

List Number:

Student Number:

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