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Ammonium Carbamate Decomposition

This document provides information about chemicals, phases, mass flow rates, and heat of reaction for a chemical process. The process involves streams containing CO2, air, NH3, urea, carbamate, and water. Energy calculations show that 1.0434x1010 kJ/day of heat is required for the stripper, which can be supplied by 62611.6893 kg/day of medium pressure steam at 10 bar and 198°C. The total energy in is 11892076913 kJ/day and the total energy out is 4644047019 kJ/day.

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Al- Dhaheri
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© Attribution Non-Commercial (BY-NC)
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Download as PDF, TXT or read online on Scribd
88 views

Ammonium Carbamate Decomposition

This document provides information about chemicals, phases, mass flow rates, and heat of reaction for a chemical process. The process involves streams containing CO2, air, NH3, urea, carbamate, and water. Energy calculations show that 1.0434x1010 kJ/day of heat is required for the stripper, which can be supplied by 62611.6893 kg/day of medium pressure steam at 10 bar and 198°C. The total energy in is 11892076913 kJ/day and the total energy out is 4644047019 kJ/day.

Uploaded by

Al- Dhaheri
Copyright
© Attribution Non-Commercial (BY-NC)
Available Formats
Download as PDF, TXT or read online on Scribd
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Chemical

Co2 (4.184)
Air ( 8.314)
NH3 (4.184)
Urea (60)

phases
gas
gas
gas
liq

Carbamate
(17)NH3

liq
liq
liq

(8.314)H2O
Stripper
Input
Stream 6

Stream 2

Output
Stream 4

Stream 7

Chemical
Co2
Air

B
C
D
10.34 0.00274
0
3.355 0.000575
0
6.7
0.0063
0
1.08 0.00277 0.0000104
4.6278
8.712

phases
gas
gas

-0.0043
0.00125

-195500 Cp kcal/kmol.k
-1600
0 Cp kcal/kmol.k
0 Cp(kg/kmol.c)

0.0002
-1.8E-07

MTPD
Kg/d
Kmoles/day T(ref)
2592.593 2592592.59 58922.55892
298
49
49000 1691.98895
298

Urea
Liq
Carbamate Liq
NH3
Liq

3517.6
3517600 58626.66667
2377.287 2377286.86 30478.03664
1473.029 1473028.65 86648.74395

298
298
298

H2O

Liq

1864.502 1864502.39 103583.4663

298

Chemical
Co2
NH3

phases
gas
gas

Urea
Liq
Carbamate Liq
H2O
Liq

MTPD
Kg/d
Kmoles/day T(ref)
3488.478 3488478.39 79283.59971
298
2267.3 2267300.2 133370.5999
298
3517.6
3517600 58626.66667
789.1257 789125.676 10116.99585
1864.502 1864502.39 103583.4663

Ammonium Carbamate decomposition

Qd

3186128240
Energy required for the stripper

QH

1.0434E+10 kj/day

Medium pressure steam load assumed at 10bar and 198C for heating
Hevp(kj/kg)
166648.724
Steam Amount (kg/day)
m(steam )

0
0

62611.6893

298
298
298

Cp kcal/kmol.k

4.184

Cp kcal/kmol.k
Cp(kg/kmol.c)

300-800 K

T2

4.184

A*T1
B*T1^2/2 C*T1^3/3 D/T1
A*T2
B*T2^2/2 C*T2^3/3
373 3081.32 121.6615
0 -656.0402685 3856.82 190.6067
0
373
999.79 25.53115
0
1.92953E-06 1251.415 39.99959
0
456
321.84 122.9935 91.74045
456
456 1379.084 -190.929 1764.239

456 2596.176

0 3972.672

T2
453
453

55.5025

-1.58782

492.48 287.9914 328.7052

0 2110.277

-447.062 6321.254
129.96

-5.68913

A*T1
B*T1^2/2 C*T1^3/3 D/T1
A*T2
B*T2^2/2 C*T2^3/3
3081.32 121.6615
0 -656.0402685 4684.02 281.1363
0
1996.6 279.7326
0
2.11409E-05
3035.1 646.4084
0

441
321.84 122.9935 91.74045
441
441 2596.176 55.5025 -1.58782

476.28 269.3562 297.3226

0 3841.992 121.5506

-5.14597

D/T2
Cp kj/kmol.k Q(kj/day)
-524.129 4085.076986 240703189.4
-4.28954 2176.637553 3682846.688
0 34356.15579
202.49
0 85545.25007

2014186894
975096626.9
7412388469

0 12029.12908
Total (in)

1246018887
11892076913

D/T2
Cp kj/kmol.k Q(kj/day)
-431.567 8312.134351 659015932.6
0 5879.25525 784119799.3
0 30383.08473
202.49
0 10877.25586
Total (out)

1781258981
292948440
1126703866
4644047019

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