| il Atomic Structure S518 D © CHEMISTRY [Link]wSaral Contents 1 Module Description 2 Homework Index 3 Exercise 1 4, Exercise 1A 5. Exercise 2 6 Exercise 2A 7 Answer Key Note Page - ii Page - ii Page - 1 Page - 7 Page - 11 Page - 14 Page - 17 Detailed solutions are available on the eSaral App. Atomic Structure wWSaral & at wae area SlwSaral Atomic Structure Module Description For mastering the concepts only learning is not sufficient. We have to practice and apply those concepts in problem solving. This sheet does just that. It contains a collection of problems segregated in the following exercises to help you master the concepts in a systematic and organized way. “Practice makes a man perfect” 1. Concept builder—1& 1A As soon as you have finished learning the concept do the problems from these exercises first These exercises contains easy level questions to help you build your concepts. 1 —+» Contains Single Correct Type questions 1A —» Contains pattern based questions incorporating the latest JEE Advanced based patterns like more than one correct, matching list, match the column, ete. 2. Brain Booster— 2 & 2A Now that you have built your concepts it’s time to master them by solving Brain Boosting problems, Don’t hurry through these problems. Take time to solve & learn from them. These exercises contains Medium & Tough level problems. Do questions from 2 & 2A after attempting I & 1A 2 —+ Single Correct Type questions. 2A ——» Pattern Based questions. 3. Simulator — JM & JA Contains questions from previous year JEE Mains & JEE Advanced questions in exercise JM & exercise JA respectively. Get the real taste & feel of the type of questions being asked in JEE. It’s a great tool for simulating your mind with JEE problems. These exercises are not included in the module but are provided separately. JM —» JEE Mains previous years topic wise questions. JA —+ IEE Advance previous years topic wise questions. Eee scat (rodwSaral Home Work Index Problem solving is an integral part of learning, Atomic Structure Find questions to solve after each video in the homework Index. Make sure that you attempt all the problems (in Ex 1 to 2A) after learning a topic from the videos. For example if you have finished topic 8, first attempt all the problems listed in the index corresponding to topic 8 before proceeding to the video of topic 9. [Link]. Topic Name Ext | Exta | Ex2 | Ex2A 1 [Discovery of electron and its charge | 1-2 1 2 |Rutherford's model 3-7 2 3 Size of Nucleus 8,9 26-27, 32 1 4 [Wave theory lo-11,13 2 5 [Planck's theory 12, 14-15] 3,28 3-4 3 5-8, 6 |Bohr’s model 627 | 4523 fe fa4a7i7 8, 10, 7 |SpectrumRydberg formula 28-34 6-7 maa | RM 8 Photoelectric effect 35-39 9-10, 15-17 9,12 g _|Pebrosle’s hypothess & Hesenbere’s | ag 4g |g ti.3i | 915-16} 11,13 uncertainty principle 12, 13, 18-22 er 49-54 a * 10 | Quantum Numbers S BP a9 7 14 11 |Radial probabiity distribution fanction | 55-58 2s 1-22 | 2 12. |Rules for fling ofeletron 59, 64 23-24 13. |Eleotronic configuration 60-63 30 25-28 14 |tticher clement & Magnetic moment | 65-66 4 29 15 _ [Basic concept ofchemistry 67-69 wWSaral & at wae area SlwSaral Exercise - 1 Atomic Structure Concept Builder SINGLE CORRECT TYPE Each question has FOUR options for correct answer: ONLY ONE of these four options is correct option. For each question, choose the correct option 10 answer the question. Discovery of electron & it’s charge a. @ Which of the following properties of cathode rays is incorrect? (A) Glow inthe tube on application of current (B) Defelection in Electric Field (C) Flow from Anode to Cathode (D) e/m ratio is independent of the cathode material The minimum real charge on any Particle which can exist. (A) 16 «10°C (C) 48 « 10"C (B) 1.6 10°C (D) Zero Rutherford’s model & size of nucleus Qs. Which of the following statements are not true for anode ray ? (A) They are deflected by electric and magnetic fields (B) Their e/m ratio depends on the gas in discharge tube used to produce anode rays (C) The e/m ratio of anode rays is constant. (D) They are produced by ionization of the ‘gas in discharge tube, Rutherford’s experiment, which established the nuclear model of atom, use a beam of ? (A) fi particles, which impinged on a metal foil and get absorbed (B) y-rays, which impinged on a metal foil and get absorbed. (C) Helium atoms, which impinged on a metal foil and