Max Planck: Pioneer of Quantum Theory
Max Planck: Pioneer of Quantum Theory
In October 1878, Planck passed his qualifying exams and in February 1879 defended his dissertation
Über den zweiten Hauptsatz der mechanischen Wärmetheorie (On the Second Law of Mechanical Heat
Theory). He briefly taught mathematics and physics at his former school in Munich.
By the year 1880, Planck had obtained the two highest academic degrees offered in Europe. The first was
a doctorate degree after he completed his paper detailing his research and theory of thermodynamics.[7]
He then presented his thesis called Gleichgewichtszustände isotroper Körper in verschiedenen
Temperaturen (Equilibrium states of isotropic bodies at different temperatures), which earned him a
habilitation.
Career
With the completion of his habilitation thesis, Planck became an
unpaid Privatdozent (German academic rank comparable to
lecturer/assistant professor) in Munich, waiting until he was
offered an academic position. Although he was initially ignored by
the academic community, he furthered his work on the field of
heat theory and discovered one after another the same
thermodynamical formalism as Gibbs without realizing it.
Clausius's ideas on entropy occupied a central role in his work.
Entropy
Thermodynamics, also known as the "mechanical theory of heat" at the end of the 19th century, had
emerged at the beginning of this century from an attempt to understand the functioning of steam engines
and to improve their efficiency. In the 1840s, several researchers independently discovered and
formulated the law of conservation of energy, which is now also known as the first law of
thermodynamics. In 1850, Rudolf Clausius formulated the so-called second law of thermodynamics,
which states that a voluntary (or spontaneous) transfer of energy is only possible from a warmer to a
colder body, but not vice versa. In England at this time William Thomson came to the same conclusion.
Clausius generalized his formulation further and further and came up with a new formulation in 1865. To
this end, he introduced the concept of Entropy, which he defined as a measure of the reversible supply of
heat in relation to the absolute temperature.
The new formulation of the second law, which is still valid today, was: "Entropy can be created, but never
destroyed". Clausius, whose work Planck read as a young student during his stay in Berlin, successfully
applied this new law of nature to mechanical, thermoelectric and chemical processes.
In his dissertation in 1879, Planck summarized Clausius' writings, pointing out contradictions and
inaccuracies in their formulation and then clarifying them. In addition, he generalized the validity of the
second law to all processes in nature, Clausius had limited its application to reversible processes and
thermal processes. Furthermore, Planck dealt intensively with the new concept of entropy and
emphasized, that entropy is not only a property of a physical system, but at the same time a measure of
the irreversibility of a process: If entropy is generated in a process, it is irreversible, since entropy cannot
be destroyed according to the second law. In reversible processes, the entropy remains constant. He
presented this fact in detail in 1887 in a series of treatises entitled "On the Princip of the Increase of
Entropy".[24]
In his study of the concept of entropy, Planck did not follow the molecular, probabilistic interpretation
that prevailed at the time, as these do not provide absolute proof of universality. Instead, he pursued a
phenomenological approach and was also skeptical of atomism. Even though he later abandoned this
attitude in the course of his work on the law of radiation, his early work impressively shows the
possibilites of thermodynamics in solving concrete physicochemical problems.[25][26]
Planck's understanding of entropy included the realization that the maximum of entropy corresponds to
the equilibrium state. The accompanying conclusion that knowledge of the Entropy allows all laws of
thermodynamic equilibrium states to be derived corresponds to the modern understanding of such states.
Planck therefore chose equilibrium processes as his research focus and, based on his habilitation thesis,
researched the coexistence of aggregate states and the equilibrium of gas reactions, for example. This
work on the frontier of chemical thermodynamics also received great attention due to the rapidly
expanding chemical work at that time.
