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Quantum Mechanics: Professor of Physics The University of Texas at Austin

This document outlines the contents and topics covered in a course on quantum mechanics. The course is divided into 14 chapters covering fundamental concepts like wave-particle duality, probability theory, one-dimensional potentials, multi-particle systems, angular momentum, perturbation theory, and more. The instructor provides an overview of the key concepts and equations covered in each chapter to give students an understanding of what will be learned over the course.

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0% found this document useful (0 votes)

231 views

Quantum Mechanics: Professor of Physics The University of Texas at Austin

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Quantum Mechanics

Richard Fitzpatrick
Professor of Physics
The University of Texas at Austin

Contents
1 Introduction
1.1 Intended audience .
1.2 Major Sources . . .
1.3 Aim of Course . . .
1.4 Outline of Course .

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2 Probability Theory
2.1 Introduction . . . . . . . . . . . . . . . .
2.2 What is Probability? . . . . . . . . . . . .
2.3 Combining Probabilities . . . . . . . . . .
2.4 Mean, Variance, and Standard Deviation
2.5 Continuous Probability Distributions . . .

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3 Wave-Particle Duality
3.1 Introduction . . . . . . . . . . . . . . . . . . . .
3.2 Wavefunctions . . . . . . . . . . . . . . . . . . .
3.3 Plane Waves . . . . . . . . . . . . . . . . . . . .
3.4 Representation of Waves via Complex Functions
3.5 Classical Light Waves . . . . . . . . . . . . . . .
3.6 Photoelectric Effect . . . . . . . . . . . . . . . .
3.7 Quantum Theory of Light . . . . . . . . . . . . .
3.8 Classical Interference of Light Waves . . . . . .
3.9 Quantum Interference of Light . . . . . . . . . .
3.10 Classical Particles . . . . . . . . . . . . . . . . .
3.11 Quantum Particles . . . . . . . . . . . . . . . . .
3.12 Wave Packets . . . . . . . . . . . . . . . . . . .

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5
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6

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7
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11

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13
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21
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25
25
26

QUANTUM MECHANICS
3.13
3.14
3.15
3.16

Evolution of Wave Packets . . . .

Heisenbergs Uncertainty Principle
Schr
odingers Equation . . . . . .
Collapse of the Wave Function . .

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4 Fundamentals of Quantum Mechanics

4.1 Introduction . . . . . . . . . . . . .
4.2 Schr
odingers Equation . . . . . . .
4.3 Normalization of the Wavefunction
4.4 Expectation Values and Variances .
4.5 Ehrenfests Theorem . . . . . . . . .
4.6 Operators . . . . . . . . . . . . . .
4.7 Momentum Representation . . . . .
4.8 Heisenbergs Uncertainty Principle .
4.9 Eigenstates and Eigenvalues . . . .
4.10 Measurement . . . . . . . . . . . .
4.11 Continuous Eigenvalues . . . . . . .
4.12 Stationary States . . . . . . . . . .
5 One-Dimensional Potentials
5.1 Introduction . . . . . . . . .
5.2 Infinite Potential Well . . . .
5.3 Square Potential Barrier . . .
5.4 WKB Approximation . . . .
5.5 Cold Emission . . . . . . . .
5.6 Alpha Decay . . . . . . . . .
5.7 Square Potential Well . . . .
5.8 Simple Harmonic Oscillator
6 Multi-Particle Systems
6.1 Introduction . . . . . . .
6.2 Fundamental Concepts .
6.3 Non-Interacting Particles
6.4 Two-Particle Systems . .
6.5 Identical Particles . . . .

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7 Three-Dimensional Quantum Mechanics

7.1 Introduction . . . . . . . . . . . . .
7.2 Fundamental Concepts . . . . . . .
7.3 Particle in a Box . . . . . . . . . . .
7.4 Degenerate Electron Gases . . . . .
7.5 White-Dwarf Stars . . . . . . . . . .