got scattered, (D) Helium nuclei, which impinged on a metal foil and got scattered Qs. Qi. In Rutherford's scattering experiment, which of the following does not happen? (A) Most of the @ -rays pass through without deflection, (B) A few @-pa nucleus (©) A few a-particles are deflected back. () a-particles going near the nucleus are slightly deflected. les pass through the Rutherford q-particle scattering experiment led to the conclusion that ? (A) mass and energy are related (B) The mass and the positive charge of an atom are concentrated in nucleus, (C) Neutrons are present in nucleus (D) atoms are electrically neutral In Rutherford’s scattering experiment an @-particle is projected with K.E. = 4 MeV, minimum distance upto which this a-particle can reach to the nucleus of Cu nucleus- (atomic number of Cu = 29) (A) 2.08 « 10 m (B) 2.08 « 10 m (©) 1.04 « 10" m (D)1.04 « 10 m Anatom having atomie mass number 13 has 7 neutrons. What is the atomic number of the atom? (A)6 (8 (B)7 (D)9 Anion with mass number 56 contains 3 units of positive charge and 30.4% more neutrons than electrons. Assign the symbol to this ion. (A) jFe** (B) $$Fe* (C) Fe (D) Fee" wWSaral & at we area SlwSaral Wave & Planck’s Theory Qi0. qu. Qn. Qu3. Qua. Calculate the wave number of a radiation having wavelength 600 nm ? (A) 1.67 = 108m! (B) 1.67 = 10! m* (©) 1.67 = 10 m! (D) 1.67 « 10° m" The frequency of an electromagnetic radiation is 2 * 10° Hz, What is its wavelength in metres (Velocity of light = 3 «10 ms") (A) 6.0 x 10 (B) 1.5 «10° (C) 1.5 * 10? (D) 066 = 107 Calculate the energy of'a photon of sodium light of wavelength 2 10 m? (A) 9.9 «10°F (B) 6.6 * 10" (C) 9.9 * 10" T (D) 4.8 « 10" J The energies E, and E, of two radiations are 25 eV and S0eV respectively. The relation between their wavelengths ie. 4, and , will be ? (A) 2,> 2, (B) 4,24 1 © a=4a, ) a, What is the number of photons of light with a wavelength of 4000 pm that provide 1 Joule of energy ? (A) 5.4 x 108 2 10° (B) 4.2 « 10" (D) 2.0 « 10" The power output for a certain laser transition was found to be 2.79 J per see per square meter. Given 2 = 520 nm, calculate the number of quanta emitted per square meter per second. (A) 3.10 x 10" (C) 2.10 * 10" (B) 5.10 « 10” (D) 7.30 * 10 Atomic Structure Bohr Model QI6. Qi. ais. Qu. Q20. Qui. Q22. According to quantum restriction on angular ‘momentum, imposed by Bohr (a) watt T (By m-th (me = D)5= Rul =) 3 The distance between 2 and 1" bohr orbit of hydrogen atom is ? (A) 0.529 «108 em (C) 2.116 « 10%em (B) 1.587 « 10-8 em (D) 1.058 « 10%em The ratio of the radii of the 5" orbits of He* & Li’ will be? (A) 2:3 (4:1 (B) 3:2 (D) 5:3 The ratio of the radii of two Bohr orbit's of H-atoms is 4 : 9 what would be their nomenclature (A) K and L (C)N and L (B) L and M (D) 2 and 3 both In the Bohr's orbit, what is the ratio of total potential energy and total energy of the electron? (A) V2 @x (B)2 (p) +2 Find out the K.E, ofthe the hydrogen atom :- (A) -13.6 ev (C)+34ev st excited state of (B)-3.4ev (D) +13.6 ev For which of the following species, Bohr's theory is not applicable ? (A) Be (B) Li? (D)HwSaral Q23. Electron absorb photon when :~ Q29, (A) it revolves in a stationary path (B) it jumps from n= 2 ton (C) it jumps from ton (D) all are correct Q24. The graphical representation of energy of e and atomic number is ? Zz ) t © () Zz Q25, The ratio of E,-E, to E;-E, for the H-atom is approx. equal to ? (a) 10 (B) Is «17 (Dy 12 Q26, The ratio of the energy of electron in second excited state of He’ ion to the energy of the electron in the first excited state of Be* is? | Q32, (A133 (B) 9:16 (1:9 (D) 16:9 Q27. If the speed of electron in the Bohr's first orbit of hydrogen atom is x, the speed of the electron in the Bohr's third orbit is ? Q33. (A) x9 (B) x3 (©) 3x (D) x Spectrum, Rydberg Formula Q28. The line spectra of two elements are not identical because ? Qa. (A) The elements do not have the same number of neutrons (B) They have different mass number (C) Their outermost electrons are at different energy levels (D) They have different valencies + + Q30. 