Touch 18
1. Find the oxidation numbers of all the atoms in the following species
1) SO3
2) NO" !
3) H2S
4) SO!$#
5) CO!$%
6) C! O!$#
7) H3PO3
8) H3PO4
9) CH4
10) CCl4
11) CHCl3
12) CH2Cl2
13) H2O2
14) K2O2
15) KO2
16) NaCl
17) MgBr2
18) CaO
19) S! O!$
%
20) NO$ !
21) NO$ %
22) HCN
23) Cr! O!$&
24) CrO!$#
25) MnO$ #
2. Balance the following redox reactions
1) Fe + MnO$ OH $ Fe2+ + MnO2
#
H"
2) S + HNO3 H2SO4 + NO2
1
3. Balance the following redox reactions using both oxidation number change method and half reaction
method
i. H2S + HNO3 S + NO2 (H+ medium)
ii. H2O2 + Cr3+ H2O + CrO!$
# (OH- medium)
iii. C + HNO3 CO2 + NO2
iv. NO$
% + Al NH3 + AlO$ -
! (OH medium)
v. Cu2+ + I- Cu+ + I2
4. A sample of 1.5 g of an impure K2Cr2O7 was dissolved in dilute H2SO4 and water was added to make the
final volume 250.0 cm3. A volume of 25.0 cm3 of that was taken in to a flask and excess KI was added.
The formed I2 was titrated with 0.1 mol dm-3 Na2S2O3 and end point was recorded at 24.00 cm3.
(K – 39, Cr – 52, O – 16)
i. Write balanced chemical equations for all the reactions taking place
ii. Find the mass % of K2Cr2O7 in the impure sample