27-07-2025

1721CJA101021250017 JM

PHYSICS

SECTION-I

1) In the figure shown the current flowing through 2R is:

(A) from left to right

(B) from right to left
(C) no current
(D) None of these

2) For a particular resistance X in the figure shown the thermal power generated in ‘Y’ is maximum
when Y = 4Ω. Then X is:

(A) 2Ω
(B) 3Ω
(C) 1Ω
(D) 6Ω

3) In the figure shown the current through 2Ω resistor is

(A) 2 A
(B) 0 A
(C) 4 A
(D) 6 A

4) An insulating pipe of cross-section area 'A' contains an electrolyte which has two types of ions,
their charges being –e and +2e. A potential difference applied between the ends of the pipe result in
the drifting of the two types of ions, having drift speed = v (–ve ion) and v/4 (+ve ion). Both ions
have the same number per unit volume = n. The current flowing through the pipe is :

(A)

(B)

(C)

(D)

5) A fuse-wire is a wire of :

(A) low resistance and low melting point

(B) high resistance and low melting point
(C) low resistance and high melting point
(D) high resistance and high melting point

6) In the arrangement of the experiment of the metre-bridge, if AC corresponding to null deflection

of galvanometer is x, what would be its value if the radius of the wire AB is doubled?

(A) x
(B) x/4
(C) 4x
(D) 2x

7) A milliammeter of range 10 mA and resistance 9 Ω is joined in a circuit as shown. The metre gives
full-scale deflection for current I when A and B are used as its terminals, i.e., current enters at A and
leaves at B (C is left isolated). The value of I is
(A) 100 mA
(B) 900 mA
(C) 1 A
(D) 1.1 A

8) In the circuit shown the resistance of voltmeter is 10,000 ohm and that of ammeter is 20 ohm. The
ammeter reading is 0.10 Amp and voltmeter reading is 12 volt. Then R is equal to

(A) 122 Ω
(B) 140 Ω
(C) 116 Ω
(D) 100 Ω

9) A galvanometer together with an unknown resistance in series is connected to two identical

batteries each of 1.5V. When the batteries are connected in series, the galvanometer records a
current of 1A, and when the batteries are in parallel the current is 0.6A. What is the internal
resistance of the battery?

(A)

(B)

(C)

(D)

10) n identical cells are connected initially in series and then in parallel. What is the ratio of
maximum possible powers dissipated in both cases?

(A) n
(B) n2
(C) 1/n
(D) 1

11) The circuit given has two cells in opposition to each other. One cell has an emf of 6V and internal
resistance of 2Ω and the other cell has an emf of 4V and internal resistance of 8Ω. The potential
difference across the terminals X and Y is

(A) 5.4 V
(B) 5.6 V
(C) 5.8 V
(D) 6.0 V

12) Eight cells marked 1 to 8 each of emf 5V and internal resistance 0.2 Ω are connected as shown in
the figure. What is the reading of the ideal voltmeter V?

(A) 40 V
(B) 20 V
(C) 5 V
(D) Zero

13) The internal resistances of cells in the circuit shown in the figure are negligible. The current in
the circuit is
(A) 0.5 A flowing from A to D
(B) 0.5 A flowing from B to C
(C) 1.0 A flowing from A to B
(D) 1.0 A flowing from B to A

14) In the given circuit,

The current through branch AB is

(A) zero
(B) 2 A from A to B
(C) 2 A from B to A
(D) 5A from A to B

15) In the circuit, the galvanometer G shows zero deflection. If the batteries A and B have negligible
internal resistances, the value of the resistor R will be :

(A) 200 Ω
(B) 100 Ω
(C) 500 Ω
(D) 1000 Ω
16) Find the equivalent resistance across AB.

(A) 1 Ω
(B) 2 Ω
(C) 3 Ω
(D) 4 Ω

17) Six identical resistors are connected as shown in figure. The equivalent resistance will be :

(A) maximum between P and R

(B) maximum between Q and R
(C) maximum between P and Q
(D) all are equal

18) Calculate the current I in the circuit shown in figure?

(A) 2 A
(B) 1 A
(C) 3 A
(D) 4 A

19) The resistor in which the maximum heat is produced is given by

(A) 2 Ω
(B) 3 Ω
(C) 4 Ω
(D) 12 Ω

20) All the resistors of the circuit in the figure have same resistance R Ω . The current through the
resistor AB is

(A)

(B)

(C)

(D) Zero

SECTION-II

1) For the part of the circuit shown in the figure, the current through the 2 Ω resistor is
2) In the circuit shown in figure, all wires have equal resistance r. If the equivalent resistance

between A and B is then the value of m + n = ?