4 @) se . A Zs Q31. Atomic Structure With a certain exciting radiation of a particular frequency, to which hydrogen atoms are exposed. the maximum number of spectral lines obtainable in the emission is 15. The uppermost energy level to which the electron is excited is n= ? (Ay4 (B) 5 © 6 (D)7 Calculate the wavelength (in A) of radiation emitted, producing a line in Lyman series, when an electron falls from fourth stationary state to ground state in hydrogen atom. (A) 970 A (B) 900 A (C) 800A (D) 920 A IFR is the Rydberg constant for hydrogen, then wave number of the first line in the Lyman series is ? R (A) 2R () > 3R R o> OF ‘The wavelength of limiting line in balmer series of H-atom is ? (A) 3.644 A° (B) 36.44 Ae (C) 364.4 A® (D) 3644 Ae Third line of Balmer series is produced by which transition in spectrum of H-atom ? (A) 5 to2 (B) Sto 1 (©) 4102 (D) 401 The longest 4 for the Lyman series is? [Given R,, = 109678 em'] (A) 1215 (B) 1315 (©) 1415 (D) 1515 wWSaral & at wae area SIwSaral Photoelect & Q36. Qa. Q38. Effect Which of the following is incorrect regarding photoelectric effect ?” (A) It helped in establishing the particle nature of light (B) There is a minimum frequency below which no photoelectrons are ejected (C) Photocurrent increases with increasing intensity (D) Energy ofall the photoelectrons ejected is the same Which of the following explains almost instantaneous ejection of electrons from cathode? (A) Energy of radiations being continuous (B) Planck’s idea of radiation being made of particles called quantum (C) Low ionisation potential of cathode (D) None of the above In photoelectric effect work function of any metal is 2.5 eV. The most energetic emitted electron are stopped by potential of 1.5 Volt, then ? (A) Energy of incident photons is 4eV (B) Energy of incident photons is 1eV (C) Wavelength of emitted electron is 1 A (D) Photocurrent increases with the appli- cation of photons of high frequency The ejection of the photoelectron from the silver metal in the photoelectric effect experiment can be stopped by applying the voltage of 0.35 V when the radiation 256.7 nm is used. Calculate the work function for silver metal (A) 4.48 eV (C)3.18 eV (B)2.18 eV (D) 0.21 eV If the photon of the wavelength 150 pm strikes an atom and one of its inner bound electrons is ejected out with a velocity of 1.5 * 10? ms", calculate the energy with which it is bound to the nucleus. (A) 5.1210 '8J (BY 1.22 * 1085 (C)434* 1085 (D)2.34* 1075 Get Top Ranks in IIT-JEE/NEE Atomic Structure Principle Q40. Qa. 42. Qu. 45. Assuming that monsieur de-Broglie weighing 70 kg was jogging at 15 knv/hr. Calculate the wavelength at which he was Jogging. (A) 4.166 m (©) 227 «10m (B) 2.27 « 10% em (D) None of these Two particles of masses m and 2m have equal kinetic energies. Their de Broglie wavelengths are in the ratio of ? (A) Le (B) 1:2 (1: V2 (D) y2 51 The de Broglie wavelength associated with aball of mass 1 kg having kinetic energy 0.5 Sis? (A) 6.626 * (B) 5.257 « (C) 6.297 « (D) 7.287 * 104m 107m 10cm 10cm A beam of electron is accelerated by a potential difference of 100 volt. Find the wave length of wave associated with electron ? (A) 1.23. A (C) 262A (B) 123A (D) 22.6 A If the de-Broglie wavelength of the fourth Bohr orbit of hydrogen atom is 4A, the circumference of the orbit will be ? (A) 4A (B) 4 om (C) 16 A (D) 16 nm What is the minimum product of the uncertainty in position & the uncertainty in momentum of a moving electron ? aye B) AE (B) 2x pt > Get it on P: (rodwSaral Atomic Structure Q46. Ifuncertainty in position of electron is zero | Q52. Sub-shells present in N-shell will be ? the uncertainty in its momentum would be? (A) 4s, 4p, 4d, 4 (A) Zero (B) 2x (B) 3s, 3p, 3d (C) han (D) Infinity (C) 2s, 2p (D) None Q47. Uncertainty in position and momentum are ? equal. Uncertainty in velocity is ? Q53. Which of the following is not permissible ? i h (A)n=4, ¢=3,m=0 (A) yo ® an 7 7 (B)n=4, ¢=2,m=1 Lk (C)n=4, ¢=4,m=1 ) ome (D) None of these (D)n=4, ¢=0,m=0 Q48. In an atom, an electron is moving with a speed of 600 m/s with an accuracy of | 254 0.005%. Certainty with which the position ‘An electron has spin quantum No. +4 and a magnetic quantum no. I. It cannot be of the electron can be located i present in ? (= 6.6 * 10 kg ms, mass of electron, A) orbital my fortital o = 9.1 x 10°" ke) (A) dorbita (B) orbital - (©) sorbital (D) p-orbital (A) 1.52 «104m (B) 5.10 « 108 m (C) 1.92 «109 m_— (D) 3.84 «109m Radial Probability Distribution Functions Quantum Numbers Q55. The statements which is correct regarding Q49. Which of the following is correct for Nodes ? 