eprintid: 77195 rev_number: 10 eprint_status: archive userid: 16805 dir: disk0/00/07/71/95 datestamp: 2013-03-26 14:10:19 lastmod: 2021-09-23 08:37:18 status_changed: 2013-03-26 14:10:19 type: article metadata_visibility: show creators_name: Krakovský, I. creators_name: Hanus, J. creators_name: Pleštil, J. creators_name: Baldrian, J. creators_name: Salmerón-Sánchez, M. creators_orcid: 0000-0002-8112-2100 title: Structure and swelling behaviour of epoxy networks based on α,ω-diamino terminated poly(oxypropylene)-block-poly(oxyethylene)-block-poly(oxypropylene) ispublished: pub divisions: 30303000 abstract: Structure and swelling behaviour of hydrophilic epoxy networks prepared from α,ω-diamino terminated poly(oxypropylene)-block-poly(oxyethylene)-block-poly(oxypropylene) and diglycidyl ether of brominated Bisphenol A in dependence on the initial molar ratio of reactive amino and epoxy groups has been investigated by small- and wide-angle X-ray scattering (SAXS and WAXS), differential scanning calorimetry (DSC) and dynamic mechanic analysis (DMA). Anomalous swelling behaviour of the networks in water has been found. The anomaly is attributed to the changing microphase separation in the networks controlled by their composition and crosslinking density, and inhomogeneous swelling on nanometer space scale. date: 2005-01-06 date_type: published id_number: 10.1016/j.polymer.2004.10.073 uniqueid: glaseprints:2005-77195 published_online: 2004-11-23 issn_online: 1873-2291 scopus_impact: 9 scopus_cluster: 2-s2.0-10044272211 scopus_datestamp: 2013-10-26 09:33:32 wos_impact: 9 wos_cluster: WOS:000226316700012 wos_datestamp: 2013-05-21 23:21:15 full_text_status: none publication: Polymer volume: 46 number: 1 pagerange: 109-119 refereed: TRUE issn: 0032-3861 hoa_compliant: 305 hoa_date_pub: 2004-11-23 hoa_exclude: FALSE hoa_gold: FALSE citation: Krakovský, I., Hanus, J., Pleštil, J., Baldrian, J. and Salmerón-Sánchez, M. (2005) Structure and swelling behaviour of epoxy networks based on α,ω-diamino terminated poly(oxypropylene)-block-poly(oxyethylene)-block-poly(oxypropylene). Polymer , 46(1), pp. 109-119. (doi: 10.1016/j.polymer.2004.10.073 )