Independently of Planck, Josiah Willard Gibbs had also discovered almost all the knowledge Planck
gained about the properties of physicochemical equilibria and published them from 1876 onwards. Planck
was unaware of these essays, and they did not appear in German until 1892. However, both scientists
approached the topic in different ways, while Planck dealt with irreversible processes, Gibbs looked at
equilibria. This approach was finally able to prevail because of its simplicity, but Planck's approach is
attributed the greater universality.[27]
Black-body radiation
In 1894, Planck turned his attention to the problem of black-body
radiation. The problem had been stated by Kirchhoff in 1859:
"how does the intensity of the electromagnetic radiation emitted
by a black body (a perfect absorber, also known as a cavity
radiator) depend on the frequency of the radiation (i.e., the color
of the light) and the temperature of the body?". The question had
been explored experimentally, but no theoretical treatment had
agreed with the experimentally observed evidence. Wilhelm Wien
proposed Wien's law, which correctly predicted the behaviour at
high frequencies, but failed at low frequencies. The Rayleigh–
Jeans law, another approach to the problem, agreed with
experimental results at low frequencies, but created what was later
known as the "ultraviolet catastrophe" at high frequencies, as
predicted by classical physics. However, contrary to many
textbooks, this was not a motivation for Planck.[28]
The central assumption behind his new derivation, presented to the DPG on 14 December 1900, was the
supposition, now known as the Planck postulate, that electromagnetic energy could be emitted only in
quantized form, in other words, the energy could only be a multiple of an elementary unit:
where h is the Planck constant, also known as Planck's action quantum (introduced already in 1899), and
ν is the frequency of the radiation. Note that the elementary units of energy discussed here are
represented by hν and not simply by ν. Physicists now call these quanta photons, and a photon of
frequency ν will have its own specific and unique energy. The total energy at that frequency is then equal
to hν multiplied by the number of photons at that frequency.
Max Born wrote about Planck: "He was, by nature, a conservative mind; he had nothing of the
revolutionary and was thoroughly skeptical about speculations. Yet his belief in the compelling force of
logical reasoning from facts was so strong that he did not flinch from announcing the most revolutionary
idea which ever has shaken physics."[1]
Einstein's hypothesis of light quanta (photons), based on Heinrich Hertz's 1887 discovery (and further
investigation by Philipp Lenard) of the photoelectric effect, was initially rejected by Planck. He was
unwilling to discard completely Maxwell's theory of electrodynamics. "The theory of light would be
thrown back not by decades, but by centuries, into the age when Christiaan Huygens dared to fight
against the mighty emission theory of Isaac Newton ..."[34]
In 1910, Einstein pointed out the anomalous behavior of specific heat at low temperatures as another
example of a phenomenon which defies explanation by classical physics. Planck and Walther Nernst,
seeking to clarify the increasing number of contradictions, organized the First Solvay Conference
(Brussels 1911). At this meeting Einstein was able to convince Planck.
Meanwhile, Planck had been appointed dean of Berlin University, whereby it was possible for him to call
Einstein to Berlin and establish a new professorship for him (1914). Soon the two scientists became close
friends and met frequently to play music together.
In 1915, when Italy was still a neutral power, Planck voted successfully for a scientific paper from Italy,
which received a prize from the Prussian Academy of Sciences, where Planck was one of four permanent
presidents.
In October 1920, he and Fritz Haber established the Notgemeinschaft der Deutschen Wissenschaft
(Emergency Organization of German Science), aimed at providing financial support for scientific
research. A considerable portion of the money the organization would distribute was raised abroad.
Planck held leading positions at Berlin University, the Prussian Academy of Sciences, the German
Physical Society, and the Kaiser Wilhelm Society (which became the Max Planck Society in 1948).
During this time economic conditions in Germany were such that he was hardly able to conduct research.
In 1926, Planck became a foreign member of the Royal Netherlands Academy of Arts and Sciences.[37]
During the interwar period, Planck became a member of the Deutsche Volks-Partei (German People's
Party), the party of Nobel Peace Prize laureate Gustav Stresemann, which aspired to liberal aims for
domestic policy and rather revisionistic aims for politics around the world.
Planck disagreed with the introduction of universal suffrage and later expressed the view that the Nazi
dictatorship resulted from "the ascent of the rule of the crowds".[38]
Quantum mechanics
At the end of the 1920s, Niels Bohr, Werner
Heisenberg, and Wolfgang Pauli had worked out
the Copenhagen interpretation of quantum
mechanics, but it was rejected by Planck, and by
Schrödinger, Laue, and Einstein as well. Planck
expected that wave mechanics would soon render
quantum theory – his own child – unnecessary.