2p-orbitals ? ” ,€=2 (B)n=1,¢-0 ()n=2,¢=0 (D)n=2,6=1 (A) Number of total node in an orbital = n (B) Number of radial node in an orbital =n-¢-1 (C) Number of Angular node in an orbital QS0. The correct set of quantum number of 3f =n orbital (D) All of the above 1 1 (AN3.3145 (B)3,2,2,45 2 2 | Q86. ‘The nodal plane for the orbital given below 5? 1 is? (4,33, 45 (D) None of these y QS1. In the absence of external magnetic field £ : sub-shell has ? (A) 5 degenerate orbitals (B) 3 degenerate orbitals (C) 7 degenerate orbitals (A) xy. yz (B) xz, ye (D) Non-degenerate orbitals (©) xz, xy (D) Zero wWSaral & at wae area a1wSaral Qs7. Qs8. The wave function of atomic orbital of H- like species is given as : _ J 3 V20 = 4 ig 23 (2-2r) e% ‘The radius for nodal surface for He’ ion in Ais? (ALSA (2A (IA (D)4A For an orbital in B* radial function is ? 3 z 1 4 =—-| 4-o)o © RO) omc) (4-o)o€ 0.529 A; Z=atomic a where o = — and ag number, r = radial distance from nucleus. The radial node of orbital is at distance from nucleus. (A) 0.529 A (C) 1.06 A (B)212A (D) 0.423 A Rules for Filling of Electrons & Electronic Configuration Q59, Q60, The correct order of energy of subshells is? (A) af < 7s < 5d < 6p (B) Af < Sd < 6p < 7s (C) 1s < Sd < 6p <4f (D) 5d < 6p < 4f< 78 Arrange the following in increasing order of energy @n=4, = (in m (ii) n=4, ¢ = |. m=0,s=—% (iv) n=5, 6 = (A) (i < (ii) < Gil) < (iv) (B) Gill) < (i) < (i < (©) Gili) < Gv) < Gi) < (D) (ii) < (iii) < () < (iv) Q61. 62. 263. Q64. Q65. 66. Atomic Structure The four quantum numbers of the outermost orbital of K (atomic no. = 19) are ? (A)n=2, ¢=0,m=0,s (B) n= 4, ¢ =0,m=0,5 (C)n=3, ¢=1m=1s (D)n=4, ¢ =2,m=-1,s= +5 Correct set of four quantum numbers for valence electron of rubidium (Z = 37) is ? (A) 5, 0, 0, +4 1 B) 5.1, 0 +> 1 6, 0, 0, + = (D) 6, 0, 2 1 1+ (C) 5, + 2 The electronic configuration of Fe’? is ? (A) [Ard 4s! (B) [Ar}3d° 43° (©) [ArB3d° 48" (D) [Ar]3° 4s" fh) (VTL 14 2s 2P,2P, 2P, can follow the hund's rule by (A) Changing the spin of electron present in the P, orbital (B) Changing the spin of electron present in the P.-orbital (C) Both (1) and (2) are correct (D) Changing the spin of electron present in the P. orbital this electronic arrangment Maximum magnetic moment will be shown by? (A) 34° (© 3d” (B) 32 (D) 3d’ The spin only magnetic moment (in BM) of. Cr ion is? (A) 48, (B) J35 (© V4 (D) ViswSaral Atomic Structure Basic Concepts of Chemistry Q68. The charge of one mole of electrons is ? (A) 3.64 10°C (B) 5.32 « 10° C Q67. Select isoelectronic set :- (C) 7.53 * 10°C (D) 9.63 10°C (a) K*. $2, Se® b) Nat, H.0*, NE Q69. Naturally occuring Neon has two isotopes, (0) Nav, Bi « whose atomic weight are 20 (I) and 22 (II). (¢) CO,, H,0", NH, Atomic weight of natural neon is 20.2. The (a) 0,2, Ny C2 percentage of isotopes (I) and (II) (A)aed B) bed respectively is ? Oabd Dabe (A) 30 and 70 (B) 10 and 90 _ ° (©) 90 and 10 (D) 70 and 30 Exercise - 1A Concept Builder ONE OR MORE THAN O Q3. According to planck’s quantum theory : CORRECT TYPE (A) Energy is absorbed or lost continuously in the form of quantum Each question has FOUR options for correct @ypEaeray is absosbed or lost dis- answer(s). ONE OR MORE THAN ONE of these comimouslyanithe form of quantum four option(s) is (are) correct option(s). For each (©) Electromagnetic radiations are made of question, choose the correct option(s) to answer the small energy packets known as quantum question. (D) Quantum, which has 4 = 38004 ~7600A, is known as photon QI. Which of the following is not true for Thomson's model of the atom ? 4. Incorrect for Bohs model = (A) The radius of an electron can be ; calculated using this model (A) applicable for any species (B) In an undisturbed atom, the electrons @® m= will be embedded in positively charged an spheres (©) order of energies of orbitals E, green > orange > yellow (B) orange > yellow > blue > violet (C) yellow > green > blue > violet (D) violet > blue > orange > red Q16, A laser producing monochromatic lights of different wavelength is used to eject electron from the sheet of gold having threshold frequency 6.15 = 10 s' which of the following incident radiation will be suitable for the ejection of electrons ? Atomic Structure (A) One photon with frequency 5.16 * 10's (B) 1.5 moles of photons having frequency 3.05 * 10s? (©) 0.5 moles of photon of frequency 12.3 x 10" s? (D) All of the above