3) Given that 5.0 A passes along the branch from C to B in figure what is the voltage of point A?

4) A circuit shown in the figure has resistances 20Ω and 30Ω. At what value of resistance Rx will the
thermal power generated in it be practically independent of small variations of that resistance? The
voltage between points A and B is supposed to be constant in this case.
5) A fuse made up of a particle material goes out at current of 10 amp. Then the threshold current
for another fuse of 4 times radius of cross section made of same material is 16 × N(amp). Then N =
?

CHEMISTRY

SECTION-I

1) In the reaction C(s) + CO2(g) ⇌ 2CO(g), the equilibrium pressure is 12 atm. If 50% of CO2 reacts
then Kp will be:

(A) 12 atm
(B) 16 atm
(C) 20 atm
(D) 24 atm

2) If pressure is increased on the equilibrium N2(g) + O2(g) 2NO(g), the equilibrium will

(A) shift in the forward direction

(B) shift in the backward direction
(C) remains undisturbed
(D) may shift in the forward or backward direction

3)

The conversion of ozone into oxygen is exothermic. Under what conditions is ozone the most stable?

2O3(g) 3O2(g)
(A) At low pressure and low temperature
(B) At high pressure and high temperature
(C) At high pressure and low temperature
(D) At low pressure and high temperature

4) For the equilibrium SO2Cl2(g) SO2(g) + Cl2(g), what is the temperature at which ?
(A) 0.027 K
(B) 0.36 K
(C) 36.54 K
(D) 273 K

5) For a reaction N2 + 3H2 2NH3, the value of KC does not depends upon :-
(a) Initial concentration of the reactants
(b) Pressure
(c) Temperature (d) Catalyst

(A) Only a
(B) a, b, c
(C) a, b, d
(D) a, b, c, d

6) At 527°C the reaction :

NH3(g) N2(g) + H2 (g) has Kc = 4

What is Kp for the reaction
N2(g) + 3H2(g) 2NH3(g) :

(A) 16 × (800 R)2

(B)

(C)

(D) None of these

7) 2AB2(g) 2AB(g) + B2 (g)

Degree of dissociation of AB2 is x. What will be equation for x in terms of KP and equilibrium
pressure P ?

(A)

(B)

(C)

(D)
Kp= ×P

8) Assume that the decomposition of HNO3 can be represented by the following equation : 4HNO3(g)

4NO2(g) + 2H2O(g) + O2(g) and the reaction approaches equilibrium at 400 K temperature
and 30 atm pressure. At equilibrium partial pressure of HNO3 is 2 atm.
Calculate KC in (mol/L)3 at 400 K :
(Use : R = 0.08 atm-L/mol-K)

(A) 4
(B) 8
(C) 16
(D) 32

9) Let ΔU1 and ΔU2 be the changes in internal energy of an ideal gas in the processes A and B then :-

(A) ΔU1 = ΔU2

(B) ΔU1 > ΔU2
(C) ΔU1 < ΔU2
(D) ΔU1 ≠ ΔU2

10)

A piston filled with 0.04 mol of an ideal gas expands reversibly from 50.0 mL to 375 mL at a constant
temperature of 37.0ºC. As it does so, it absorbs 208 J of heat. The values of q and w for the process
will be:
(R = 8.314 J/mol K) (ln 7.5 = 2.01)

(A) q = +208 J, w = – 208 J

(B) q = –208 J, w = – 208 J
(C) q = –208 J, w = + 208 J
(D) q = +208 J, w = + 208 J

11) Which of the following statements are correct ?

(a) Both work and heat appears at the boundaries of system.
(b) Heat given to a system is given +ve sign.
(c) Heat given to a system is equal to increase in internal energy under isothermal conditions.
(d) Heat given to a system is used to increase internal energy under isochoric conditions.
(e) Both work and heat are not state functions but their sum (q + w) is state function.

