20-07-2025

6001CJA10102125SRG05 JA

PHYSICS

SECTION-I(i)

1) The circuit shown in the diagram extends to the right into infinity. Each battery has the
electromotive force V (unknown) and the internal resistance r (known). Each resistor has the
resistance 4r. The reading of the ideal ammeter shown in the diagram is I. Find the value of V in

terms of I and r.

(A)

(B)

(C) V = 4.5 Ir
(D) V = 3.0 Ir

2) Between the plates of a parallel-plate capacitor, there is a metallic plate whose thickness takes up
60% of the capacitor gap. When that plate is absent the capacitor has a capacity C = 20nF. The
capacitor is connected to a dc voltage source of voltage =100 V. The metallic plate is slowly
extracted from gap. Find the mechanical work (in μJ) performed in the process of plate extraction.

(A) 150
(B) 100
(C) 200
(D) 250

3) When a body is placed in surroundings at a constant temperature of 20°C, and heated by a 10-W
heater, its temperature remains constant at 40°C. If the temperature of the body is now raised from
20°C to 80°C in 5 minutes at a uniform rate, the total heat it will lose to the surroundings will be-
[Assume Newton's law of cooling]

(A) 3000 J
(B) 3600 J
(C) 4500 J
(D) 5400 J

4) If two electric charges q and –2q are placed at distance 6a apart, then locus of point in the plane
of charges, where electric potential is zero is : (Take charge q at origin and –2q lies on positive x-
axis)
(A) x2 + y2 + 4ax – 6a2 = 0
(B) x2 + y2 + 4ax – 12a2 = 0
(C) x2 + y2 + 2ax – 12a2 = 0
(D) x2 + y2 – 4ax + 12a2 = 0

SECTION-I(ii)

1) Two large thin conducting plates with small gap in between are placed in a uniform electric field
E (perpendicular to the plates). Area of each plate is A and charges +Q and –Q are given to these
plates as shown in the figure. If points R,S and T as shown in the figure are three points in space,

then the

(A) field at point R is E

(B) field at point S is E

(C)
field at point T is

(D)
field at point S is

2) A hemispherical shell of mass 2M and radius 6R and a point mass M are performing circular
motion due to their mutual gravitational interaction. Their positions are shown in figure at any
moment of time during motion. If r1 and r2 are the radii of circular path of hemispherical shell and
point mass respectively and ω1 and ω2 are the angular speeds of hemi-spherical shell and point mass

respectively, then choose the correct statement(s).

(A)

(B)

(C)
(D)

3) For the resistance network shown in the figure, choose the correct option(s).

(A) the current through PQ is zero

(B) I1 = 3A
(C) The potential at S is less than that at Q
(D) I2 = 1A

4) The figure shows a graph of the current in a discharging circuit of a capacitor through a resistor

of resistance 10Ω.

(A) The initial potential difference across the capacitor is 100 volt.

(B)
The capacitance of the capacitor is .
(C) The total heat produced in the circuit will be 500 Joules.

(D)
The thermal power in the resistor will decrease with a time constant second.

SECTION-II

1) Two charged balls are connected by an inextensible thread of length 3 m. Masses of balls are 2
kg and 1 kg, the charges are +20 μC and –100 μC. What minimum constant external force F (in
newton)must be applied to the ball of mass 1 kg so that the thread does not slack? Neglect gravity
and friction.

2) A cylindrical block of length 0.4 m and area of cross-section 0.04m2 is placed coaxially on a thin
metal disc of mass 0.4 kg and of the same cross-section. The upper face of the cylinder is maintained
at a constant temperature of 400K and the initial temperature of the disc is 300K. If the thermal
conductivity of the material of the cylinder is 10 watt/m-K and the specific heat of the material of the
disc is
600 J/kg-K, how long (in s) will it take for the temperature of the disc to increase to 350K? Assume,
for purposes of calculation, the thermal conductivity of the disc to be very high and the system to be
thermally insulated except for the upper face of the cylinder.