QI7. The number of photo electrons emitted depends upon - (A) The product of intensity and frequency of incident radiation (B) The frequency of the incident radiation (C) The intensity of the incident radiation (D) None of these Paragraph for (Q. 18 to 22) ‘Quantum numbers are required to specify the energy of electron, number of electron in any shell, to determine orbital angular momentum [Link] are filled in the order of increasing energy starting from lowest energy. Any two electron in any atom can not have four quantum number same. Qs. Maximum number of electron which may 1 have m=+ 1 & 8=—> for Fe 2 Bl ©3 Wes Q19. Orbital angular momentum is non-zero for:~ (Is (B)2p O3s M)4s 20. Which quantum number will affect if we remove one electron from Mg :- An Be Om (js Q2L. Which quantum number represent the magnitude and direction of orbital angular momentum :- (A) n,m (B)¢,m (ms (D)m, ¢ Q22. In which of the following set/s of orbitals electron have equal orbital angular momentum = (A) 1s,2p (B)2s,2p (C)2p.3p (D)3p.3d wSaral & at wa area SIwSaral ‘Atrmmla Structure MATCHING LIST TYPE Each question has TWO (02) matching lists: LIST Land LIST I. FOUR options are given representing matching of elements from LIST | and LIST Hl, ONLY ONE of these four options corresponds to a correct matching. For each question,choose the option corresponding to the correct matching. 23, Match the column for the energy and radius of Hydrogen. List I List II (A) Radius of 1* orbit (P) ~ 13.6 eV/atom (B) Radius of 2” orbit (Q)-3.4 eV/atom (C) Energy of 1* orbit (R) 0.529 A (D) Energy of 2* orbit (8) 2.1164 A B Cc D A Q R Pos ®) S R Q P © R S PQ © S R PQ MATCH THE COLUMN TYPE Following questions contain statements given in two columns, which have to be matched. The statements in Column-1 are labelled as A, B, C and D while the statements in Column-II are labelled as (P), (Q), (R) and (S). Any given statement in Column-I can have correct matching with ONE OR MORE statement(s) in Column-II. Q24, Match the column correctly — Column I Column II (A) No. of orbitals in the n® shell () 2Q¢+1) (B) Max. no. of electrons in a subshell Qn (C) No. of subshells in n shell (R)2¢ 41 (D) No. of orbitals in a subshell (S) 0 Q25. Match the column correctly — Column 1 Column IT (A) The radial node of $s atomic orbital is Po (B) The angular node of 34, atomic orbital is @ 4 (C) The sum of angular node and radial node of = (R)—2 4d, atomic orbital (D) The angular node of 3p atomic orbital is (Ss) 3 CSG cs (rodwSaral Atomic Structure NUMERICAL TYPE 29. Maximum number of electrons possible in a sublevel is equal to a ¢ +b. Value of (ab). The answer to each question is a NUMERICAL VALUE. For each question, find the correct numerical value (in decimal notation, truncated/ | Q30- How many electron in ,K have n=3, ¢ =0. rounded-off to the second decimal pla 6.25, 7.00, 0.33, -.30, 30.27, -127.30) Q31._De-Broglic wavelength ofa particle becomes Q26. Atomic number of metal which used as foil z times when its K.E, increase x times. in Rutherford experiment ? Value of x =? Q27. q-particle has mass in amu ? [Write your Ans, nearest integer value] Q32. If X* has 25 neutron, 28 electron, then calculate electron, proton & neutron in X"? Q28. Ratio of energies of a photon if its wave [Write your answer as sum of electron + length is 6200 pm and 310A is a/b. Find protondemetrox] value of (a +b) ? Exercise - 2 Brain Booster SINGLE CORRECT TYPE (A) 15 «10 (B) 27.2 « 10 (C) 17.2 * 10 (D) 25.2 « 10” Each question has FOUR options for correct answer: ONLY ONE of these four options is correct | Q4. The energy required to break one mole of option. For each question, choose the correct option CLCI bonds in Cl, is 242 kJ mol, The to answer the question. longest wavelength of light capable of breaking a single CI-Cl bond is ? QI. What will be ratio of volume of nucteus with (c=3x10'ms™ and N,, = 6.0210" mot") volume of atom ? Assume that nucleus and (A) 494 nm (B) 594 nm atom are spherical aa £0} 760 am (A) 10° (B) 10" (©) 10 @)10 QS. The energy of an electron in excited hydrogen atom is ~3.4 eV. Then, according Q2. Which of the following statements is to Bohr’s theory the angular momentum of incorrect ? this electron in Jsee is ? (A) The frequency of radiation is inversely (A) 2.1 « 10 (B) 42 « 10 proportional to its wavelength (© 66x10" (D) 3.2 «10 (B) Energy of radiation