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Problem 34

The document contains data from two experiments: 1) A reaction over time, with lines of best fit showing the reaction is first-order. 2) An Arrhenius plot of rate vs. inverse temperature, with lines of best fit used to calculate the activation energy (E) of 0 kJ/mol and frequency factor (Do) of 0.049041915.

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Joel Sanchez
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© Attribution Non-Commercial (BY-NC)
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20 views

Problem 34

The document contains data from two experiments: 1) A reaction over time, with lines of best fit showing the reaction is first-order. 2) An Arrhenius plot of rate vs. inverse temperature, with lines of best fit used to calculate the activation energy (E) of 0 kJ/mol and frequency factor (Do) of 0.049041915.

Uploaded by

Joel Sanchez
Copyright
© Attribution Non-Commercial (BY-NC)
Available Formats
Download as XLSX, PDF, TXT or read online on Scribd
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time

Cae=
Ca0=

ln
0
36
65
100
160

0
-0.32658
-0.61079
-0.91855
-1.48765

0.0495
0.1823
0.1453
0.1216
0.1025
0.0795

Ln() vs Time
0.2
0
0

20

40

60

80

100

-0.2

Ln()

-0.4
-0.6
-0.8
-1

y = -0.0093x + 0.0023

-1.2
-1.4
-1.6

Time (mins)

120

140

160

180

T
347
374.2
396.2
420.7
447.7
471.2

D
0.00000134
0.0000025
0.00000455
0.00000852
0.00001407
0.00001999

1/T
0.00288184
0.00267237
0.00252398
0.00237699
0.00223364
0.00212224

lnD
-13.5228
-12.8992
-12.3004
-11.6731
-11.1715
-10.8203

(1/T)*(lnD)
-0.038970723
-0.034471459
-0.031045894
-0.027746837
-0.024953017
-0.022963239

(1/T)^2
8.30503E-06
7.14155E-06
6.37046E-06
5.65008E-06
4.98914E-06
4.50391E-06

m=(-E/R)
x=(1/T)

Sx
Sxx
Sy
Sxy

0.00246851
6.16003E-06
-12.0645471
-0.03002519

(-E/R)
lnDo
Do
E

-3665.963252
-3.015079937
0.049041915
0

b= LnDo
y=LnD

1.34
2.5
4.55
8.52
14.07
19.99

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