Reversible Reactions
Definitions: Chemical Reactions that can go in both forward and reverse directions
One of the reactions(Forward/Backward)-> Exothermic/Another-> Endothermic
Dynamic Equilibrium: If a reversible reaction is carried out in the closed container so that products
and reactants cannot escape, a state of dynamic equilibrium is established.
Dynamic: Forward/Reverse reactions are ongoing Exothermic: Anhydrous->hydrated
Equilibrium: Endothermic: Hydrated->Anhydrous
- Rate of forward reactions and reverse reactions are the same
- Concentration of products and reactants do not change
- Occur inside the closed system
Factors affecting the position of equilibrium
- Concentration of products and reactants
- Pressure (only in gaseous state)
- Temperature
Catalysts do not have effect on equilibrium
Effect of temperature on equilibrium
- Temperature decreases-> favors/equilibrium shifts to exothermic reaction side
- Temperature increases->favors endothermic reaction side
Effect of pressure on equilibrium
- Pressure increases->favors/equilibrium shifts to the side of lesser mole
- Pressure decreases->favors the side of greater mole
- Gas-> Pressure effect/ Solid, Liquid-> No pressure effect/does not need to calculate mole
- If the moles/volumes are the same on both side (reactants/products), there is no pressure
effect.
Effect of concentration on equilibrium
- More reactants-> Shift to the right to increase the concentration of products and reduce
amount of reactants
- Less reactants-> Shift to the right to increase the concentration of products and reduce
amount of products
- More products-> Shift to the left to increase the concentration of products and reduce the
amount of reactants
- Less products-> Shift to the left to increase the concentration of products and reduce the
amount of reactants.
Catalysts: Increase the rate of reaction on both forward and reverse reactions equally so position of
equilibrium do not change