increases with © a in eaueney ds th | Q% l'radius of n® shell is 2.116 A for H-atom By OF radiation decreases with caleulate velocity of ein the same shell increases in wavelength as a (D) The frequency of radiation is directly (A) 2.188 « 10° m/s (B) 2.188 10" m/s proportional to its wavelength (C) 1.094 10° m/s (D) 1.094 * 10° ms Q3. A bulb emits light of wavelength 4500A. | Q7- Which orbit of Be has the same orbit radius The bulb is rate as 150 watt and 8 percent of the energy is emitted as light. How many photons are emitted by the bulb per second? as that of the ground state of hydrogen atom? (A) 3 (B)2 4 (D)5 wWSaral & at wae area SI¥Sa ral Quo. qu. Qn. Qu3. The energy required to dislodge electron fiom excited isolated H-atom, (E,=-13.6 eV) is? (A) = 13.6eV (B) >13.6eV (C) <13.6 and >3.4eV (D) <34eV The angular momentum of any electron can have the value(s) ? (a) 3 (vz) (b) 2.5 (22) (©) 0.5 (hn) (@) (Wz) (A) a,b, d (B) bd (abe @) acd The radii of any two of the first four Bobr's orbits of the hydrogen atom are in the ratio 1: 4. The energy difference between them may be ? (A) Either 12.09 eV or 3.4 eV (B) Either 2.55 eV or 10.2 eV (©) Either 13.6 eV or 3.4 eV (D) Either 3.4 eV or 0.85 eV The kinetic energy of an electron in second Bohr's orbit of a hydrogen atom is : (a, is Bohr's radius):- bh? h? ‘may ®) 16n?maj, h ©) 64n7mag, for balmer series, what is the value of ¢,? 4 2 WR, ®R, (©2R, (Dy AR, Which of the following statement(s) about spectral series is/are correct ? (a) Paschen series appears in the infrared region (b) The lines in the Balmer series corres- ponds to electron transitions from higher energy levels to n = 2 energy level Qu. Qis. QI6. Qu. as. Atomic Structure (©) Transitions from higher energy levels to 5* energy level produce pfund series which falls in the infrared region (d) The lines of Lyman series appear in the visible region (Aya bd (C) a,b, (B) b, d (D) aed In hydrogen spectrum; Ifn = 4 then ratio of number of lines in emission spectrum, in the ultraviolet and visible regions (A) 2:3 (B) (3:2 (D) None of these de Broglie equation has no significance for? (A) Electron (B) Proton (C) Neutron (D) Cricket ball An q-particle is accelerated through a potential difference of V volts fromrest. The de-Broglie's wavelength associated with it is? For an electron present in which of the following orbital for which (n+ /-+ m+ s) value is maximum, Consider maximum possible value for ‘m’ and minimum possible value of*s’ (where ever applicable). (A) 3p (B) Sp (4d (D) 5s This curve can show radial probability distribution of 2 4erty'O] 1 (a) 3s (b) 3p () 3d (@) 4p (©) 5d (Aa be (©) a TeddwSaral Qu. Q20. Qu. Q22, Q23. Which of the following statement is FALSE? (A) Number of spherical node for 4d orbital is3 (B) For p, orbital xz. plane is angular node (©) For's’ orbital, y?is maximumat nucleus. (D) Angular wave function of P, orbital is proportional to cos q (Given : q is angle from z-axis) The radial part of schrodinger wave equation for hydrogen atom is ? 1 Tolgart (% DO 80 + 12)e0* wl Where a, = constant & o = 2r/na,; n= principle quantum number Select the incorrect statement: (A) Distance of nearest radial node from the nucleus is 2a, (B) Distance of farthest radial node from the nucleus is 12a, (©) wO0) is for 4s orbital (D) (x) is for 4p orbital Find the group of orbitals in which atleast one common nodal plane is present : (A) 44. Sd, (B)2p,34,, 4d, ©) 2p,27,4d,— (D)2p, 344d, Which orbital notation does not have spherical node = (Ayn=2,¢=0 (B)n (C)n=3,¢-0 (D) The orbital diagram in which aufbau principle is violated is ? OA A 8) (LE Ont of Mat Qu, Q25. 0 Q26. Q7. Q28. Q29. Atomic Structure The orbital diagram in which Pauli exclusion principle, Hund’s rule and Aufbau principle are violated is ? 