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CONTENTS

8 Orbital Angular Momentum

8.1 Introduction . . . . . . . . . . . . . . .
8.2 Angular Momentum Operators . . . . .
8.3 Representation of Angular Momentum
8.4 Eigenstates of Angular Momentum . . .
8.5 Eigenvalues of Lz . . . . . . . . . . . .
8.6 Eigenvalues of L2 . . . . . . . . . . . .
8.7 Spherical Harmonics . . . . . . . . . .

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103
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110

9 Central Potentials
9.1 Introduction . . . . . . . . . . .
9.2 Derivation of Radial Equation .
9.3 Infinite Spherical Potential Well
9.4 Hydrogen Atom . . . . . . . . .
9.5 Rydberg Formula . . . . . . . .

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126

10 Spin Angular Momentum

10.1 Introduction . . . . . .
10.2 Spin Operators . . . . .
10.3 Spin Space . . . . . . .
10.4 Eigenstates of Sz and S2
10.5 Pauli Representation .
10.6 Spin Precession . . . .

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129
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136

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141
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147

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151
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170

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11 Addition of Angular Momentum

11.1 Introduction . . . . . . . . . . . . . . . . .
11.2 General Principles . . . . . . . . . . . . . .
11.3 Angular Momentum in the Hydrogen Atom
11.4 Two Spin One-Half Particles . . . . . . . .
12 Time-Independent Perturbation Theory
12.1 Introduction . . . . . . . . . . . . . .
12.2 Improved Notation . . . . . . . . . .
12.3 Two-State System . . . . . . . . . . .
12.4 Non-Degenerate Perturbation Theory
12.5 Quadratic Stark Effect . . . . . . . . .
12.6 Degenerate Perturbation Theory . . .
12.7 Linear Stark Effect . . . . . . . . . . .
12.8 Fine Structure of Hydrogen . . . . . .
12.9 Zeeman Effect . . . . . . . . . . . . .
12.10 Hyperfine Structure . . . . . . . . . .
13 Time-Dependent Perturbation Theory

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175

QUANTUM MECHANICS
13.1
13.2
13.3
13.4
13.5
13.6
13.7
13.8
13.9
13.10
13.11
13.12
13.13
13.14

Introduction . . . . . . . . . . . . . .
Preliminary Analysis . . . . . . . . . .
Two-State System . . . . . . . . . . .
Spin Magnetic Resonance . . . . . . .
Perturbation Expansion . . . . . . . .
Harmonic Perturbations . . . . . . . .
Electromagnetic Radiation . . . . . .
Electric Dipole Approximation . . . .
Spontaneous Emission . . . . . . . .
Radiation from a Harmonic Oscillator
Selection Rules . . . . . . . . . . . .
2P 1S Transitions in Hydrogen . .
Intensity Rules . . . . . . . . . . . . .
Forbidden Transitions . . . . . . . . .

14 Variational Methods
14.1 Introduction . . . . . .
14.2 Variational Principle . .
14.3 Helium Atom . . . . .
14.4 Hydrogen Molecule Ion

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15 Scattering Theory
15.1 Introduction . . . . . . . . . .
15.2 Fundamentals . . . . . . . . .
15.3 Born Approximation . . . . . .
15.4 Partial Waves . . . . . . . . .
15.5 Determination of Phase-Shifts
15.6 Hard Sphere Scattering . . . .
15.7 Low Energy Scattering . . . .
15.8 Resonances . . . . . . . . . . .

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175
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194

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Quantum Mechanics: Professor of Physics The University of Texas at Austin

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Quantum Mechanics: Professor of Physics The University of Texas at Austin

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Quantum Mechanics

Evolution of Wave Packets . . . .

4 Fundamentals of Quantum Mechanics

7 Three-Dimensional Quantum Mechanics

8 Orbital Angular Momentum

10 Spin Angular Momentum

11 Addition of Angular Momentum

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