The __toString() method is extremely useful for converting class attribute names and values into common string representations of data (of which there are many choices). I mention this as previous references to __toString() refer only to debugging uses.

I have previously used the __toString() method in the following ways:

 - representing a data-holding object as:
   - XML
   - raw POST data
   - a GET query string
   - header name:value pairs

 - representing a custom mail object as an actual email (headers then body, all correctly represented)

When creating a class, consider what possible standard string representations are available and, of those, which would be the most relevant with respect to the purpose of the class.

Being able to represent data-holding objects in standardised string forms makes it much easier for your internal representations of data to be shared in an interoperable way with other applications.