Issue 16, 2000
From the journal:

Chemical Communications

Unusual double-bond migration as a plausible key reaction in the biosynthesis of the isoprenoidal membrane lipids of methanogenic archaeaElectronic supplementary information (ESI) available: 1H NMR and 1H–1H COSY spectra. See http://www.rsc.org/suppdata/cc/b0/b003948i/

Tadashi Eguchi,*a   Hayato Takyo,a   Mikio Morita,b   Katsumi Kakinuma*b  and  Yosuke Kogac  

* Corresponding authors

a Department of Chemistry and Materials Science, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo, Japan.
E-mail: [email protected]

b Department of Chemistry, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo, Japan

c Department of Chemistry, University of Occupational and Environmental Health, Yahatanishi-ku, Kitakyushu, Japan

Abstract

Labeling experiments of mevalonolactone-d9 were pursued for studies of the biosynthesis of the core membrane lipids from thermophilic methanogenic archaea, which revealed that unusual double-bond migration occurred during the ultimate formation of the saturated isoprenoid chains in these particular archaea.

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Article information

DOI
https://doi.org/10.1039/B003948I
Article type
Communication
Submitted
17 May 2000
Accepted
21 Jun 2000
First published
26 Jul 2000

Chem. Commun., 2000, 1545-1546

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Unusual double-bond migration as a plausible key reaction in the biosynthesis of the isoprenoidal membrane lipids of methanogenic archaea

T. Eguchi, H. Takyo, M. Morita, K. Kakinuma and Y. Koga, Chem. Commun., 2000, 1545 DOI: 10.1039/B003948I

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