- The fourth of six children. He has one older sister (Elizabeth Keuchler), two older brothers (Alec Baldwin and Daniel Baldwin), one younger sister (Jane Sasso) and one younger brother (Stephen Baldwin).
- Both William and younger brother Stephen Baldwin are former Calvin Klein models.
- William and his older brother Alec Baldwin were both very close friends of the late John Kennedy Jr..
- William, who trained for three weeks at the Chicago Fire Academy, rode along with the Chicago Fire Department's Squad 5 while preparing for his role as Brian McCaffrey in Backdraft (1991).
- William and his brothers were all wrestlers in high school, and he even wrestled in college. Aside from being a wrestler in high school, William also played on the high school football team.
- Four years after they got together, William and Chynna were married on 9 September 1995 at the Sacred Hearts of Jesus and Mary Roman Catholic Church in South Hampton, New York.
- Both he and his brother Alec Baldwin won $250,000 for charity on separate celebrity episodes of Who Wants to Be a Millionaire (1999).
- Like his brother Alec Baldwin, William is a vegetarian and was once nominated for PETA's "Sexiest Vegetarian".
- A former wrestler, he was inducted into the Amateur Wrestling Hall of Fame after receiving the 2003 Outstanding American Award. Past recipients included Senator Paul Wellstone, Dan Dierdorf, astronaut Mike Collins, actor Kirk Douglas, writer John Irving, Donald Rumsfeld, General Norman Schwarzkopf, and many former presidents.
- According to most biographies on the Baldwin Brothers, William and his brothers, Alec Baldwin, Stephen Baldwin, and Daniel Baldwin, attended Massapequa High School, but they actually went to Alfred G. Berner High School, two miles from Massapequa High School. But their father, Alexander Jr., was a highly respected history teacher and football coach at Massapequa High. In 1998/1999, he was honored by the school, and the auditorium was renamed for him. (One of Al Baldwin's former students is Brian Kilmeade).
- Baldwin and pop singer Chynna Phillips gave birth to 7 lb., 2 oz. daughter, Jamison Leon. (February 27, 2000)
- Son-in-law of John Phillips and Michelle Phillips.
- William likes jazz, the Count Basie Band (swing), and Van Morrison, but has no favorite genre of music.
- William worked as an aide on Capitol Hill for U.S. Representative Thomas J. Downey (New York, Democrat).
- Wanted to name one of his sons Gehrig after New York Yankees legend Lou Gehrig.
- Attended the State University of New York at Binghamton for two years before leaving to go to Hollywood.
- Before becoming an actor, he worked as a male model.
- Daughter Brooke Michelle was born to his wife Chynna Phillips in New York on 6 December 2004, weighing 7 pounds, 6 ounces.
- Son Vance Alexander was born on 23 October 2001 in New York City.
- Has a dog named Thurman, named after New York Yankees great Thurman Munson.
- The Creative Coalition (TCC ) elected William as their new president.
- Studied Political Science at university.
- He is of Irish, English, Scottish, French-Canadian, and German descent.
- No relation to actor Adam Baldwin and voice actor Greg Baldwin.
- Brother-in-law of Joanne Smith-Baldwin, Kennya Baldwin, and Hilaria Baldwin. Ex-brother-in-law of Elizabeth Baldwin and Kim Basinger.
- Son of Carol M. Baldwin
- Cousin of actor Joseph Baldwin.
- Graduated from Alfred G. Berner High School in Massapequa, Long Island, New York in 1981.
- Half-brother-in-law of Austin Hines, Lois Kessel, Aron Wilson, Bijou Phillips, Mackenzie Phillips, Tamerlane Phillips, and Jeffrey Phillips.
- Attended Alfred G. Berner High School in Massapequa, Long Island, New York with the Gilgo Beach serial killer Rex Heuermann.
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