This was not to be the case, however. Further
work only served to underscore the enduring
central importance of quantum theory, even
against his and Einstein's philosophical
revulsions. Here Planck experienced the truth of
From left to right: W. Nernst, A. Einstein, Planck, R. A.
his own earlier observation from his struggle Millikan, and von Laue at a dinner given by von Laue in
with the older views during his younger years: Berlin on 11 November 1931
"A new scientific truth does not triumph by
convincing its opponents and making them see
the light, but rather because its opponents eventually die, and a new generation grows up that is familiar
with it."[39]
Otto Hahn asked Planck to gather well-known German professors in order to issue a public proclamation
against the treatment of Jewish professors, but Planck replied, "If you are able to gather today 30 such
gentlemen, then tomorrow 150 others will come and speak against it, because they are eager to take over
the positions of the others."[41] Under Planck's leadership, the Kaiser Wilhelm Society (KWG) avoided
open conflict with the Nazi regime, except concerning the Jewish Fritz Haber. In May of 1933 Planck
requested and received an interview with the recently appointed Chancellor of Germany Adolf Hitler to
discuss the issue, telling him that the "forced immigration of Jews would kill German science and Jews
could be good Germans", to which the chancellor replied "but we don't have anything against the Jews,
only against communists". Planck was therefore unsuccessful, since this reply "took from him every basis
for further negotiation",[42] as to Hitler "the Jews are all Communists, and these are my enemies." In the
following year, 1934, Haber died in exile.[43]
One year later, Planck, having been the president of the KWG since 1930, organized in a somewhat
provocative style an official commemorative meeting for Haber. He also succeeded in secretly enabling a
number of Jewish scientists to continue working in institutes of the KWG for several years. In 1936, his
term as president of the KWG ended, and the Nazi government pressured him to refrain from seeking
another term.
As the political climate in Germany gradually became more hostile, Johannes Stark, prominent exponent
of the Deutsche Physik ("German Physics", also called "Aryan Physics") attacked Planck, Arnold
Sommerfeld, and Heisenberg for continuing to teach the theories of Einstein, calling them "white Jews".
The "Hauptamt Wissenschaft" (Nazi government office for science) started an investigation of Planck's
ancestry, claiming that he was "1/16 Jewish", but Planck denied it.[44]
In 1938, Planck celebrated his 80th birthday. The DPG held a celebration, during which the Max-Planck
medal (founded as the highest medal by the DPG in 1928) was awarded to French physicist Louis de
Broglie. At the end of 1938, the Prussian Academy lost its remaining independence and was taken over
by Nazis (Gleichschaltung). Planck protested by resigning his presidency. He continued to travel
frequently, giving numerous public talks, such as his talk on Religion and Science, and five years later he
was sufficiently fit to climb 3,000-metre peaks in the Alps.
During the Second World War the increasing number of Allied bombing missions against Berlin forced
Planck and his wife to temporarily leave the city and live in the countryside. In 1942, he wrote: "In me an
ardent desire has grown to persevere this crisis and live long enough to be able to witness the turning
point, the beginning of a new rise." In February 1944, his home in Berlin was completely destroyed by an
air raid, annihilating all his scientific records and correspondence. His rural retreat was threatened by the
rapid advance of the Allied armies from both sides.
In 1944, Planck's son Erwin was arrested by the Gestapo following the attempted assassination of Hitler
in the 20 July plot. He was tried and sentenced to death by the People's Court in October 1944. Erwin was
hanged at Berlin's Plötzensee Prison in January 1945. The death of his son destroyed much of Planck's
will to live.[45]
After living in the apartment in Berlin, the Planck family lived in a villa in Berlin-Grunewald,
Wangenheimstrasse 21. Several other professors from University of Berlin lived nearby, among them
theologian Adolf von Harnack, who became a close friend of Planck. Soon the Planck home became a
social and cultural center. Numerous well-known scientists, such
as Albert Einstein, Otto Hahn and Lise Meitner were frequent
visitors. The tradition of jointly performing music had already
been established in the home of Helmholtz.
During the First World War Planck's second son Erwin was taken
prisoner by the French in 1914, while his oldest son Karl was
killed in action at Verdun. Grete died in 1917 while giving birth to
her first child. Her sister died the same way two years later, after Planck's grave in Göttingen
having married Grete's widower. Both granddaughters survived
and were named after their mothers. Planck endured these losses
stoically.