3) A galvanometer of coil resistance 1Ω is converted into voltmeter by using a resistance of 5Ω in

series and another identical galvanometer is converted into ammeter by using a shunt of 1Ω. Now
ammeter and voltmeter connected in circuit as shown, find the ratio of reading of voltmeter (in volts)

and ammeter (in amperes).

4) The diagram shows four capacitors with capacitances and break down voltages as mentioned.
What should be the maximum value of the external emf source such that no capacitor breaks down?

(Answer in KV)

5) A square non-conducting sheet of side a has uniform charge density σ. A point charge Q is placed
at perpendicular distance d = a above one of it's vertices. Then component of electric force acting on

sheet perpendicular to its plane is F. Find .

6) A small object is placed at the center of a large evacuated hollow spherical container. Assume that
the container is maintained at 0 K. At time t = 0, the temperature of the object is 200 K. The
temperature of the object becomes 100 K at t = t1 and 50 K at t = t2. Assume the object and the
container to be ideal black bodies. The heat capacity of the object does not depend on temperature.
The ratio (t2/t1) is____.

7) The resistance of uniform wire AB is 9Ω. Find the resistance of part BC (in Ω) for which
galvanometer G will show zero deflection.

8) If C is equal to 2000 μF then find the summation of charges (in C) on all capacitors after steady

state.

CHEMISTRY

SECTION-I(i)

1) Which of the following is NOT matched correctly?

(A)

Reaction through SN1 and rearrangement.

(B) Reaction through SNi

(C)
Reaction through SN2 reaction
(D)

Reaction through SN2, inversion product is formed as major

2) A dilute solution of NaCl is placed between two Pt electrodes which are 8.5cm apart. A potential
difference of 7.5 volt is applied across the electrodes, what will be the distance travelled by Na+ in 1
hr
Given

(A) 2.3 cm
(B) 4.8 cm
(C) 3.5 cm
(D) 7.8 cm

3) The Henry's law constant for the solubility of N2 gas in water at 298K is 1.0 × 105 atm. The mole
fraction of N2 in air is 0.8. The number of moles of N2 from air dissolved in 10 moles of water at 298K
and 5atm pressure is

(A) 4.0 × 10–4

(B) 4.0 × 10–5
(C) 5.0 × 10–4
(D) 4.0 × 10–6

4) More number of oxidation states are exhibited by the actinoids than by the lanthanoids. The main
reason for this is:

(A) greater metallic character of the lanthanides than that of the corresponding actinides
(B) lesser energy difference between 5f and 6d-orbitals than that between 4f and 5d-orbitals
(C) more active nature of actinoids
(D) more energy difference between 5f and 6d-orbitals than that between 4f and 5d-orbitals

SECTION-I(ii)

1) When excess KMnO4 is added to concentrated H2SO4 an oily green color covalent compound X is
formed. Which of the following is/are TRUE?

(A) X is formed by a dehydration reaction

(B) In 'X', Mn is octahedrally surrounded by 'O' atoms
(C) X is an amphoteric oxide
(D) X contains a bridge bond
2) In the electrolysis of a 27.372 lit CuSO4 solution, there are two possible reactions at anode
(i) and (ii)
A current of 1.0A is passed for 2.0 hrs. The loss in mass of the Cu anode was 1.50g. Now, select the
CORRECT statement(s) of the following ([Link]. of Cu = 63.5 g mol–1)

(A) 0.07461 mol of electrons are passed through the solution during entire electrolysis
(B) 153.4 mL of O2(g) is liberated at NTP at anode
(C) Fraction of current used in the production of Cu2+ ions = 0.633
(D) pH around anode drops to 3

3) Two liquids A and B form an ideal solution. The solution has a vapor pressure of 700 torr at 80°C.
It is distilled till 2/3rd of the solution is collected as condensate. The composition of the condensate
is and that of the residue is . If the vapor pressure of the residue at 80°C is 600
torr, which of the following is/are TRUE?
0
[ xA , , represent mole fractions of liquid A ; P A and PB0 are pure vapour pressures of A and B]

(A) The composition of the original liquid was xA = 0.6

(B) The composition of the original liquid was xA = 0.4
0
(C) P A = 2500/3 torr
0
(D) PB = 500 torr

