In organometallic chemistry, A-frame complexes are coordination compounds that contain two bridging bidentate ligands and a single atom bridge. They have the formula M2(μ-X)(bd)2L2, where bd is a bidentate ligand like dppm, and X and L are a wide variety of ligands. The term was coined to describe products arising from the oxidative addition to Rh(I)Rh(I) complexes.
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