2a 2a ) [1] ATP) @ Gd NN 2s 2p 2s 2p. oj oy Lb LET Tb Which of the following has the maximum number of unpaired electrons ? (A) Mn (B) Ti Ov (D) Al Prediet the total spin in Ni 5 3 (a) 43 @) #5 1 (Cc) Sa (D) +1 Which of the following statement is true ? (a) 6 electrons are present in Mg for which m=0 (b) 6 electron are present in one p-orbital of Mg (c) Maximum 18 electrons present in M- shell (d) 3-electron present in phosphorous for which, ¢ = 0,m=0, s= +4 (A) a, bc, d (aed (B) abe (D) c,d Select the correct answer (A) number of ein Cr for which /= 0 are 5 (B) two nodal plane present in Sp, orbital (C) Se" present in Mg for which (n + 1) = 3 (D) All are correct If spin only magnetic moment is 2.85 BM for x” then x is ? ac @o (BN (D)F wWSaral & at we area SlwSaral Exercise - 2A Atomic Structure Brain Booster ONE OR MORE THAN CORRECT TYPE Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these _four option(s) is (are) correct option(s). For each question, choose the correct option(s) to answer the question. au. Qu. Q3. Which of the following statements (regarding an atom of H) is/are correct ? (A) Kinetic energy of the electron is maximum in the first orbit (B) Potential energy of the electron is maximum in the first orbit (C) Radius of the second orbit is four times the radius of the first orbit (D) Various energy levels are unequally spaced For radial function & angular function correct option is/are? (A) RG) determine size of an orbital (B) angular function determine energy (C) R@) contains n & m only (D) q(q) contains ¢ & m. Neon gas is generally used in the sign boards. If it emits strongly at 316 nm. Choose the correct options — (A) The frequency of emission is 9.5 « 10" Hz (B) Distance travelled by this radiation in 30s is 9 x 10° km (C) Energy of quantum is 6.29 x 103 (D) Number of quanta present ifit produces 23 of energy is 3.18 * 10° The energy levels of hypothetical one electron atom are Oev n= a —0.50 eV —n=5 -145 eV —n=4 ~ 3.08 eV —2=3 3eV —n=2 15.6 eV —n=1 Get Top Ranks in IIT-JEE/NEE Qi. Choose the correct options (A) The ionisation potential of atom is 15.6 eV. (B) The short wavelength limit of the series terminating at n = 2 is 233.9 nm. (C) The wave no. of photon emitted for the tran n made by the electron from third orbit to its orbit is 1.009 x 107m! (D) The ionisation potential of atom is 25.6eV Which is / are correct statement ? (A) The difference in angular momentum associated with the electron present in consecutive orbits of H-atom is (n-1) cam 2m (B) Energy difference between energy levels will be changed if, P.E. at infinity assigned value other than zero. (C) Energy of the shells is in the order of 2 <3 <4. (D) On moving away from the nucleus, kinetic energy of electron decrease The LP. ofan atom is 16eV. What are wrong values of the value of first excitation potential? (A) 10-2 ev (B) 12 eV (©) 14ev (D) 16 ev 10.84 x 10 hydrogen atoms are excited by radiations. The study of spectra indicates that 27% of the atoms are in 3" energy level and 15% of atoms in 2™ energy level and the rest in ground state. IP of His 13.6 eV. Choose the correct options ~ (A) No. of atoms present in I* energy level is 628.72 x 10” atoms (B) No. of atoms present in 2 energy level 162.6 * 10" atoms (©) No. ofatoms present in 3" energy level 292.68 * 10°! atoms (D) Total energy evolved when all the atoms to ground Cea ‘Google PlaywSaral Q8. Which gives line spectrum ? (A) Atomie Hydrogen (B) Molecular Hydrogen (C) Methane (D) Atomic Helium When photons of energy 4.25 eV strike the surface of a metal A, the ejected photoelectrons have maximum kinetic energy T, (expressed in eV) and de Broglie wavelength 7 ,. The maximum kinetic energy of photoelectrons liberated from another metal B by photons of energy 4.2 eV is T,=T, — 1.50 eV. If the de Broglie wavelength of these photoelectrons is 2,-2.2... then which is correct ? (A) The work function of A is 2.25 eV (B) The work function of B is 3.70 eV (C)T,=2.00eV (D)T,=2.75 eV Q10. A gas of identical H like atoms has some atoms in the lowest (ground) energy level A and some atoms in a particular upper (excited) energy level 'B' and there are no atoms in any other energy level. The atoms ofthe gas make transition to a higher energy level by ab sorbing monochromatic light of photon energy 2.7 eV. Subsequently, the atoms emit radiations of only six different photon energies. Some of the emitted photons have energy of 2.7 eV. Some have more and some less than 2.7 eV. Choose the correct options ~ (A) The principal quantum number initially excited level B is 2 (B) The ionization energy for the gas atoms is 14.4 eV (C) The maximum energy of the emitted photons is 13.5 eV (D) The minimum energy of the emitted photons is 0.7 eV PARAGRAPH TYPE This section contains PARAGRAPHS. Based on each paragraph, there are questions. Each question has FOUR options. ONLY ONE of these four options corresponds to the correct answer. For each question, choose