4) Which of the following radical(s) decolourise acidified KMnO4 without evolving any gas

(A)
(B)
(C)
(D)

SECTION-II

0
1) If "X" represents standard reduction potential (E , in V) of and "Y" represents
0
standard reduction potential (E , in V) of then |X–Y| is

[Given: ]

2) An aqueous solution is prepared by dissolving 0.1 mol of an ionic salt in 0.9 kg of water at 35°C.
The salt remains 80% dissociated in the solution. The vapour pressure of the solution is 59.500 mm
of Hg. Vapour pressure of water at 35°C is 60.000 mm of Hg. The number of ions present per
formula unit of the ionic salt is ____.
(Nearest integer value)

3) How many of the following statements with regards to the Lanthanides (Ln) is/are correct:
(i) The common oxidation state of Ln is +3
(ii) Ce+4 salts act as stronger oxidising agents
(iii) Ln can produce H2(g) when it reacts with dil. HCl as well as with H2O.
(iv) All Ln(OH)3 are basic
(v) Mischmetal, an alloy of lanthanoids has approx. 5% iron and traces of S, C, Ca and Al.

4) Consider the following reaction sequence:

The total possible number of dibromo derivative of (D) are

5) Water insoluble gas is being collected over contaminated water in a container of capacity 4 litre
at 300K. Pressure observed was 18.5 atmosphere. Mole fraction of non-volatile solute particles in
contaminated water is 0.3427. How many numbers of moles of insoluble gas must have been
collected in the container? (aq. tension of pure water at 300K is 31.8 mm Hg, R = 0.082 lit atm
mol–1 K–1)

6) The values of for HCl, NaCl, CH3COONa are 421.5, 126 & 91 S cm2/mol respectively. The
resistance of conductivity cell with cell constant 2.01cm–1 is 520Ω, when filled with 0.1M CH3COOH.
Find pH of solution in the conductivity cell.

7)
During conversion of three molecules of R–OH into three molecules of R–Cl using PCl3, how many
times SN (Nucleophilic substitution) reaction takes place?

8) Which compounds give an substitution reaction on treatment with alcoholic NaSH?

 MATHEMATICS

SECTION-I(i)

1) If , where , then the value of

(A) 3
(B)
(C)

(D)

2) Let ; .
Then which of the following statement is(are) true?

(A) There are exactly 35 increasing functions from S to T.

(B) There are more than 350 continuous functions from S to T.
(C) There are less than 350 differential functions from S to T.
(D) Every continuous function from S to T is not differentiable.

3) For the equation

, Which of the following statement is not true?

(A) For , the equation has 2 distinct real solutions

(B) For , the equation has 3 distinct real solutions
(C) For , the equation has 3 distinct real solutions
(D) For , the equation has infinite solutions

4) If f : , ; . Then at

then |k| is equal to ______.

(A) 5
(B) 4
(C) 8
(D) 3

SECTION-I(ii)
1) Let f(x) be a continuous function satisfying and . If

then which of the following options is/are CORRECT?

(A)

(B)

(C) Number of points where g(x) is non-derivable is 3

(D) Number of points where g(x) is non-derivable is 5

2) Let denotes greatest integer function be the function defined as

. Then which of the following is/are CORRECT?

(A) The function f is dis-continuous at exactly two points.

There exists exactly two points in (0,1) at which the function f is continuous but NOT
(B)
differentiable.
(C) The function f(x) is Not differentiable at more than three points in (0,1).
(D) The minimum value of f is 0

3) If , then
identify which of the following statement(s)is /are correct?

(A)
There exists atleast one real value of x which satisfy the equation

(B)
There exists atleast one real value of x which satisfy the equation

(C)
There exists no real value of x which satisfy the equation
There exists atleast one real value of x which satisfy the equation
(D)

4) Which of the following is/are TRUE?