(A) (a),(b),(d),(e)
(B) (a),(c),(d),(e)
(C) (a),(b),(c),(d)
(D) (b),(c),(d),(e)

12) Two moles of helium gas undergo a cyclic process as shown in figure. Assuming gas to be ideal,
what is the net work involved in the cyclic process
(A) –100 R ln 4
(B) +100 R ln 4
(C) –200 R ln 4
(D) +200 R ln 4

13) Rate of decarboxylation of following carboxylic acid with sodalime will be in order

(A) r1 > r2 > r3

(B) r3 > r2 > r1
(C) r2 > r3 > r1
(D) r1 > r3 > r2

14) Which of the following alkene has minimum heat of hydrogenation :

(A)

(B)

(C)

(D)

15)

Arrange the acid derivative in the order of nucleophilic substitution reaction :-

(A) Acid halide (B) Ester

(C) Anhydride (D) Amide

(A) A > B > C > D
(B) B > C > A > D
(C) A > C > B > D
(D) D > B > C > A

16) Which of the following can not give iodoform test ?

(A) Ethanol
(B) Ethanal
(C) Acetophenone
(D) Benzophenone

17) Which of the following reactions would give the best yield of t-butyl methyl ether ?

(A)

(B) (CH3)3C–Br + CH3OH —→

(C)

(D)

18) on mercuration-
demercuration produces the major product :-

(A)

(B)

(C)

(D)

19)
In above reaction out of the following which will be obtained in maximum yield.
(A)

(B)

(C)

(D)

20)
Select best reagent to carry out above conversion.

(A) LiAlH4
(B) NaBH4
(C) NH2–NH2+H2O2
(D) H2 (excess) / Ni, Δ

SECTION-II

1)
Find the molar mass of Z.

2) How many positional isomers are possible for dimethylcyclohexane :

3) At 1990 K and 1 atm pressure, there are equal number of Cl2 molecules and Cl atoms in the
reaction mixture. The value KP for the reaction Cl2(g) ⇌ 2Cl(g) under the above conditions is x × 10–1.
The value of x is _______.
(Rounded off to the nearest integer)

4) A mixture of 1 mole of H2O and 1 mole of CO is taken in a 10 litre container and heated to 725 K.
At equilibrium 40% of water by mass reacts with carbon monoxide according to the equation :
CO(g) + H2O(g) CO2(g) + H2(g)
The equilibrium constant Kc 102 for the reaction is _________. (Nearest integer)

5)

If work done by the system is 300 joule when 100 cal heat is supplied to it. The change in internal
energy during the process is (in joule) ?

MATHS

SECTION-I

1) Two rays are drawn through a point A at an angle of 30° . A point B is taken on one of them at a
distance 'a' from the point A. A perpendicular is drawn from the point B to the other ray and another
perpendicular is drawn from its foot to AB to meet AB at another point from where the similar
process is repeated indefinitely. The length of the resulting infinite polygon line is

(A)

(B)

(C) a
(D) None of these

2) The number of pairs (x,y) satisfying the equations and is

(A) 0
(B) 1
(C) 2
(D) None of these

3) The smallest positive number P for which the equation has a solution
in is

(A)

(B)

(C)

(D)
4) Number of positive values of x for which 2 cos x, |cos x| and 1 - 3 cos2 x are in G.P., lying
in is

(A) 1
(B) 2
(C) 3
(D) None of these

5) The number of solutions of the equation :

(A) 0
(B) 1
(C) 2
(D) 3

6) Minimum value of function , where is

(A)

(B)

(C)

(D)

7) The global maximum value of the function on the

set A = {x| x2 – 4x < 0}

(A) 2034
(B) 2036
(C) does not exist
(D) 2156

8) For the equation , where 0 < a < b < 1/2, then which of
the following is true -

(A) there is no real root of the equation in (a, b)

(B) there is exactly one real root of the equation in (a, b)
(C) there is atleast one root of the equation in (a, b)
(D) none of these

9) Let f(x) = x3 + bx2 + ax + 12 (b ≠ 0). If (–3, 2) is the largest possible interval for which f(x) is
decreasing function then the value of ‘a’ is :

(A) 3
(B) 9
(C) –9
(D) –18

10)

If ex+y = (y – x)2, then is equal to (where C is constant of integeration)-

(A) ex+y + (y – x) + C
(B) (y + x)2 + (y – x) + C

(C)

(D)

11) =

(A)

(B)

(C)

(D)

12) If and

Where and C is constant of integration,

then the value of α + 2β + 3γ – 4δ is equal to:

(A) 1
(B) –4
(C) –8
(D) 4

13) The integral equals :

(A)

(B)

(C)

(D)

14) If
(where C is constant of integration), then w is equal to-

(A)

(B)

(C)

(D)

15) equals
(where C is integration constant)

(A)
+C

(B)
+C

(C)
+C

(D)
+C

16)