In January 1945, Erwin Planck, to whom he had been particularly close, was sentenced to death by the
Nazi Volksgerichtshof because of his participation in the failed attempt to assassinate Hitler in July 1944.
Erwin was executed on 23 January 1945.[46]
After World War II ended, Planck, his second wife, and their son were brought to a relative in Göttingen,
where Planck died on October 4, 1947. He was buried in the old Stadtfriedhof (City Cemetery) in
Göttingen.[47]
Religious views
Planck was a member of the Lutheran Church in Germany.[48] He
was very tolerant toward alternative views and religions.[49] In a
lecture in 1937 entitled "Religion und Naturwissenschaft"
("Religion and Natural Science") he suggested the importance of
these symbols and rituals related directly with a believer's ability
to worship God, but that one must be mindful that the symbols
provide an imperfect illustration of divinity. He criticized atheism
for being focused on the derision of such symbols, while at the
same time warned of the over-estimation of the importance of
such symbols by believers.[50]
Planck said in 1944, "As a man who has devoted his whole life to the most clear headed science, to the
study of matter, I can tell you as a result of my research about atoms this much: There is no matter as
such. All matter originates and exists only by virtue of a force which brings the particle of an atom to
vibration and holds this most minute solar system of the atom together. We must assume behind this force
the existence of a conscious and intelligent spirit [orig. geist]. This spirit is the matrix of all matter."[51]
Planck argued that the concept of God is important to both religion and science, but in different ways:
"Both religion and science require a belief in God. For believers, God is in the beginning, and for
physicists He is at the end of all considerations … To the former He is the foundation, to the latter, the
crown of the edifice of every generalized world view".[52]
..."to believe" means "to recognize as a truth", and the knowledge of nature, continually
advancing on incontestably safe tracks, has made it utterly impossible for a person
possessing some training in natural science to recognize as founded on truth the many reports
of extraordinary occurrences contradicting the laws of nature, of miracles which are still
commonly regarded as essential supports and confirmations of religious doctrines, and which
formerly used to be accepted as facts pure and simple, without doubt or criticism. The belief
in miracles must retreat step by step before relentlessly and reliably progressing science and
we cannot doubt that sooner or later it must vanish completely.[53]
Noted historian of science John L. Heilbron characterized Planck's views on God as deistic.[54] Heilbron
further relates that when asked about his religious affiliation, Planck replied that although he had always
been deeply religious, he did not believe "in a personal God, let alone a Christian God".[55]
Publications
Planck, M. (1900a). "Über eine Verbesserung der Wienschen Spektralgleichung" ([Link]
[Link]/stream/verhandlungende01goog#page/n212/mode/2up). Verhandlungen der
Deutschen Physikalischen Gesellschaft. 2: 202–204. Translated in ter Haar, D. (1967). "On
an Improvement of Wien's Equation for the Spectrum" ([Link]
o_maletin/Planck%20%281900%29,%20Improvement%20of%20Wien%[Link]) (PDF). The
Old Quantum Theory. Pergamon Press. pp. 79–81. LCCN 66029628 ([Link]
029628).
Planck, M. (1900b). "Zur Theorie des Gesetzes der Energieverteilung im Normalspectrum"
([Link] Verhandlungen
der Deutschen Physikalischen Gesellschaft. 2: 237. Translated in
ter Haar, D. (1967). "On the Theory of the Energy Distribution Law of the Normal Spectrum" ([Link]
[Link]/web/20160920053757/[Link]
0%29,%20Distribution%[Link]) (PDF). The Old Quantum Theory. Pergamon Press. p. 82.
LCCN 66029628 ([Link] Archived from
the original ([Link]
ck%20%281900%29,%20Distribution%[Link]) (PDF) on 20
September 2016. Retrieved 5 April 2014.
See also
Biographies portal
Physics portal
List of things named after Max Planck
German inventors and discoverers
Photon polarization
Statue of Max Planck
Zero-point energy
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28. For a solid approach to the complexity of Planck's intellectual motivations for the quantum,
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41. In a slightly different translation, Hahn remembers Planck saying: "If you bring together 30
such men today, then tomorrow 150 will come to denounce them because they want to take
their places." This translated quote is found in: Heilbron, 2000, p. 150. Heilbron, at the end
of the paragraph, on p. 151, cites the following references to Hahn's writings: Otto Hahn
Einige persönliche Erinnerungen an Max Planck MPG, Mitteilungen (1957) p. 244, and Otto
Hahn My Life (Herder and Herder, 1970) p. 140.