(A) The equation , has at least one solution then the number
of integers in range of k is 1

(B) The equation , has at least one solution if

(C)
If , then the value of
(D) satisfies and , for
all , then minimum value of k is equal to 2

SECTION-II

1) If . Then value of b+c is (where [.] denotes

greatest integer function)

2) Let and , then the value

of equals

3) The value of the is , then is equal to

4) Let A( 3,2), B(2,5) be two given points. If the point P(0,k) on y axis is such that |PA PB| attains

its greatest value, then is equal to

5) Define the sequence and for each , then

______.

6) The number of Solution(s) of equation is/are (here

[.] represents greatest integer less than or equal to 'x')

7) The equations of the sides AB, BC, CA of a triangle ABC are 2x + y = 0, x + py = q, x y = 3

respectively. The point P is (2,3) If P is the centroid then the value of p +q is and if P(2,3)is the
orthocenter of the triangle then the value of p + q is then

8) The sum of all real root(s) of the equation is ______

 ANSWER KEYS

PHYSICS

SECTION-I(i)

Q. 1 2 3 4
A. B A C B

SECTION-I(ii)

Q. 5 6 7 8
A. A,D B,C A,B,C A,B

SECTION-II

Q. 9 10 11 12 13 14 15 16
A. 3.00 166.00 to 168.00 1.00 2.5 24.00 9.00 3.00 4.00

CHEMISTRY

SECTION-I(i)

Q. 17 18 19 20
A. D A A B

SECTION-I(ii)

Q. 21 22 23 24
A. A,D A,B,C,D A,C,D B,C

SECTION-II

Q. 25 26 27 28 29 30 31 32
A. 0.47 to 0.48 5 5 4 2.98 to 3.02 2 6 5

MATHEMATICS

SECTION-I(i)

Q. 33 34 35 36
A. D C C B

SECTION-I(ii)

Q. 37 38 39 40
A. A,D A,D A,C A,C,D
 SECTION-II

Q. 41 42 43 44 45 46 47 48
A. 2.00 3.00 2.00 2.00 1.00 0 11.00 0
 SOLUTIONS

PHYSICS

1)

⇒ R2 – 4rR – 4r2 = 0

⇒
Resistance can not be negative, so

2) wext + wB = uf – ui

ui =

uf =
wB = ΔQv

wext = =

3) Let θ = the temperature of the body,

θ0 = the temperature of the surroundings = 20°C (given).

Rate of loss of heat =

For , = 10 = k(40 – 20) ⇒ k =

When the temperature of the body is raised uniformly, its temperature is given by

t = 20 + ,
where t = time in seconds
∴ = =

4) According to question

⇒ (x– 6a)2 + y2 = 4(x2 + y2)

⇒ x2 + y2 + 4ax – 12a2 = 0

5)

6) The system is equivalent to a binary system as shown in the diagram.

r2 = 2R
Considering the circular motion of point mass m

7)
Since resitances in two arms upper and lower are in same ratio.
Current through PQ is zero.

, and Potential of S is less than that at Q.

8) Formula Used:
• Initial Voltage Across the Capacitor: V0 = i0 R
Where i0 is the initial current and R is the resistance.
• Current Decay Equation:

• Capacitance from Current Decay:

Where t is the time, i0 is the initial current, and i is the current at time t.

• Heat Produced:
• Thermal Power: P=I2R
Calculation (in brief):
Step 1: Calculate Initial Voltage Across the Capacitor
From the graph, the initial current i0 = 10A and the resistance R = 10 Ω. Using V0 = i0R, we
calculate:

Step 2: Calculate Capacitance

Using the current decay equation , we solve for C. From the graph, at t =
2 seconds, i = 2.5 A. Using the equation:

Step 3: Calculate Heat Produced

The heat produced is equal to the energy stored in the capacitor, which is:

Substituting and :

Step 4: Calculate Thermal Power and Time Constant

The thermal power is given by P = i2R, and using the decay formula, the time constant is τ
=RC.
From the current equation, the time constant is:

Answer:
• Option 1: The initial potential difference across the capacitor is 100 V .
• Option 2: The capacitance of the capacitor is .

• Option 3: The total heat produced in the circuit will be Joules.

• Option 4: The thermal power in the resistor will decrease with a time constant of
seconds.

