eprintid: 76790 rev_number: 10 eprint_status: archive userid: 16805 dir: disk0/00/07/67/90 datestamp: 2013-03-25 11:27:03 lastmod: 2021-09-23 08:33:35 status_changed: 2013-03-25 11:27:03 type: article metadata_visibility: show creators_name: Salmerón-Sánchez, M. creators_name: Molina Mateo, J. creators_name: Romero Colomer, F.J. creators_name: Gómez Ribelles, J.L. creators_orcid: 0000-0002-8112-2100 title: Nanoindentation and tapping mode AFM study of phase separation in poly(ethyl acrylate-co-hydroxyethyl methacrylate) copolymer networks ispublished: pub divisions: 30303000 abstract: According to our previous results the free radical copolymerization of ethyl acrylate and hydroxyethyl methacrylate gives rise to a system having chain composition and morphology different from that of the random mixture in the original solution. Besides, structural relaxation experiments revealed the existence of composition heterogeneity in the material. In this work, a deeper insight in the structure of this system is gained using atomic force microscopy (AFM) in the tapping mode and nanoindentation experiments. The material architecture of the copolymerized system is revealed to be formed by nanoaggregates as a consequence of the non-random polymerization process of the comonomers. date: 2006-06 date_type: published id_number: 10.1016/j.eurpolymj.2005.12.018 uniqueid: glaseprints:2006-76790 published_online: 2006-02-21 issn_online: 1873-1945 scopus_impact: 11 scopus_cluster: 2-s2.0-33748046816 scopus_datestamp: 2013-10-26 09:27:59 wos_impact: 11 wos_cluster: WOS:000238524300020 wos_datestamp: 2013-05-21 22:55:11 full_text_status: none publication: European Polymer Journal volume: 42 number: 6 pagerange: 1378-1383 refereed: TRUE issn: 0014-3057 hoa_compliant: 305 hoa_date_pub: 2006-02-21 hoa_exclude: FALSE hoa_gold: FALSE citation: Salmerón-Sánchez, M. , Molina Mateo, J., Romero Colomer, F.J. and Gómez Ribelles, J.L. (2006) Nanoindentation and tapping mode AFM study of phase separation in poly(ethyl acrylate-co-hydroxyethyl methacrylate) copolymer networks. European Polymer Journal , 42(6), pp. 1378-1383. (doi: 10.1016/j.eurpolymj.2005.12.018 )