Let y = y(x), y(1) = 1 and y(e) = e2. Consider , J – I = g(x) and g(1) = 1,
then the value of g(e) is -

(A) 3e + 1
(B) e + 1
(C) e2 – e + 2
(D) e2 + e – 2

17) Let .Then is equal to:

(A) 10 loge 2 – 6
(B) 10 loge 2 + 6
(C) 5 loge 2 + 3
(D) 5 loge 2 – 3

18)

(A)
loge

(B)
loge

(C)
loge

(D)
loge

19) Let the function f : [0, 2] → R be defined as where [t] denotes

the greatest integer less than or equal to t. Then the value of the integral is

(A) 2e – 1

(B)

(C)

(D)

20) The value of is -

(A)

(B) 2
(C) 4
(D) undefined

SECTION-II

1) The complete set of values of x satisfying and in is

then find the value of .

2) The number of solution of the equation

is

3)

Let and .

If 25I = aπ + bln where a,b,c and d ∈N and is not a perfect square of a rational then find the
value of (a + b + c + d).

4) If θ is the acute angle between the curves y = |x2 – 1| and y = |x2 – 3| at their point of intersection
when x > 0, then 49 tan2θ is equal to

5) If the tangent at any point P(4m2, 8m3) of x3 – y2 = 0 is also a normal at any other point to the
curve x3 – y2 = 0 then 9m2 is
 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B B B D A A C D C D B D B B B A C B C D

SECTION-II

Q. 21 22 23 24 25
A. 1 8 14 12 5

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B C B C C D A D A A A A A C C D D A B B

SECTION-II

Q. 46 47 48 49 50
A. 101 4 5 44 120

MATHS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B D D B B D B C D D A D B A B B A B C C

SECTION-II

Q. 71 72 73 74 75
A. 6 2 62 32 2
 SOLUTIONS

PHYSICS

1) from right to left

2) Ans. 3Ω

3) CORRECT ANS. 0 A

4)
i = n(e) Av = neAv
inet = i+ + i

5) low resistance and low melting point

6) Ans. x

7) Correct Ans. 1 A

8) Ans. 100 Ω

9) Ans.

10) Ans .. 1

11) Correct Ans. 5.6 V

12) Ans. Zero

13) 0.5 A flowing from B to C

14) 2 A from A to B

15) Correct Ans. 100 Ω

16)
 Correct Ans. 1 Ω

17) maximum between P and Q

18) Correct Ans. 1 A

19) Ans. 4 Ω

20) Ans. Zero

21) Correct Ans. 1

22)

Correct Ans. 8

23) Correct Ans. 14

24) Correct Ans. 12

25) Correct Ans. 5

CHEMISTRY

26)

Explanation

The equilibrium constant Kp is calculated using the partial pressures of gases in a chemical
reaction.

Given Data

A. Reaction: C(s) + CO2(g) ⇌ 2CO(g)

B. Equilibrium pressure: 12 atm

C. 50% of CO2 reacts

D. Find Kp (Equilibrium constant in terms of pressure)

 Concept

A. Equilibrium Constant Expression:

B. Kp = (PCO)2/PCO2

Calculation

A. Initially: Let P0 be the initial pressure of CO2.

B. Change: Since 50% of CO2 reacts, the change in pressure of CO2 is -0.5P0, and CO
produced is +2(0.5P0) = P0.

C. At equilibrium: PCO2 = 0.5 P0, PCO = P0​

D. Total pressure at equilibrium: Ptotal = PCO2 + PCO = 0.5P0 + P0 = 1.5 P0 = 12 atm

E. Solving for P0 : P0 = 12/1.5 = 8 atm

F. PCO2 = 0.5P0 = 4 atm, PCO = 8 atm

A. Kp = (PCO)2/PCO2 = (8)2/4 = 64/4 = 16 atm

Answer option 2(16 atm)

27)

Question Explanation:

Find effect of pressure on equilibrium.

Concept:

This question is based on Le-chatelier's principle.

Solution:

N2(g) + O2(g) ⇌ 2NO(g), Δng = 0

When Δng = 0 then no. effect of change in pressure.

Final Answer:

The correct option is (3).

28) Based on Le-Chatelier's Principle.

29) KP = KC × (RT)Δng
Δng = 1
KP = KC × (RT)

3 = 0.082 × T

30) Kc depends only temperature.