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51. "Das Wesen der Materie" [The Nature of Matter], speech at Florence, Italy (1944) (from
Archiv zur Geschichte der Max-Planck-Gesellschaft, Abt. Va, Rep. 11 Planck, Nr. 1797)
52. "Religion and Natural Science" (Lecture Given 1937) Scientific Autobiography and Other
Papers, trans. F. Gaynor (New York, 1949), pp. 184
53. Max Planck, Scientific Autobiography and Other Papers
54. J. L. Heilbron (1986). The Dilemmas of an Upright Man: Max Planck and the Fortunes of
German Science. Harvard University Press. p. 198. ISBN 978-0-674-00439-9. "On the other
side, Church spokesmen could scarcely become enthusiastic about Planck's deism, which
omitted all reference to established religions and had no more doctrinal content than
Einstein's Judaism. It seemed useful therefore to paint the lily, to improve the lesson of
Planck's life for the use of proselytizers and to associate the deanthropomorphizer of
science with a belief in a traditional Godhead."
55. Heilbron, 2000, page 198 ([Link]
Archived ([Link]
=d5zKH2Bx2AwC&pg=PA198) 17 April 2018 at the Wayback Machine
Sources
Aczel, Amir D. Entanglement, Chapter 4. (Penguin, 2003) ISBN 978-0-452-28457-9
Heilbron, J. L. (2000). The Dilemmas of an Upright Man: Max Planck and the Fortunes of
German Science ([Link] Harvard University
Press. ISBN 0-674-00439-6.
Pickover, Clifford A. Archimedes to Hawking: Laws of Science and the Great Minds Behind
Them, Oxford University Press, 2008, ISBN 978-0-19-533611-5
Medawar, Jean; Pyke, David (2012). Hitler's Gift: The True Story of the Scientists Expelled
by the Nazi Regime (Paperback). New York: Arcade Publishing. ISBN 978-1-61145-709-4.
Rosenthal-Schneider, Ilse Reality and Scientific Truth: Discussions with Einstein, von Laue,
and Planck (Wayne State University, 1980) ISBN 0-8143-1650-6
External links
Works by Max Planck ([Link] at Project
Gutenberg
Works by Max Planck ([Link] at
Faded Page (Canada)
Works by or about Max Planck ([Link]
A%22Planck%2C%20Max%22%20OR%20subject%3A%22Max%20Planck%22%20OR%2
0creator%3A%22Planck%2C%20Max%22%20OR%20creator%3A%22Max%20Planck%2
2%20OR%20creator%3A%22Planck%2C%20M%2E%22%20OR%20title%3A%22Max%20
Planck%22%20OR%20description%3A%22Planck%2C%20Max%22%20OR%20descriptio
n%3A%22Max%20Planck%22%29%20OR%20%28%221858-1947%22%20AND%20Planc
k%29%29%20AND%20%28-mediatype:software%29) at the Internet Archive
Works by Max Planck ([Link] at LibriVox (public domain
audiobooks)
Annotated bibliography for Max Planck ([Link]
[Link]/[Link]?browse=people%2FPlanck%2C+Max) from the Alsos Digital
Library for Nuclear Issues
Max Planck ([Link] – Encyclopædia
Britannica article
Max Planck Biography ([Link]
[Link]) – [Link]
Max Planck Institutes of Natural Science and Astrophysics ([Link]
Max Planck – Selbstdarstellung im Filmportrait (1942) ([Link]
_continue=175&v=5mwHXBn6mcM), [Cinematic self-portrait of Max Planck], Berlin-
Brandenburgische Akademie der Wissenschaften, 1942
Max Planck ([Link] on [Link] including the Nobel
Lecture, 2 June 1920 The Genesis and Present State of Development of the Quantum
Theory
Life–Work–Personality ([Link] – Exhibition on the 50th anniversary
of Planck's death
Newspaper clippings about Max Planck ([Link] in
the 20th Century Press Archives of the ZBW