9)
Fext = 3a ⇒ a = Fext / 3

10) Ans. 166.3 sec

θ = temp of disc
θ0 = constant temp

Heat input to disc =

Heat utilised by disc =

S = Specific heat of disc

= ⇒

⇒ ⇒ t = 166.32 sec

11)

The circuit according to question will be

It can be redrawn as

Let reading of ammeter be i. Then i1 = i/3 clearly.

Reading of voltmeter is V = i1 × 3Ω = i/3 × 3 = i
V/i = 1.

12) Q1max = 3 C × 103 C.

Q2max = 4 C × 103 C.
Qmax for first branch 3 C × 103 C

=
Similarly for second branch
= 7C ×103 C = 6C × 103C

= = kV
The two branches are in parallel. So in order to find max value of voltage for which no
capacitor breaks down < .

13)

dF⊥ = (σdA) Ecosθ

F⊥ = σ [Electric flux through sheet]

14)

15)
VA = VC ∴ 5 – 2i = 0

i= A
Now apply KVL
10 + 5 = i(1 + 2 + r)
15 = 2.5 (3 + r)
r = 3Ω
(r is the resistance of BC)

16) 500 – 10 i + 2000 – 15 i = 0

⇒i=
 Now VPQ = 1000 and Ceq = C
⇒ Q = VPQ × C =2
summation of charges = 2Q = 4

CHEMISTRY

17) 3°R – OH involves SN1 reaction

18)

Dist = 2.3 cm

19) According to Henry's law,

( = Partial pressure of N2)
Given, Total pressure = 5 atm
mole fraction of N2 = 0.8
Partial pressure of N2 = 0.8 × 5 = 4

no. of moles of H2O,

no. of nmoles of N2,

20)

21)

22) Amount of Cu Converted to Cu2+ ions

Amount of electrons involved

Amount of electrons actually passed through solution

Amount of electrons involved in converting H2O to O2 = 0.07461 – 0.04724 = 0.02737 mol

Amount of oxygen liberated at anode

Volume of O2 gas produced at NTP at anode
Hence, (B) is correct.

Also, fraction of current used in the production of Cu2+ ions

Hence, (C) is also correct.
Mol. of H+ ions produced at anode = 0.02737 mol

pH = 3
Hence, (D) is correct.

23) ...(i)
...(ii)
if moles of A & B initially are x & y then

Solving given
xA = 0.6 xB = 0.4

24)
Sn+2 + KMnO4 → Sn+4 + Mn+2
SO3–2 + KMnO4 → SO4–2 + Mn+2

25)
For the required reaction

Similarly for "Y"

E = 1.77/6=0.295
Ans. = 0.48

26) 0.1 mole ionic salt in 0.9 kg water at 35°C

Vapour pressure of solution = 59.500 mm of Hg
Vapour pressure of pure H2O = 60.000 mm of Hg
Let the number of ions present per formula unit of the ionic salt be 'x'

Total moles of non-volatile particles = 0.02 + 0.08 x in 0.9 kg water.

Moles of water

Relative lowering of vapour pressure

= Mole fraction of non- volatile particles

x=5

27)

28)

(since the above molecule, possesses no symmetry element, so, possible number of optically
active isomers = 22 = 4)

29)

Now we know,

and

30)
 31) 3 times by R–OH at RX3, & 3 times by at protonated P(OR)

32) c, d, e, f & h

MATHEMATICS

33)

34) and

No. of continuous/differentiable function = 73

35) Plot the graphs of

y=
36)

37)
Number of points where function is not differentiable = 5

38)

f(x) is discontinuous and non-differentiable at

39)
There exist x.

No value of x.
(c) & (d) x = 2 only solution (but )

40) (a)

(b)

(d)

41)

x=0+h
42) ,

43)

44) A = ( 3,2), B=(2,5)

Reflection of A in y — axis is A'=(3,2)
Equation of A'B is y = 3x + 11 which intersect y axis at P (0, 11)
[PA PB| is maximum at P (0, 11)

45) Let . Then and .

Since we have
and inductively .
Hence,
for all , so .
By ,

.
46) [.] is always integer
L.H.S is even, R.H.S is odd.

47)

48) Given equation is odd.

Sum = 0