the option corresponding to the correct answer: Atomic Structure Paragraph for (Q.11 to 13) De Broglie proposed dual nature for electron by h putting his famous equation *=——. Later on Heisenberg proposed uncertainty principle as h [Link] 27. On the contrary particle nature of electron was established on the basis of photoelectric effect. When a photon strikes the metal surface, it gives up its energy to the electron. Part of this energy (say W) is used by the electrons to escape from the metal and the remaining energy Ls imparts kinetic energy (im) to the ejected photoelectron, The potential applied on the surface to reduce the velocity of photoelectron to zero is known as stopping potential, QL. Uncertainity in the position of an electron (mass 9.1 « 10° kg) moving with a velocity 300 mvs, accurate upto 0.001% will be ? ah 4m, (A) 19.2 « 102 m (©) 3.84 « 10? m 8x10 ‘) (B) 5.76 « 10? m (D) 1.92 « 102m Q12. When a beam of photons of a particular energy was incident on a surface of a particular pure metal having work funetion = (40 eV), some emitted photoelectrons has stopping potential equal to 22V, some had 12V and rest has lower values. Calculate the wavelength of incident photons assuming that at least one photoelectron is ejected with maximum possible kinetic energy. (A) 200 A (B) 248A, (C) 238A (D) 310A The circumference of third orbit of H atom is 3nm, What may be the approximate wavelength of the photon required to ionize electron from this orbit ? (A) 911m (B) 364.7nm (C) 82inm (D) 205nm Qs. wSaral & at wae ae SlwSaral Atomie Structure TRIPLE MATCH COLUMN TYPE This section contains TWO tables (each having 3 column and 4 rows).Based on each table each question has FOUR options[A},[B],[C] AND [D].ONLY ONE of these four is correct. Column-I Column-IL Column-IIl (Quantum No.) Quantises (e*) (Orbital) (Dn (P) Direction of orbital angular momentum vector (i) Size (In) ¢ (Q Direction of spin (i) Orientation (ID) m (R) Energy ii) None (v)s (S) Magnitude of orbital angular momentum (iv) Shape QU4. Select the correct option :- (A) IL, P, iv (B)1,R, iv (©) LB ii (D) IV, Q iti MATCH THE COLUMN TYPE Following questions contain statements given in two columns, which have to be matched. The statements in Column-I are labelled as A, B, Cand D while the statements in Column-HI ave labelled as (P), (Q), (R), (S) and (T). Any given statement in Column-I can have correct matching with ONE OR MORE statement(s) in Column-HL. QU5. Column-I Column-I1 (A) n=6 — n=3 (in H-atom) (P) 10 tines in spectrum (B) n=7 > n=3 (in H-atom) (Q spectral lines in visible region (C) n=5 — n=2 (in H-atom) (R) red line in spectrum (D) n=6 — n=2 (in H-atom) (S) spectral lines in infra red region (1) 6 lines in spectrum Q16, Match the column Column I Column It (A) Ina sample of H-atom for __(P) Maximum 6 spectral lines will be observed 5 52 transition from the sample (B) Ina sample of He* ion for (Q)A photon of wavelength 2 = = can be emitted. 5 — 1 transition R (©) Ina sample of H-atom for (R) A photon of wave number ¥ = +7-can be mitted. 7 — 3 transition (D) Ina sample of He* ion for (S) When single isolated atom/ion is considered, 7 = 4 transition maximum 4 spectral lines are observed for given transition. QI7. Match the column Column I Column I (A) Ratio of ionisation energy for He* ion and Be” ion, respectively (P) (B) Ratio of total energy of electron in I* excited state of He’ ion and (Q)4:1 potential energy of electron in 5 excited state of Li ion, respectively (C) Ratio of time period of revolution of electron in 1" orbit of He’ ion (R134 and 2" orbit of Be** ion, respectively (D) Ratio of radius of 3" excited state of He” ion and first ex state of H-atom. d (s)1:2 Get Top Ranks in IIT-JEE/NEE’ on V2 (rodwSaral Atomic Structure Answer Key Ex-1 fc | c |] ec fp] ep ] cf] pep} ec} ec | a | [ec {| pf a {a {| p | pf a | a | po | c | fp | a | a {ic }] a | p | c | c | p | p | | c_| | c {| c | B | c {| 6 | pb | bf sp | Ex-1A LAD 2.A,CD 3. BC.D 4. A,B,D 5.D 6.B.C TAC 8.B,D 9. A,B,C.D 10. A,B,C 11. A.D 12. B,C 13. B,C,D [Link] — 18.D 16.4 17.C 18.C 19.B 20.D 21.B 22.€ 23.(C) 24. AS, BOP,C5Q, DOR 25.A5Q,B5R,C>S8, DP 26.79 21.4 28. 6 29.2 30,2 31.2 32. 88 Ex-2A 3. A,B,C, 4. A.B.C 5.C,D 8. A.D 9. A,B,C 10. A,B,C, 13. 14.C BPS; C > QT; D > PQR B>S;C>RS;D—> PQ 17. ASR: B>P;C>S8;D>P wWSaral & at wae area SlwSaral -: Important Notes & Formulas :-