31) For reaction , N2(g) + 3H2(g) 2NH3(g)

Kc =

Kp = (R × 800)–2

32) 2AB2 2AB + B2

Initial 2 0 0
Final 2–2x 2x x
total no. of moles = 2 –2x + 2x + x = 2 + x

33) Ptotal =
∵
∴ Ptotal =
⇒ 30–2 = ×7

Kp =

= = 220
Kp = Kc = Kc (0.08 × 400)3
⇒ Kc = = 32

34) ΔU is state function.

35)

n = 0.4 mole
V1 = 50 ml = 50 cm3 = 50 × 10–6m3
V2 = 375 ml = 375 cm3 = 375 × 10–6m3
T = 37°C = 310 K
q – +208J (because heat is absorbed)
∴ it is an isothermal process
∴ ∆T = 0
∴ ∆U = nCv∆T = 0
∴ 0 = DU = q + w
∴ q = –w
∴ w = –208J

36) Conceptual.

37)

= + 600 R ln 2

= –2R(400 – 300) = –200 R

= – 200 R ln 2
= – 100 R ln 4

38)

Rate of decarboxylation α stability of carbanion

39) Heat of hydrogenation

(1) 3 α-H
(2) 6 α-H
(3) 10 α-H
(4) 4 α-H
Stability = 3 > 2 > 4 > 1
 H.O.H. = 3 < 2 < 4 < 1

40) Reactivity for N.S.R ⇒ Acid Halide > Anhydride > Ester > Amide

41) Concept:

containing group, primary alcohol, secondary alcohol containing hydrocarbon

gives Iodoform test.

42) If substrate alkyl halide or alcohols one bulkier & branched, then due to carb-cation
formation favour elimination reaction or from alkene whereas substrate is smaller &
unbranched (CH3–Br) shows SN2 reaction with attacking base or form branched ether.

43) Mercuration & Demercuration follows markawnicoff's rule (Addition of H–OH)

44) Rate of NAR ∝ magnitude of +ve

charge at or

45) NaBH4 can not reduce ester group.

46)

47) , , ,

48) Cl2 ⇌ 2Cl

Let mol of both of Cl2 and Cl is x
 49)

50) Δu will be same as u is a state function.

MATHS

51)

52)
53)

54)

55)
56)
⇒ ƒ'(x) = secx – 0 + 0 – cosecx
⇒ ƒ'(x) = secx – cosecx

ƒ'(x) = 0 ⇒ (minima)

57) f'(x) = 3x2 – 15x + 18

= 3(x2 – 5x + 6)

x2 – 4x ≤ 0 ⇒ 0 ≤ x ≤ 4
f(x)

f(z) = 8 – 30 + 36 + 2020
= 2034
f(4) = 64 – 120 + 72 + 2020 = 2036

58) Consider ƒ (x) = sin–1x

by LMVT in [a, b]

for atleast one c ∈(a, b)

sin–1b – sin–1a =

⇒
 59)

f ′ (x) = 3x2 + 2bx + a

Roots of f ′ (x) = 0 should be – 3 and 2.

60)

Let (y – x) = t ⇒

61) Let r = ;
s=

P Q r s r→s

T T F F F F T

T F T F T F F

F T T T T F F

F F T F T T T

Option (A) :
is equivalent to (not of only P) (not of only Q) = (Both P, Q) and (neither P nor Q)

62)

x lnx – x = t
⇒ [Link] = dt

⇒α=β=γ=δ=2
α + 2β + 3γ – 4δ = 4

63)
64)

So

65) Let x = ;

66) J – I =
g(x) =
Put x = 1 ⇒ 1=1+c ⇒ c=0

∴ g(x) =
g(e) = e + 1

67)

……..(1)

replace

……(2)

Eq. (1) × 5 – eq. (2) × 4

I= = 10 loge 2 – 6

68)

69) Minimum {x2 , {x}} = x2 ;

70)

71) (1)
&

(2)

72)

73) dx

Now 4I + 3J =

=
=
∴ 3I – 4J =

Now 4 × (4I + 3J) = 4 ×

adding 25I = 2p + 3ln

a = 2, b = 3, c = 28, d = 29
a + b + c + d = 62

74)
Point of intersaction when

y = x2 – 1 & y = 3 – x 2

&

75)

Equation of tangent at P(4m2, 8m3)

y – 8m3 = 3m(x – 4m2)
y = 3mx – 4m3 …(2)
2 3
y =x …(1)
Solving (1) and (2)

⇒
⇒
⇒
⇒
⇒